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Published byAndrew Gaines Modified over 8 years ago
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Are chemical compounds consisting of a carbonyl adjacent to an Ether linkage. They are derived by reacting an oxoacid with a hydroxyl compound.
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are ubiquitous, they are present fats and oils, pheromones, fragrances, DNA, explosives, and plastics.
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NameChemical StructureFlavor or Fragrance Propyl acetatePears Octyl acetateOranges Isoamyl acetateBanana Ethyl ButyratePineapple Butyl acetateApple Methyl trans- cinnamate Strawberry
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Esters are one of a number of compounds known collectively as ACID DERIVATIVES.
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In an ester, the hydrogen in the -COOH group is replaced by an alkyl group (or possibly some more complex hydrocarbon group).
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Example 1: Methyl Propanoate Propanoic Acid
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The hydrogen in the -COOH group is replaced by an alkyl group - in this case, a methyl group.
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1.) Methyl formate (C 2 H 4 O 2 ) Methyl methanoate 2.) Methyl propanoate (C 4 H 8 O 2 ) Methyl propionate
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3.) Propyl Formate (C 4 H 8 O 2 ) Propyl Methanoate 4.) Ethyl ethanoate (C 4 H 8 O 2 ) Ethyl acetate
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Alcoholysis of acyl chlorides and acid anhydides. Alcohols react with acyl chlorides and acid anhydrides to give esters: RCOCl + R'OH → RCO 2 R' + HCl (RCO) 2 O + R'OH → RCO 2 R' + RCO 2 H
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Transesterification Transesterification, which involves changing one ester into another one, is widely practiced: RCO 2 R' + CH 3 OH → RCO 2 CH 3 + R'OH
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Carbonylation Alkenes undergo "hydroesterification" in the presence of metal carbonyl catalysts. Esters of propionic acid are produced commercially by this method: C 2 H 4 + ROH + CO → C 2 H 5 CO 2 R
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Keywords: 1.Kinetics (Chemical) 2.Carl ‐ Zeiss spectrophotometer. KINETIC AND MECHANISTIC STUDY OF OXIDATION OF ESTER BY K2Cr2O7
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We found out that the oxidation of esters occurs in two ways: Hydrolysis followed by the oxidation of alcohol, or direct oxidation of esters. No conclusive evidence was provided iin support of either of the two pathways.
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www.chemguide.co.uk/ester#1 2272/vqw?.html www.wikipedia.org/ester
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