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Atomic Theory
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Atomic Theories Timeline
Use a graphic organizer like this to record information from this powerpoint and what you find online. You do NOT have to include Jabir nor al –Ghazali. Name Democritus Dalton Thomson Etc. Time Frame Key Points Candy Model Can you think of a candy that would be a good model for the atom according to this scientist? You only need candy models for: Democritus, Dalton, Thomson, Rutherford, Bohr, and Schrodinger.
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Earliest alchemists- 2500BC
The Egyptians were engaged in practical chemistry- metallurgy, making dyes, and producing glass. There is no reference to an atom.
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Kanada- India, 600BC earliest recorded reference to the idea of an atom that I could find
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Democritus 460 – 370 B.C. There are various basic elements from which all matter is made Everything is composed of small atoms moving in a void Some atoms are round, pointy, oily, have hooks, etc. to account for their properties Ideas rejected by leading philosophers because void = no existence
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Simplified model- what doesn’t this show that makes his model distinct from Dalton’s?
Video
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Jabir- Arabic chemist of 8th century
Considered one of the fathers of experimental chemistry but without atomisim
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Al-Ghazali in the 11th Century revived Islamic science
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Alchemy reigned in western Europe
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John Dalton 1766-1844 Introduced his ideas in 1803
Each element is composed of extremely small particles called atoms All the atoms of a given element are identical, but they differ from those of any other element Atoms are neither created nor destroyed in any chemical reaction A given compound always has the same relative numbers and kinds of atoms
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Dalton’s Theory 1. Elements are made of tiny, indivisible particles (atoms).
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Dalton’s Theory 2. An element’s atoms are identical and unique to that element. C = N = Ni = Note that real atoms are all basically the same shape and have no color.
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Dalton’s Theory 3. Atoms combine chemically in simple whole-number ratios. No half -atoms.
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Dalton’s Theory 4. Chemical reactions occur when atoms separate, join, or rearrange. Atoms CANNOT be changed into another atom. (You can not make gold out of lead.) + + + +
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Now go back and see if you can make a distinction between Dalton’s and Democritus’ models.
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J.J. Thomson Discovered electron 1897 – Cathode Ray Experiment Plum Pudding model 1904 Electrons in a soup of positive charges Discovered isotopes 1913
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JJ Thomson’s Ideas
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Experiments with Cathode Ray Tubes (late 1890s)
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Cathode Ray Tube Experiment
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Deflection of the “ray” Evidence of the electron
Video
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Thomson’s plum pudding
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A real plum pudding
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The Electron The Proton
Goldstein CRT canal rays Positive charge p+ Actual Mass: 1.67 x 10-24g Relative mass: 1 J.J. Thomson CRT experiment Negative Charge e- Actual Mass: x 10-28g Relative mass: 1/1840 the mass of proton (Millikan)
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Ernest Rutherford 1871-1937 Nucleus Theory 1910
alpha particle gold foil experiment An atom’s mass is mostly in the nucleus The nucleus has a positive charge (Moseley) Electrons in fixed orbit
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Gold Foil Experiment (1909)
Video
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Rutherford’s atom Nucleus with protons and “extra mass”
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Classic atom model
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James Chadwick 1891-1974 Worked with Rutherford
Interpreted work of the Curies Discovered Neutron 1932 Nobel Prize in Physics 1935
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Chadwick (1930) Evidence of the Neutron
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The Neutron Chadwick 1932 - nuclear bombardment No charge n0
Actual Mass: 1.67 x 10-24g Relative Mass: 1
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Niels Bohr 1885-1962 Planetary Model 1913
Nucleus surrounded by orbiting electrons at different energy levels Electrons have definite orbits Utilized Planck’s Quantum Energy theory Worked on the Manhattan Project (US atomic bomb)
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Bohr’s atom with energy levels (1913)
Video
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Bohr Model for Nitrogen
Pick A Candy!
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Quantum mechanical model
Bohr’s model was good for hydrogen, but failed with atoms with more electrons Schrodinger used new experimental results to come up with a mathematical equation that explains electron behavior NO exact paths to follow- more of a cloud where electrons may be found Video
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Ernst Schrödinger 1887-1961 Werner Heisenberg 1901-1976
Quantum Mechanical Model 1926 Electrons are in probability zones called “orbitals”, not orbits and the location cannot be pinpointed Electrons are particles and waves at the same time Developed quantum numbers based on theories of Einstein and Planck
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Schrodinger’s Model Electron probability map.
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Quantum Mechanical Theory Electron in a Hydrogen atom
Pick A Candy!
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Add two other players to this timeline- Millikan and de Broglie
Add two other players to this timeline- Millikan and de Broglie. They are in your textbook.
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Energy levels Electrons can only be at certain energy levels
Quantum- amount of energy needed to move from one energy level to the next Cannot stop between levels
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Energy levels Not evenly spaced
Higher energy levels are closer together. Higher energy levels are found further from the nucleus.
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Atomic orbitals A region of space where there is a high probability of finding an electron Defined mathematically by Schrodinger Each orbital has a different shape
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Orbital shapes s = spherical p= dumb bell on three axes
d= like a double p on three axes and an odd (one dumbbell with a donut) S, p, and d are also the names of the sublevels
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n = 2 orbitals
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3d orbital photo
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