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Bonding and Nomenclature Ionic and Covalent Bonds
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What is a chemical bond? A force that holds 2 atoms together.
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Why do atoms bond? To have 8 valence electrons.
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What are the 8 valence electrons called? An octet.
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What attracts two atoms together? Positive and negative forces attract.
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What is an ion called that has lost electrons? A cation
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Why does it lose electrons? In order to have a full valence shell.
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When an atom gain or loses electrons what does it resemble? A noble gas.
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What do metals do to have full valence shells? Form cations.
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How predictable are metals cations? Very! Use the periodic table.
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How do I use the periodic table? Group 1 +1 Group 2 +2 Group13 +3 Group 14 +4
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How do you name a cation? Its just the element name with ion at the end
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What is an example? Al +3 Na +
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What about transition metals? They lose different numbers of electrons, depending on the situation they are in.
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How do you know how many they lost? The metal will have a roman numeral after the element name.
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What is an example? Cu +2 Iron (III) ion
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What is the charge called? An oxidation number
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What is an ion that has gained electron called? An anion
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What are most nonmetals? Anions
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What about the metalloids? Above the stair step, they act more like nonmetals (anions) Under the stair step, they act more like metals (cations)
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What kinds of charges do the anions have? Group 14 -4 Group 15 -3 Group 16 -2 Group 17 -1
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How do you name anions? Drop the last part of the name and add -ide.
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What is an example? O 2- F -
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Here are all the PT anions … Hydride Carbide Nitride Oxide Fluoride Silicide Phosphide Sulfide Chloride Arsenide Selenide Bromide Telluride Iodide
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What is a polyatomic ion? They are groups of ions that gain or lose electrons as a whole Don’t EVER change their name or formula. EVER!
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Can you split up polyatomic ions? No!
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What are some examples? Sulfate (SO 4 ) -2 Sulfite (SO 3 ) -2
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Where can I find the polyatomic ions? On the back of my periodic table FOR THE TEST YOU MUST KNOW THE 12 PAI WE LEARNED BEFORE!
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NamePolyatomic IonNamePolyatomic Ion AcetateC 2 H 3 O 2 -1 HydroxideOH -1 AmmoniumNH 4 +1 HypobromiteBrO -1 BromateBrO 3 -1 HypochloriteClO -1 BromiteBrO 2 -1 NitrateNO 3 -1 CarbonateCO 3 -2 NitriteNO 2 -1 ChlorateClO 3 -1 OxalateC 2 O 4 -2 ChloriteClO 2 -1 PerbromateBrO 4 -1 ChromateCrO 4 -2 PerchlorateClO 4 -1 CyanateOCN -1 PermanganateMnO 4 -1 CyanideCN -1 PhosphatePO 4 -3 DichromateCr 2 O 7 -2 PhosphitePO 3 -3 Dihydrogen PhosphiteH 2 PO 4 -1 SelenateSeO 4 -2 BicarbonateHCO 3 -1 SulfateSO 4 -2 Hydrogen PhosphateHPO 4 -2 SulfiteSO 3 -2 Hydrogen SulfateHSO 4 -1 ThiocyanateSCN -1 Hydrogen SulfiteHSO 3 -1 ThiosulfateS 2 O 3 -2
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What does an ionic bond contain? A cation and an anion.
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How do I write an ionic chemical formula? Find the charge of the cation Find the charge of the anion Swap and drop the charges Reduce charges if possible
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The Compound end up NEUTRAL!!! The charges cancel each other out!
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Examples K and Br Ca and PO 4 -3 Rb and P Mg and S Sr and Si
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How do you name ionic formulas? Name the cation Name the anion NaCl is Sodium Chloride
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Examples Calcium Oxide Aluminum chloride Cs 2 Se InBr 3
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How do I name it if there is a PAI in the formula? Do NOT EVER change the NAME of the PAI! NEVER! Ca(OH) 2 is calcium hydroxide
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Differences in: Nitrate Nitrite Nitride
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What is special about the transition metals? You HAVE to write the oxidation number as a roman numeral between the cation and anion.
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What 2 elements are transition metal wannabes? Tin and Lead They get roman numerals too!
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Example FeCl 3 SnO Chromium (III) Telluride Molybdenum (VI) Sulfide
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Example problem Write all of the correct formulas between sulfur, sodium, chlorate, iron (II), and nitrogen.
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What happens in ionic bonds? Electrons are transferred from the cation to the anion.
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What is one property of ionic compounds? The compounds are packed into repeating patterns.
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What are these repeating patterns called? Crystal lattices.
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What is the smallest part of a crystal lattice? A formula unit Basically one of your formulas you wrote
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What else can be said about ionic bonds? They have high melting points and high boiling points compared to other bonds
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What about their strength? They are very strong compounds. They take a lot of energy to break apart.
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What else do ionic bonds do? They conduct electricity in aqueous solutions.
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What is another term for that? Electrolytes
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How else do atoms find an octet? They make covalent bonds.
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What is a covalent bond? When atoms share electrons to make an octet.
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What makes up a covalent bond? Two nonmetals.
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Can two metals ever make a bond? No
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Why not? They form an alloy instead of a chemical bond.
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What is an alloy? A mixture of 2 or more metals.
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What is formed when you have a covalent bond? A molecule
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What are the most common covalent bonds? Diatomic elements.
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What is a diatomic element? One that bonds to itself.
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What are the diatomic elements? BrINClHOF Bromine, Iodine, Nitrogen, Chlorine, Hydrogen, Oxygen, Fluorine
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How are they always written? Br 2, I 2, N 2, Cl 2, H 2, O 2, F 2
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How are they named? Just by their names, even though there are 2 of them.
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Examples of diatomic compounds: Hydrogen Br 2 Iodine
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How are covalent bonds named? By using prefixes.
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What are the prefixes? Mono, di, tri, tetra, penta, hexa, hepta, octa, nona, deca
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What is the first rule? The first element stays the same, the second ends in –ide.
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What is the second rule? Add the prefixes to tell how many of each element are present.
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What is the third rule? Never begin a molecule name with mono-.
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Do I reduce a covalent compound? No! Never!
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What is an example? C 5 H 7 NO PO 4 difluorine monosulfide
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What if the compound begins with H? The compound is an acid. HCl HClO 3 H 2 S
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How are acids named? It depends on their ending or what is bonding.
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What is an –ide acid? One that contains hydrogen and an anion that ends in -ide
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How are –ide acids named? Start with hydro- Write the “root” of the anion End with –ic Acid HCl is Hydrochloric acid
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What are some odd roots for anions? P becomes phosphoric S becomes sulfuric C becomes carbonic For the rest, where you would write –ide put –ic instead.
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Examples H 2 S H 3 P hydronitric acid hydrobromic acid Hydrocyanic acid
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What about naming –ate and –ite acids? Do not start with hydro- If it ends in –ate, substitute –ic Acid If it ends in –ite, substitute –ous Acid H 2 CO 3 is Carbonic Acid HClO 2 is Chlorous Acid
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What are the 2 odd polyatomic ions? Phosphate/ite and sulfate/ite. Becomes: phosphoric or phosphorous Sulfuric or sulfurous H 2 SO 4 is Sulfuric Acid H 3 PO 3 is Phosphorous Acid
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Examples HClO 4 HClO 3 Bromic acid Cyanic acid
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What are some characteristics of covalent bonds? They are relatively weak bonds. They are not strong as solids.
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What else? They have low melting and boiling points
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Are they electrolytes? No
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Molecular Shape
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What is an electron dot structure? It is a way of showing the valence electrons bonding and lone pairs of electrons.
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What is a lone pair? A pair of electrons in the valence shell that are not bonded.
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How many bonds can be in between covalent compounds? One, two or three
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What is a single bond? Two bonded elements sharing one pair of electrons
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What is a double bond? Two bonded elements sharing 2 pair of electrons.
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What is a triple bond? Two bonded elements sharing three pairs of electrons.
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What is VSEPR? Valence Shell Electron Pair Repulsion It helps us to know the shape of compounds, as electrons try to spread as far away from one another as possible.
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What are the shapes we will study? Linear Tetrahedral Trigonal Planar Bent Pyramidal
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What is the first shape? Linear
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What is a linear molecule made of? Contain two atoms, but even some with three atoms can be linear
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What is another shape? Trigonal Planar A shape that is flat and triangular in shape, on a single plane in space
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What is a trigonal planar molecule made up of? Molecules with three atoms, or two atoms and a lone pair, surrounding a central atom on one plane
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What is another shape? Tetrahedral A shape that has four surfaces, such as a pyramid, 3-D in space
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What makes up a tetrahedral molecule? Molecules contain four atoms that surround a central atom
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What is yet another shape? Pyramidal Similar to tetrahedral
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What is a pyramidal molecule made up of? Three atoms around a central atom and ONE lone pair
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What is the last molecular shape? Bent Similar to tetrahedral
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What makes up a bent molecule? Two atoms around a central atom and TWO lone pairs
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LinearHas only 2 bonds Has only 2 atoms Number of Bonds Around Central Atom Number of Lone Pairs on Central Atom Trigonal Planar3232 0101 Tetrahedral40 Pyramidal31 Bent22
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What is polarity? When one atom is more electronegative, so it does not share electrons fairly.
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What is a polar molecule? They do not share equally When one atom has a difference of EN of 0.4-1.7
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What is a non polar molecule? One in which the atoms share equally. EN is less than 0.4
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What is an ionic bond? A molecule that does not share, it steals electrons. EN is more than 1.7
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Where do I find these electronegativities? In a chart.
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Electronegativities
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What happens with molecular shape and polarity? If the shape is symmetrical, the molecule is NON POLAR
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What do we do with polarity? It helps us to figure out if things will dissolve into one another.
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What is the rule? The “ like dissolves like ” rule.
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What polarity is water? Polar
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