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Published byArron Wade Modified over 8 years ago
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How does metallic bonding dictate the properties of metals?
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The metal nuclei are insulated by free- roaming valence electrons.
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Metallic properties due to “sea of electrons” which insulate the positive nuclei.
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Better: steel = Fe + C harder metal Worse: too much C loss of malleability and ductility cast iron engine block Better: Bronze = Cu + Sn harder metal, decorative color Worse: impurities in metals can decrease electrical conductivity
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Atomic orbitals overlap to form new orbitals. The more atoms, the more overlapping and the more orbitals formed.
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Overlapping orbitals (close in energy) form energy bands or an electronic highway. e-
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With Mg, although there are 2 s electrons, the p orbitals are there and overlap. This gives the electrons more space to move around in. Hence, electrical conductance.
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Semi-conductors only need a little bit of thermal or other excitation to move an electron into the conduction band.
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Insulators have a large band gap and hence require a lot of energy to get an electron into the conduction band.
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The bands mean electrons can absorb almost any energy. A vibrating charge is itself an emitter of electromagnetic radiation, so the effect is to cause the metal to re-emit, or reflect, the incident light, producing the shiny appearance.
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