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Physics 1202: Lecture 36 Today’s Agenda Announcements: Extra creditsExtra credits –Final-like problems –Team in class –Teams 8, 9 & 10 HW 10 due Friday next weekHW 10 due Friday next week Atomic Physics: finally !
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Atomic Physics
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Bohr’s quantum model of atom +e e r F v 1. Electron moves in circular orbits. 2. Only certain electron orbits are stable. 3. Radiation is emitted by atom when electron jumps from a more energetic orbit to a low energy orbit. 4. The size of the allowed electron orbits is determined by quantization of electron angular momentum
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Bohr’s quantum model of atom Orbits of electron in Bohr’s model of hydrogen atom. An energy level diagram for hydrogen atom Frequency of the emitted photon Dependence of the wave length
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Quantum numbers Numbers used to describe a quantum state –E n = - E 0 n -2 with E 0 = 13.6 eV –n : principal quantum number Angular momentum L –Classically, any value Quantum mechanically –Quantized (Bohr model): Discrete values –where l = 0,1,2,… and l < n
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Quantum numbers Hydrogen ground state with n=1 – l = 0,1,2,… and l < n implies l = 0 only (called s) –n = 2 implies l = 0 or 1 (called s and p) –n = 3 implies l = 0, 1, or 2 (called s, p, and d) Quantization axis –Magnetic field along z –Projection on z - l < m < + l
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Electron spin Electron has an intrinsic angular momentum: spin with m s = ± ½
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Pauli exclusion principle Wolfgang Pauli (1925): Nobel 1945 –No electron can be in the same quantum state –No more than 2 electrons in an orbital –For a given n, l, m with m s = ± ½ Explains the periodic table –Electronic configuration –Shell structure of atoms
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Periodic table Atomic structure and chemical properties –Pauli principle: atomic shell model
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X-ray emission from atoms X-ray tube –Discovered by Wilheim Röntgen (1895) –Accelerated electrons hit targets –Large potentials kV to MV
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X-ray emission from atoms Bremsstrahlung –Continuous x-ray –Electron loosing energy Minimal –When all initial K is lost
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X-ray emission from atoms K, L, etc. shells and x-ray emission –Fast electron kick inner electron out –Higher electron falls in and fill the “hole” –X-ray emitted
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X-ray emission from atoms Each element has a specific spectra min
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