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17 Temperature and Kinetic Theory Thermal Equilibrium and Temperature Gas Thermometers and Absolute Temperature The Ideal Gas Law The Kinetic Theory of Gases Hk: 15, 33, 39.
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Temperature & Energy temperature: a measurement of the average KE per molecule thermal energy: the kinetic energy resulting from the random movement of atoms and molecules absolute temperature scale: a scale in which the temperature is proportional to the thermal energy. Has true zero.
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Thermal Equilibrium thermometric property: A physical property that changes with temperature, e.g. volume. thermal equilibrium: zero net heat flow while in thermal contact 0 th Law
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0 th Law
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Celsius Fahrenheit Conversions
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Absolute Kelvin Scale
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Ideal Gases N molecules (few intermolecular collisions, no long range forces) v = average speed P due to wall-collisions (P ~ Nv/t) t = time between same-wall collision
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Ideal gas pressure
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Ideal Gas Law
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11 Gas Thermometer PV ~ NT P ~ T Gas cools, avg. KE 0, (absolute zero), P 0, ≈ -273 °C
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12 Ex. Constant Pressure process on an Ideal Gas What % increase in V occurs for an ideal gas heated from 20C to 40C? (V ~ T) (It does not double, b/c C is not a thermodynamic temperature scale) V2/V1 = T2/T1 = (273+40)/(273+20) = 1.068 6.8% increase in volume.
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Summary Thermal Equilibrium and Zeroth Law Temperature and scales and conversions Thermometric properties and thermometers Ideal Gas Law Kinetic Theory explains gas behavior in terms of Newton’s Laws of Motion. /
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The absolute temperature of a gas is most closely associated with its molecules average 1.Velocity 2.Speed 3.(Speed) 2 4.Momentum
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What happens to the pressure of an ideal gas going from state A to B? 1.Increases 2.Decreases 3.No change
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