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Chapter 4: Aromatic Compounds Bitter almonds are the source of the aromatic compound benzaldehyde.

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Presentation on theme: "Chapter 4: Aromatic Compounds Bitter almonds are the source of the aromatic compound benzaldehyde."— Presentation transcript:

1 Chapter 4: Aromatic Compounds Bitter almonds are the source of the aromatic compound benzaldehyde

2 Sources of Benzene

3 Some Facts About Benzene Reacts mainly by substitution

4 Friedrich August Kekule’

5 The Orbital Model for Benzene Symbols for Benzene

6 Nomenclature of Aromatic Compounds Monosubstituted benzenes with common names

7 Monosubstituted benzenes that do not have common names

8 When two substituents are present, we use prefixes ortho-, meta-, and para-, usually abbreviated as o-, m-, and p-, respectively.

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10 For more than two substituents, their positions are designated by numbering the ring.

11 Aromatic hydrocarbons, as a class called Arenes (Ar) the aryl groups are therefore aromatic substituents.

12 The symbol Ph is sometimes used as an abbreviation for phenyl group

13 Name the following structures

14 The Resonance Energy of Benzene

15 Electrophilic Aromatic Substitution

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19 The Mechanisms of Electrophilic Substitutions

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24 Nitration

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26 sulfonation

27 Alkylation and Acylation (Friedel-Crafts reaction)

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29 Vitamin E- (TCP and TCT

30 Ring-Activating and ring-Deactivating Substituents

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32 Ortho, Para-Directing and Meta-Directing Groups

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34 Ortho, Para-Directing Groups

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42 Importance of Directing Effects in Synthesis

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44 Polycyclic Aromatic Hydrocarbons

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46 Fused polycyclic hydrocarbons

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