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Published byEmma Stevenson Modified over 8 years ago
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Equilibrium is reached in a closed system when the rates of the forward and the backward reaction are equal. The Equilibrium law describes how the equilibrium constant (K c ) can be determined for a particular chemical equation. The magnitude of the equilibrium constant indicates the extent of a reaction at equilibrium and is temperature dependent. The reaction quotient(Q) measures relative amount of product and reactants present during a reaction at a particular point in time. Q is the equilibrium expression with non-equilibrium concentrations. This changes with changes in concentration, pressure, and temperature. A catalyst has no effect on the position of equilibrium of the equilibrium constant.
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In a ‘traditional’ reaction, all the reactants get turned into products (assuming no excess) In an equilibrium reaction this is not the case, and the reaction sort of ‘stops’ part way through REACTANTSPRODUCTS ‘TRADITIONAL’ EQUILIBRIUM
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Equilibrium reactions are written using a double arrow Each of the arrows only has a single-sided head The unit will make a lot of reference to the rate of the: ‘forward reaction’ (reactants becoming products) ‘back reaction’ (products becoming reactants) REACTANTSPRODUCTS
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The concentration of reactants and products is constant They are NOT equal to each other They are just not changing The rate of the forward reaction is equal to the rate of the back reaction At equilibrium these are not zero…even though it looks like it on the graph
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The reaction hasn’t stopped, it is still going, but the rate of the forward and back reactions are equal, so there is no overall change. This is different to a static equilibrium (for example a see-saw) where there is no change at all.
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The equilibrium constant describes where the position of equilibrium lies: Minimum: 0, maximum: ∞, half-way: 1 Greater than 1: products favoured Less than 1: reactants favoured For the reaction: wA + xB ⇌ yC + zD
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Complete the paper equilibrium activity.paper equilibrium activity Record your observations in a table like this: StepWhite squares Black squares Forward rate Backward rate Equilibrium constant 01000n/a ∞ 1 2 …
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