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Single displacement reactions only occur when the displaced element is less reactive than the one replacing it. We can predict if a reaction will occur by comparing the involved elements on the activity series.
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Fe (s) + CuSO 4(aq) FeSO 4(aq) + Cu (s) iron + copper (II) sulfate iron (II) sulfate + copper This reaction occurs because iron donates its electrons more readily than copper (iron is more reactive). Fe (s) + AlCl 3(aq) No Reaction Iron is less reactive than aluminum.
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Cl 2(g) + 2NaBr (aq) 2NaCl (aq) + Br 2(g) Chlorine is more reactive than bromine, so this reaction occurs. Cl 2(g) + 2NaF (aq) no reaction Chlorine is less reactive than fluorine, so no reaction occurs. We will show that no reaction occurs by simply writing “NR” on the products side of an equation.
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Cations exchange places in aqueous solutions. General formula: AX + BY AY + BX
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A reaction may form a solid (precipitate) Cu(NO 3 ) 2(aq) + AgCl (aq) CuCl 2(aq) + AgNO 3(s) We can predict if a precipitate will form by referring to a set of solubility guidelines that have been established based on experimental results
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Anion+ Cation Solubility of Compound 1MostAlkali metal ions (Li +, K +, Rb +, Cs +, Fr + )Soluble MostHydrogen ion (H + )Soluble MostAmmonium ion (NH 4 + )Soluble 2Nitrate (NO 3 - )MostSoluble Acetate (CH 3 COO - )Ag + Low solubility Most othersSoluble 3Chloride (Cl - ) Bromide (Br - ), Iodide (I - ) Ag +, Pb +, Hg 2 +, Cu +, Tl + Low solubility All othersSoluble 4.4. Flouride (F - )Mg 2+, Ca 2+, Ba 2+, Pb 2+ Low solubility Most othersSoluble 5.5. Sulfate (SO 4 2- )Ca 2+, Sr 2+,Ba 2+, Pb 2+ Low solubility Most othersSoluble 6.6. Sulfide (S 2 - )Alkali ions and H +, NH 4 +, Be 2+, Mg 2+, Ca 2+, Sr 2+, Ba 2+ Soluble All othersLow solubility 7Hydroxide (OH - )Alkali ions and H +, NH 4 +, Sr 2+, Ba 2+, Tl + Soluble All othersLow solubility 8Phosphate (PO 4 3- )Alkali ions and H +, NH 4 + Soluble All othersLow solubility
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Magnesium chloride and lead (II) acetate form a precipitate. Predict the products and write a balanced equation identifying the precipitate.
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1. Identify the ions that make up each reactant. Magnesium chloride: Mg 2+, Cl - Lead acetate: Pb 2+, CH 3 COO - 2. Switch the pairs of ions to determine the products, and write the equation. MgCl 2(aq) + Pb(CH 3 COO) 2(aq) Mg(CH 3 COO) 2 + PbCl 2
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3. Use the solubility guidelines to determine the precipitate. Acetate is soluble with magnesium Lead (II) ions have low solubility with chloride ions. Therefore PbCl 2 is solid. MgCl 2(aq) + Pb(CH 3 COO) 2(aq) Mg(CH 3 COO) 2(aq) + PbCl 2(s)
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A reaction may form a gas NaOH (aq) + NH 4 Cl (aq) HOH (l) + NaCl (aq) + NH 3(g) A reaction may form water H 2 SO 4(aq) + 2 NaOH (aq) 2 HOH (l) + Na 2 SO 4(aq)
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If one reactant…+ the other reactant… then the products include is an aqueous salt a precipitate is an acidhas carbonate ionswater and carbon dioxide has ammonium ionshas hydroxide ionswater and ammonia is an acidhas hydroxide ionswater
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Neutralization Reactions: Specific type of double displacement reaction involving acids and bases: General Formula: acid + base salt + water Example: HCl + NaOH NaCl + HOH
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Combustion Reactions: Oxygen combines with another substance to produce energy (heat and light) and one or more oxides
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Hydrocarbon Combustion: Complete Combustion: A hydrocarbon reacts with an abundant amount of oxygen gas to produce water and carbon dioxide Incomplete Combustion: A hydrogen combustion reaction with a poor supply of oxygen which produces any combination of CO 2, H 2 O, CO and C (soot)
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Oxides and Water: Metal oxides combine with water to produce hydrogen gas and metallic hydroxides. The resulting metallic hydroxide solution is a basic solution. BaO(s) + 2 H 2 O (l) H 2 (g) + Ba(OH) 2 (aq) Na 2 O(s) + 2 H 2 O (l) H 2 (g) + 2 NaOH (aq)
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Non-metallic oxides combine with water to produce acidic solutions (oxyacids). CO 2 (g) + H 2 O (l) H 2 CO 3 (aq) P 4 O 10 (s) + 6 H 2 O (l) 4 H 3 PO 4 (aq)
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Complete worksheet on Reaction Prediction. Check your answers AFTER you have completed your work.
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