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Published byJeffrey Maurice Cameron Modified over 8 years ago
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Acids and Bases Chapter 19
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Ants use formic acid to alert each other of danger. Citrus acid gives OJ it’s flavor. Limestone is carved away by acid in rain to make these caves.
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What makes a solution acid or basic? Can something be neutral? Water, the most common solvent, breaks down into ions H 2 O H + + OH - The relative amounts of ions determine if a solution is acidic, basic or neutral Acidic = more H + (hydride) ions Basic = more OH - (hydroxide ion) Neutral = same amount of both (pH=7)
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Robert Boyle described differences between acids and bases Acids Contains more H+ Taste sour Corrosive to metals Changes litmus paper red Become less acidic when reacted with bases Forms hydrogen gas when reacted with metals pH 0-6.9 Bases Contains more OH- Taste Bitter Feel slippery Changes litmus paper blue Become less basic when reacted with acids pH 7.1-14
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Arrhenius acids –release hydrogen (H+) ions
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Arrhenius bases –release hydroxide (OH-) ions
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The Arrhenius theory doesn’t explain why some substances can act like a base even though they do not contain hydroxide ions Johannes Bronsted and Thomas Lowry wrote independent papers to offer another explanation of acids and bases
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Bronsted-Lowry Bronsted-Lowry Acid = any substance that can donate a hydrogen ion or a proton –Very similar to Arrhenius definition
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Bronsted-Lowry Base = any substance that can accept a hydrogen ion –Opposite of an acid –Explains why NaOH and KOH are considered bases b/c they accept a H+ from acid to form water –Also it explains why substance that do not contain OH- are still considered bases
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Conjugate Acids Conjugate acid = formed from the base by addition of a proton (H+) Base conjugate acid
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Conjugate Bases Conjugate base = formed from the acid by loss of a proton (H+) Acid conjugate base
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Conjugate acid-base pair consists of two substances related to each other by the donating and accepting of a single proton
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Water can act like both an acid and a base. When substances can act as both an acid and a base they are called amphoteric
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The idea that a base can make an acid weaker and vice versa is called neutralization NaOH + HCl NaCl + H 2 O
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