1. Photocatalysis based on TiO2
Dr. Cao yang
Supervised by Pro. Mo

2. Contents Photocatalysis Background of TiO2
TiO2 Photocatalytic water splitting
TiO2 Photocatalytic organic reaction
TiO2 electron storage
Summary & perspective

3. solar environmental catalysts
Photocatalysis
CO2 conversion in Plant
Water splitting
solar environmental catalysts
Photo synthesis
A. Kudo* and Y. Miseki, Chem. Soc. Rev., 2009, 38,

4. Photo catalytic ability
Photocatalysis
Photo catalytic ability
Edit by Jin-An Wang et. al., Advanced Catalytic Materials Photocatalysis and Other Current Trends., publishes on Feb. 3, (Ch 7, P 170).

5. Photocatalysis Water splitting Learn from nature “Artificial leaf”
A. Kudo* and Y. Miseki, Chem. Soc. Rev., 2009, 38,

6. Solar environmental catalysts
Photocatalysis
Solar environmental catalysts
CO2 + H2O
Edited by Jin-An Wang et. al., Advanced Catalytic Materials Photocatalysis and Other Current Trends., publishes on Feb. 3, (Ch 13, P 360).

7. Photocatalysis Photo synthesis
D. Kim, P. D. Yang* et. al., Angew. Chem. Int. Ed., 2015, 54,

8. Photocatalysis Band gap ruling
A. Kudo* and Y. Miseki, Chem. Soc. Rev., 2009, 38,

9. Photocatalysis Elements ruling
A. Kudo* and Y. Miseki, Chem. Soc. Rev., 2009, 38,

10. Background of TiO2
TiO2: high chemical and optical stability, nontoxicity, low cost,and corrosion resistance.
Edited by Jin-An Wang et. al., Advanced Catalytic Materials Photocatalysis and Other
Current Trends., publishes on Feb. 3, 2016.
J. Schneider*, D. W. Bahnemann* et. al., Chem. Rev., 2014, 114,

11. TiO2 photo synthesis TiO2 aerobic oxidation system
Q. Wang, J. Zhao* et. al., Angew. Chem. Int. Ed., 2010, 49,
X. Liang, J Zhao* et. al., Acc. Chem. Res., 2014, 47,

12. TiO2 photo synthesis Oxidation of Amine to imine system
N. Li, C. Chen* et. al., Chem. Commun., 2013, 49,
X. Liang, J Zhao* et. al., Acc. Chem. Res., 2014, 47,

13. TiO2 photo synthesis Oxidation of cyclohexane system ATR FT-IR study:
A. R. Almeida, G. Mul* et. al., J. Phys. Chem. C, 2008, 112,
A. R. Almeida , G. Mul* et. al., J. Phys. Chem. C, 2011, 115,
X. Liang, J. Zhao* et. al., Acc. Chem. Res., 2014, 47,

14. TiO2 photo synthesis Dye/TiO2/TEMPO system (visible light>450 nm)
M. Zhang, J. Zhao* et. al., Angew. Chem. Int. Ed., 2008, 47,
X. Liang, J. Zhao* et. al., Acc. Chem. Res., 2014, 47,

15. TiO2 electron storage TiO2 with various color
W. Wang, C. Lu* et. al., Applied Catalysis B: Environmental, 2012, 127,
X. Yu, Y. K. Kim* et. al., ACS Catal., 2013, 3, ; Nano Lett., 2011, 11,

16. TiO2 electron storage UV induced electron storage TiO2 ZnO
Joel N. Schrauben, James M. Mayer* et. al., Science, 2012, 336,

17. TiO2 electron storage TiO2:Sb/Cr system for longer electron life time
T. Ikeda, H. Onishi* et. al., J. Phys. Chem. C, 2008, 112,

18. TiO2 electron storage TiO2:La system for longer electron life time
A. Yamakata* et. al., J. Phys. Chem. B, 2003, 51,

19. TiO2 electron storage TiO2-x system TiO2 Black TiO2-x
Z. Wang, F. Huang* et. al., Energy Environ. Sci., 2013, 6,

20. Summary & perspective Electron could be stored in TiO2.
The photocatalyst can be designed to use the hole(h+) to
catalyse the reaction.
The photocatalytic system could accelerate the working
efficiency.