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1 Green Energy Today for a Better Tomorrow Renewable Hydrogen Production Using Virent's BioForming TM Process NHA Annual Hydrogen Conference 2007 Greg Keenan, VP Business Development
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22 Virent’s BioForming TM Technology Enables the Economic Use of Carbohydrates for the Production of Hydrogen Low Temperature Heterogeneous Catalysis Selectively Produces Hydrogen Feedstock Flexible
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33 BioForming Process Enabling the widespread replacement of fossil fuels by economically transforming biomass into universally used fuels and chemicals. Glycerine Sorbitol Glucose Sucrose Five Carbon Sugars Alcohols Ethylene Glycol Mixed Streams VirentAPR Temperatures ~ 260 o C Pressures < 600 psi Liquid Fuels Liquid Fuels Gasoline Diesel Chemicals Chemicals Hydrogen Propylene Glycol Gaseous Fuels Gaseous Fuels SuperNatural Gas Hydrogen
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44 Virent Energy Systems Business Overview Founded in 2002 by Dr. Jim Dumesic and Dr. Randy Cortright at UW- Madison Extensive intellectual property position in aqueous phase reforming of oxygenated hydrocarbons Commercializing products based on the revolutionary catalytic BioForming TM process Has 34 employees in 19,500 square feet of lab and office space in Madison, WI. Funding $7.8 million in government funding $9.4 million in private equity Investors Cargill Ventures Honda Strategic Ventures Venture Investors LLP
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55 Features of the BioForming Process Liquid Phase Process Pressure is built by pumping liquid. 600 PSI exit gas is easily integrated with purifiers. Simple, inexpensive system construction. Gentle environment for catalyst stability. Use of multiple high energy density, low cost, renewable feedstocks. Low Temperature (~260 o C) Process Simple, inexpensive reactor construction. Easily utilizes waste heat from other sources (ICE). Operating conditions eliminate the need for a separate shift reactor.
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66 Reforming Thermodynamics Equilibrium is favorable for reforming of oxygenated compounds at low temperatures Reforming of Hydrocarbons C n H 2n+2 + nH 2 O ↔ nCO + (2n+1)H 2 Reforming of Oxygenated Compounds C n H 2n+2 + nH 2 O ↔ nCO + (2n+1)H 2 Water-Gas Shift CO + H 2 O ↔ CO 2 + H 2
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77 Reaction Pathways
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88 SNG Catalyst Vol. %, Dry H2 Catalyst Vol. %, Dry Hydrogen35%60% Methane8%7.5% Ethane12%1.5% Propane5%0.5% CO240%30.5% APR Outlet Gas Composition Glycerol Feedstock
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99 BioForming Catalyst Development BioForming Catalyst Development 10 -9 10 -8 10 -7 10 -6 10 -5 Industrial Catalysts Measure of Productivity: Space Time Yield ( moles reactant per second per cc of reaction volume) 20022004 Current Biochemical Processes
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1010 Hydrogen Production using the BioForming Process Feedstock Flexible Simple Catalytic Process No Desulphurizer No Water Gas Shift No Steam System No Gas Compressor Energy Efficient Scalable
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1111 Hydrogen Pilot Plant
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1212 Feedstock Considerations Near Term Opportunity Feedstock- Glycerol Distributed Electricity Distributed Hydrogen Chemicals Mid to Long Term Feedstocks- Plant Based Sugars Hydrogen Chemicals Liquid Fuels
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1313 Evaporation Distillation Adsorption Up-grade MeOH Stripper Water Glycerol MeOH FFA Catalyst BioDiesel MeOH Oil / Fats Catalyst Water Bio Diesel Process MeOH Virent Pharm-Grade Glycerol BioForming Products H 2 SNG LPG Polyols Liquid Fuels Glycerol Utilization
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1414 Glycerol to Hydrogen C 3 H 8 O 3 ( l )+ 3 H 2 O ( l )→ 3 CO 2 (g) + 7 H 2 (g) Glycerol to Hydrogen (from projected overcapacity) US & EU: 50 – 100 mmkg H 2 / yr (2007 Capacity + Under Construct) Potential to serve merchant and bulk hydrogen customers 30 mmgal/yr Biodiesel Plant could produce > 1200 Nm3/hr of hydrogen One trailer of glycerol will provide the same amount of hydrogen as one LH2 trailer (~ 4000 kg)
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1515 Projected Cost of Hydrogen Using the BioForming Process Capital Cost Includes APR PSA Current Performance Glycerol 45% Yield Projected Performance 70% Yield 1500 Kg/day, 10% ROI, 10 Year Project Life
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1616 Glycerol Supply / Demand
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1717 Feedstock Considerations Near Term Opportunity Feedstock- Glycerol Distributed Electricity Distributed Hydrogen Chemicals Mid to Long Term Feedstocks- Plant Based Sugars Hydrogen Chemicals Liquid Fuels
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1818 Biomass to Hydrogen via Ethanol BiomassPretreat CookingHydrolysisFiltration Syrup Conc. FermentationDistillation Starch / Cellulosic Sugar Yeast Acids / Enzymes Conc./Evap. Reformer Hydrogen Solids DG Recycle Liquor Sugar Syrup Stillage Ethanol
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1919 Biomass to Hydrogen via the BioForming Process BiomassPretreat CookingHydrolysisFiltration Syrup Conc. Starch / Cellulosic Sugar Acids / Enzymes Virent BioForming Hydrogen Solids Sugar Syrup
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2020 Development Activities Catalyst Lifetime Selectivity Cost Reactor Design Feedstock Specification Crude Feedstock Screening Pretreatment Development
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2121 BioForming Process Summary Efficiently and economically reforms carbohydrates into a variety of hydrocarbon-based products which today are primarily produced from fossil fuels. As a catalytic process BioForming is fast, robust, and scalable for distributed or centralized production. Is feedstock flexible enabling the use of the lowest cost biomass sources available in each location.
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2222THANKS Randy Cortright Bob Rozmiarek Lucie Bednarova
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2323 Contact Information Greg Keenan Vice President Business Development Virent Energy Systems, Inc 3571 Anderson Street Madison, WI 53704 E-Mail: greg_keenan@virent.com Phone: 608-663-0228 Cell: 608-354-8240 Fax:608-663-1630 www.virent.com
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