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C. Lewis Dot Diagrams zElectron Dot Diagrams – model for showing ionic and covalent bonds yshow valence e - as dots ydistribute dots like arrows in an orbital diagram X
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Gilbert Newton Lewis Invented “Electron-dot” formulas or “Lewis Structures” I’m so tired of writing all those useless inner electrons, in the Bohring models!
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C. Lewis Structures zOctet Rule yMost atoms form bonds in order to obtain 8 valence e - yFull energy level stability ~ Noble Gases Ne
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C. Lewis Structures zIonic – Show the transfer of e-
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++ -- ++ C. Covalent – Electrons shared zNonpolar Covalent - no charges zPolar Covalent - partial charges
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IIIIIIIV II. Naming Compounds Ch. 5 & 6 - Chemical Bonding
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A. Vocabulary CHEMICAL BONDS 2 nonmetals Metal + Nonmetal IONICCOVALENT CO 2 NaCl e- transferred e- shared
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A. Vocabulary CHEMICAL FORMULA Molecular Formula Unit IONICCOVALENT CO 2 NaCl
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A. Vocabulary COMPOUND Ternary Compound Binary Compound 2 elements more than 2 elements NaNO 3 NaCl
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A. Vocabulary ION Polyatomic Ion Monatomic Ion 1 atom 2 or more atoms NO 3 - Na + Cation Anion
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B. Covalent/Molecular Nomenclature zPrefix System (binary compounds) 1.Less e - neg atom comes first. Ex. CO 2 2.Add prefixes to indicate # of atoms. Omit mono- prefix on first element. Ex.Carbon Dioxide 3.Change the ending of the second element to -ide.
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PREFIX mono- di- tri- tetra- penta- hexa- hepta- octa- nona- deca- NUMBER 1 2 3 4 5 6 7 8 9 10 B. Molecular Nomenclature
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zCCl 4 zH 2 O zSF 6 ycarbon tetrachloride ydihydrogen monoxide ysulfur hexafluoride B. Molecular Nomenclature
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zarsenic trichloride zdinitrogen pentoxide ztetraphosphorus decoxide yAsCl 3 yN2O5yN2O5 yP 4 O 10 B. Molecular Nomenclature
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C. Ionic Nomenclature Ionic Formulas zWrite each ion, cation (+) first. Don’t show charges in the final formula. zOverall charge must equal zero. yIf charges cancel, just write symbols. yIf not, use subscripts to balance charges. Sodium Iodide: Na + I - NaI Calcium Bromide: Ca +2 Br - CaBr 2
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1+ 2+3+NA3-2-1- 0 C. Ionic Nomenclature
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Ionic Names zWrite the names of both ions, cation (+) first. zChange ending of monatomic ions to -ide. zPolyatomic ions have special names. Use parentheses to show more than one polyatomic ion in a formula. zStock System - Use Roman numerals to show the ion’s charge if more than one is possible for the transition metals.
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C. Ionic Nomenclature zConsider the following: yDoes it contain a polyatomic ion? x-ide, 2 elements no x-ate, -ite, 3+ elements yes yDoes it contain a Roman numeral? xCheck the table for metals not in Groups 1 or 2. yNo prefixes!
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zpotassium chloride zmagnesium nitrate zcopper(II) chloride K + Cl Mg 2+ NO 3 Cu 2+ Cl KCl Mg(NO 3 ) 2 CuCl 2 C. Ionic Nomenclature
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zMgBr 2 zNa 2 CO 3 zFeCl 3 ymagnesium bromide ysodium carbonate yiron(III) chloride C. Ionic Nomenclature
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D. Hydrates yHydrates - Ionic compounds that absorb water into their solid structure yWater can be removed by heating yAnhydrous is the opposite and means “without water”.
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D. Hydrates zFormula and name of a hydrate: CuSO 4 o 5H 2 0 Copper (II) Sulfate PentaHydrate CoCl 2 o 6H 2 0 Cobalt (II) Chloride HexaHydrate
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E. Determining Charge yFind the charge of each ion and the total number of atoms: xNa 3 PO 4 : Chg: Na +1 PO 4 -3 –Na – 3 atoms; P – 1; O – 4 atoms xFe(OH) 3 : Chg: Fe +3 OH -1 –Fe – 1 atom; O – 3; H – 3 atoms xCu(NO 3 ) 2 : Chg: Cu +2 NO 3 -1 –Cu – 1 atom; N – 2; O – 6 atoms
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