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Molecular Spectroscopy
박영동 교수
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Atomic Age
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원자 시대
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화학혁명기 이후의 한국( ) 출처: 위키백과사전 한국사 연표에서
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the electromagnetic spectrum
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Interactions, Materials
Atoms Molecules Crystals and Extended Materials Nuclei in out1 out2
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Worked example 3.1 Question. A diffraction grating has a ruled area that is cm wide, has grooves per mm and is blazed at an angle of 45.00°. (a) What is the wavelength of radiation diffracted at the blaze angle in the first, fourth and ninth orders? (b) What is the resolving power in these orders? (c) What is the resolution in terms of wavelength (nm), wavenumber (cm-1) and frequency (GHz) in the ninth order at 300 nm? ∅=45° 104.0 mm
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Absorption cell window
Table 3.1 Elements of an absorption experiment in various regions of the spectrum Region Source Absorption cell window Dispersing element Detector Microwave Klystron; backward wave oscillator Mica None Crystal diode Millimetre wave Klyston (frequency multiplied); backward wave oscillator Mica; polymer Crystal diode; Golay cell; thermocouple; bolometer; pyroelectric Far-infrared Mercury arc Polymer Grating; interferometer Golay cell; thermocouple;b olometer; pyroelectric Mid- and near- infrared Nernst filament; globar NaCl or KBr Golay cell; thermocouple; bolometer; pyroelectric; photoconductive semiconductor Visible Tungsten filament; xenon arc Glass Prism; grating; interferometer Photomultiplier; photodiode; photographic plate Near-ultraviolet Deuterium discharge; xenon arc Quartz Photomultiplier; photodiode; photographic plate Far-ultraviolet Microwave discharge in noble gases; Lyman discharge LiF (or no windows) Grating
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Figure 3.17 The Czerny–Turner grating mounting
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Attenuated total reflectance(ATR) spectroscopy and reflection–absorption infrared spectroscopy(RAIRS) Figure 3.18 Total reflection of radiation in a medium of refractive index n2 by a thin film of refractive index n1, where n2 >> n1
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Figure 3.20 The principle of atomic absorption spectroscopy(AAS)
λ2 λ1
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Figure 3.21 A plasma torch for inductively coupled plasma atomic emission spectroscopy(ICP-AES)
T = 7000–8000 K,
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