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1 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt 10 pt 15 pt 20 pt 25 pt 5 pt Light and Waves Periodic Trends Quantum Theory Mass, Atoms, Moles, and How Many Naming
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2 Which has the higher energy: X-rays or Microwaves
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3 X-rays
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4 T/F Energy and wavelength are directly proportional
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5 False E=
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6 For the electronic transition in the hydrogen atom from n = 2 to n = 5 determine whether the radiation is emitted or absorbed during the transition.
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7 absorbed
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8 For the electronic transition in the hydrogen atom from n = 2 to n = 5, calculate the energy of the associated radiation.
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9 Answer: E = -2.178*10 -18 (1/n f 2 - 1/n i 2 ) E = -2.178*10 -18 (1/25-1/4) E = 4.578*10 -19 J
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10 For the electronic transition in the hydrogen atom from n = 2 to n = 5, calculate the frequency and wavelength of the associated radiation.
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11 Answer: E = -2.178*10 -18 (1/n f 2 - 1/n i 2 ) E = -2.178*10 -18 (1/25-1/4) E = 4.578*10 -19 J E = hν ν = 4.578*10 -19 / 6.63*10 -34 ν = 6.909*10 14 Hz c = λν λ = 3.0*10 8 / 6.909*10 14 λ = 4.3*10 -7 m
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12 T/F Within each group, ionization energy tends to increase from top to bottom.
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13 False
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14 Define ionization energy
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15 The ease with which an atom LOSES an electron Increases going up and over
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16 T/F More metallic atoms are found in the top left corner of the periodic table
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17 False More metallic elements are found in the BOTTOM left corner of the periodic table
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18 Explain what Z eff is, how it is calculated, and how it helps explain the periodic trends of Ionization Energy, Electron Affinity, and Atomic Radius.
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19 Answer:
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20 Arrange the following sets of atoms in order of increasing Ionic Size: I, Mg, O, F
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21 Mg 2+, F -, O 2-, I -
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22 Draw one example of d orbital:
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23 Answer:
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24 Give the set of four quantum numbers n, l, m l, and m s for the following electrons: The fourth electron to fall in the 3p orbital
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25 3, 1, -1, -1/2
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26 Identify the element and write its ground-state electron configuration: [Ne]3s 1 3p 2 4s 1 3d 2
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27 Sulfur [Ne] 3s 2 3p 4
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28 What is the electron configuration for Fe
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29 Answer: [Ar]4s 2 3d 6
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30 State Hund’s Rule
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31 For degenerate orbitals, the lowest energy is attained when the number of electrons with the same spin is maximized
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32 Estriol (C 18 H 24 O 3 ) is one of the three main estrogens produced by the human body. What is the molar mass of estriol?
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33 Answer: MM = 12.01*18 + 1.007*24 + 16*3 MM = 288.35 g/mol
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34 How many moles of estriol (C 18 H 24 O 3 ) are present in 2.30 mg of estriol?
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35 Answer: 2.30 mg * g * mol = 1000 mg 288.35 g 7.99*10 -6 mol
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36 How many molecules of estriol (C 18 H 24 O 3 ) are present in 2.30 mg of estriol?
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37 Answer: 2.30 mg * g * mol * 6.022*10 23 molecules = 1000 mg 288.35 g 1 mol 4.80*10 18 molecules
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38 How many hydrogen atoms are present in 2.30 mg of estriol (C 18 H 24 O 3 )?
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39 Answer: 2.30 mg * g * mol * 6.022*10 23 molecules * 24 H atoms = 1000 mg 288.35 g 1 mol1 molecule 1.15*10 20 H atoms
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40 How many protons are present in 2.30 mg of estriol (C 18 H 24 O 3 ) ?
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41 Answer: C = 6(18) prot H = 1(24) proO = 8(3) pro Total protons = 156 2.30 mg * g * mol * 6.022*10 23 molecules*156 protons = 1000 mg 288.35 g 1 mol1 molecule 7.49*10 20 protons
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42 Name the following compound: MgO
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43 Magnesium oxide
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44 Name the following compound: Cu(NO 3 ) 2
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45 Copper (II) nitrate
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46 Name the following compound: H 2 CO 3
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47 Carbonic acid
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48 Write the chemical formula for each substance mentioned. The substance phosphorus trihydride, commonly called phosphine, is a toxic gas.
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49 PH 3
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50 The following description refers to which of the following compounds? A yellow solid at room temperature and 1 atm. (A) CH 4 (B) CCl 3 F (C) H 2 S (D) H 2 O 2 (E) K 2 CrO 4
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51 (E) K 2 CrO 4
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