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Paint Analysis
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What crimes involve paint?
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Hit and Run Burglary Painting forgery
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Paint Analysis Comparative studies to see if from common source
Paint Chip On Victim Suspect Car May be able to determine color, make and model of car No Suspect Car Paint Chip On Victim
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What is Paint?
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Paint= Mixture of pigments (Color) Additives Binder Compound
Solvent (Evaporates when paint applied)
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Auto Paint Electrocoat Primer: Onto steel Resists Corrosion
Black to Grey
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Auto Paint 2. Primer Surfacer: Smooth out surface, hides seams
Light Grey or Red
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Auto Paint 3. Basecoat: a.k.a. Colorcoat “eye appeal”
may have metal flakes
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Auto Paint 4. Clearcoat: Unpigmented Glossy
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Paint As Evidence Individual Characteristics or Class Characteristics?
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Class unless…… Multilayered Paint Chip Custom Finishes
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Problem A single type of car paint can be on many different models
For a given color/type of paint, batches don’t vary much in composition Binder chemical composition may vary very slightly from batch to batch What to do? What to do?
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Paint Analysis Perform pyrolysis on paint sample coupled with gas chromatography Polarized light microscopy Emission spectroscopy Neutron activation X-ray diffraction X-ray spectroscopy
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PDQ (Paint Data Query) Law enforcement database of specific paint formulas added onto cars since 1974
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Art Fraud and Paint Need to show materials in a painting were unavailable in the real time that they were made
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Case Study “Shroud of Turin” Christ’s Death Shroud? Christ's blood on
linen?
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Human dried blood on linen (Brown)
“Christ” blood on linen (Red) 1000X-Real blood (Brown) 1000X- Red Ochre Pigments
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Hans Van Meegeren Traded fake paintings for genuine artwork in the 1930s
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Christ and the Disciples at Emmaus
Supposedly an undiscovered masterpiece by Vermeer
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Johannes Vermeer Last Supper supposedly by Vermeer
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Technique Used a synthetic phenolformaldehyde resin - known as Albertol or Ambertol - dissolved in a spirit such as turpentine and/or an essential (i.e., non-fatty) oil such as oil of lilac or oil of lavender, which would then be mixed with hand-ground powder pigments.
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He heated the resin transforming its chemical composition so that chemical tests would show it is really not the chemical it actually was He painted over low value17th century paintings. He scraped away old painting
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“Leveling Paint”
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