1. «ZEOFORMING» TECHNOLOGY
«HIMMASH-APPARAT»
«STC «ZEOSIT»
«ZEOFORMING» TECHNOLOGY
Sortable engine fuels highly effective production from virgin naphtha fraction and gas condensate
2015

2. Index «Zeoforming» technology. Advantages 3
«Zeoforming» process technological scheme advantages
Raw material processing into engine fuels with «Zeoforming» process 5
Design technology scheme: Reactor unit 6
Design technology scheme: Stabilization and benzine extraction unit 7
Commercial gasoline production without additional technological units 8
Automobile gasoline characteristics with «Zeoforming» technology 9
Cost-effective and eco-friendly zeolite catalyst KN
Chemical principles of «Zeoforming» process
Succesful «Zeoforming» process implementation stages 12
Working units under «Zeoforming» technology
Positive factors at «Zeoforming» implementation in small refinery plant construction 14
Complex project realization scheme
Contact details

3. «Zeoforming» technology is: «Zeoforming» technology advantages:
Cost-effective way to manufacture high octane benzine from straight-run low octane fractions.
High octane gasoline Regular-92 to Premium-95 according to GOST and GOST without any additives or compounding manufacturing.
Processing depth increase at minimum investments.
«Zeoforming» technology advantages:
Equipment technology scheme ease, low capital construction costs.
Commercial benzine manufacturing from straight-run without additional technology units used.
Cost-effective and eco-friendly catalyst KN-30.

4. «Zeoforming» process technological scheme advantages
Process technology ease and mode regulation, fast and easy mode change to produce other gasoline type, class.
Process soft conditionsТ = °С, Р =5-15 atm.
Possible to implement at separate engine fuels units and in existing petrol-, gas-, chemical complexes.
Unit operation independence allows to use at difficult grounds, far from oil and gas condensate extraction fields. 4

5. Oil (after crude desalter unit) or Gas condensate
Oil or gas condensate processing into engine fuels with «Zeoforming» process АТ
Zeoforming
Straight-run gasoline
Oil (after crude desalter unit) or Gas condensate
Diesel fuel
High octane gasoline
LPG
Mazute
Product unit 5

6. Design technology scheme: Reactor unit
Fraction >200C to storage
To burner
To raw storage 6

7. Design technology scheme: Stabilization and benzine extraction unit
LPG output
To burner
Benzine output 7

8. Commercial gasoline production without additional technological units:
No need in compounding.
No need in additional high octane benzine manufacturing units.
No need in hydrogen production unit.
«Zeoforming» unit output gasoline is commercial and corresponds to GOST and GOST
Low capital costs:
No need in hydrogen production unit.
No need in hydrogen circulation and compressor, auxiliary compression and separation equipment.
Relatively low process pressure allows to significantly lower equipment metal capacity.
Unit construction costs:
Unit capacity
Cost, million US Dollars
«Zeoforming»
«Reforming»
50 thousand tones/year*
10-8
20-15
100 thousand tones/year
12-10
22-21
* Unit similar to Glimar petroleum plant, Poland. 8

9. Automobile gasoline characteristics with «Zeoforming» technology
Not more % mass.
<0,015-0,001% mass. (Euro-3 – Euro-5)
Sulfur presence in benzine
- At fraction оС
- At fraction оС
72-85%
75-90%
68-82%
70-85%
«Premium-95»
«Regular-92»
less % mass.
Not limited
Raw material sulfur allowance
Gasoline output depends on compounding
Automobile gasoline:
Target product output:
5-10 % vol.
% vol.
Benzole
High octane aromatic benzine, needs compounding.
High octane benzine, ready for use.
Second target product is liquefied hydrocarbon gas.
Final product
Containing Pt, Pd and other heavy metals
No contains of noble metals, eco-friendly.
Catalyst
Hydrocarbon fractions С6 –180оС; or
fractions оС (naphthenic base)
Hydrocarbon fractions C5 –( оС ).
Olefin containing gases. Oxygen containing combinations.
Raw material
Needed -
Raw material hydro cleaning
Hydrogen unit
15-35
5-15
Pressure, atm.
Reaction temperature, °С
Reforming
Zeoforming
Parameters 9

10. Cost-effective and eco-friendly zeolite catalyst KN-30
Catalyst poison resistant.
Noble metals absence reduce costs.
Eco-friendly easy utilizing.
Possible to manufacture at several Russian catalyst plants.
Service support during activation and all operation cycle. TC
For use in «Zeoforming» process, developed by ZAO «STC «Zeosit».
Manufactured under patents №№ ,
, , , ,
Patent owner - ZAO «STC «Zeosit».
Operation period
before recovery:
hours.
Total operation time:
~ hours
KN-30 catalyst is used to produce high octane benzines (components) from low octane benzine fractions of different origin (gas benzines, gas condensates, oils), complying with the Technical Code. 10

11. Chemical principles of «Zeoforming» process Aromatic hydrocarbons
General process to acquire high octane benzine fractions from hydrocarbons, boiling at оС, on zeolite KH-30 type catalysts includes several consequent and parallel chemical acid-base reactions, progressing by carbon-ion mechanism. There are two stages according to the scheme below: I
Paraffins
+ Olefins
Paraffins II
Aromatic hydrocarbons
Paraffins С2-С6 + I
Naphtenes
Olefins II
At stage (I) there are splitting reactions of C-C hydrocarbons connection making intermediate olefin fractions with high endoenergic heat effect.
At next stage (II), resulting from hydrogen disproportionation in olefins, followed by transmuting of olefins into paraffin and aromatic hydrocarbons, going with high exothermic reaction heat effect. 11

12. Succesful «Zeoforming» process implementation stages
Lab research
Pilot stage
Industrial test stage
Industrial use 12

13. Working units under «Zeoforming» technology
Nizhnevartovsk Gas Refinery (5 thousand t/year) Nizhnevartovsk, Russia, 1992
OJSC «Sosnogorsk Gas Refinery» (30 thousand t/year)
Sosnogorsk, Russia, 1998
«Glimar Refinery» (50 thousand t/year)
Gorlice, Poland, 1997
Material:
Stable gas benzine. Target product:
Automobile gasoline 80.
Material:
Straight-run benzine fractions of
gas condensate. Target product:
Automobile gasoline 80.
Material:
Straight-run benzine of different oils.
Target product:
Automobile gasoline Eurosuper-95, liquefied gas.
А 150 thousand t/year Zeoforming unit is currently being developed in Kazakhstan 13

14. Positive factors at «Zeoforming» implementation in small petroleum plant construction:
High octane benzines production supplies.
Refining depth increase.
Lower region energy dependence on petrol products supplies from other areas.
Lower capital export to purchase automobile fuels.
Better automobile fuels supplies for area customers.
Lower fuel transportation costs.
Additional working places.
Industrial area development acceleration. 14

15. Complex project realization scheme
License agreement was signed in 2014 between ZAO «VNIINEFTEMASH» and ZAO «STC «Zeosit» to implement unique technologies in cooperation.
ZAO «STC «Zeosit»
Is high octane benzines production technological processes developer and licenser, makes project design and author supervision;
ZAO «VNIINEFTEMASH»
Can offer following services complex in design:
Design works:
- project documentation design;
- project expertise;
- working documents design.
Equipment manufacturing and supply.
Chief mounting and start-up works.
EPC-contract scheme possible. 15

16. «HIMMASH-APPARAT», LLC Ryazansky prospect 24, bld 2
109248, Moscow, Russia
+7 (495)
www. him-apparat.ru
ZAO «STC «Zeosit»
Akademika Lavrent’eva prospect, 6
630090, Novosibirsk-90, Russia
+7 (383) 17