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Introduction Chemistry
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Introduction Safety Rules and Contract-see handout Safety Contract and 30 lab hour letter must be returned, signed by a parent/guardian by Equipment-see handout 3. Precision vs. Accuracy Metric System 5. Dimensional Analysis Significant Figures a. Addition and Subtraction b. Multiplication and Division % error-Table T Density-Table T Graphing
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You are expected to follow all safety rules at ALL times whether
in the classroom area or in the laboratory area. Before we begin any lab, you must have your apron and safety goggles on. Safety goggles and aprons are the LAST pieces of equipment that we remove after a lab. You must be completely cleaned up and ready to sit down before they are removed. You must be able to identify the safety equipment as noted in class. You will take a safety lab quiz which you MUST get every question correct. You will continue to take it until you answer all questions correctly. Each additional time you take it, you will only be able to score a 90, then an 80, then a 70 and so forth. Therefore, it is to your advantage to get all answers correct the first time and score a 100.
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Two words which we use interchangeably are precision
and accuracy. Theoretically, they have very different meanings. Precision- Describes the closeness, or reproducibility, of a set of measurements taken under the same conditions Accuracy- The closeness of a measurement to the true value of what is being measured See the duck handout in your packet
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Four students perform experiments to determine the density of
sulfur. The accepted density of sulfur is 2.06 g/cm3. Which set of data is precise and accurate? precise but not accurate? not precise but accurate? neither precise nor accurate? IV I II III 2.02 2.07 2.00 2.03 1.08 3.69 0.76 2.76 2.06 2.05 3.00 3.01 2.99 3.02 Neither precise nor accurate Precise & accurate Precise but not accurate Not precise but accurate
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Metric System Is an international system of measurement. The US is the only industrialized country that is not officially using the metric system. The other countries that do not use the metric are Liberia (W. Africa) and Myanmar (SE Asia). The nice thing about the metric system is that it is based on the number 10 and therefore just requires moving the decimal point to make conversions. Base Units Mass- Gram (g) Length- Meter (m) Heat- Joule (j) Volume- Liter (L)
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Kilo Hecto Deka Base Deci Centi Milli 3400 34000 340000 3.4 34 340 If you are moving to the right, move the decimal pt. to the right If you are moving to the left, move the decimal pt. to the left .065 .65 6.5 65 650 6500 65000 .142 1.42 14.2 142 1420 14200 142000 .00029 .0029 .029 .29 2.9 29 1.75 17.5 175 1750 17500 175000
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Move decimal pt. to the left, number gets smaller
Kilo Hecto Deka Base Deci Centi Milli 13 130 1300 13000 130000 0.0087 0.087 0.87 5.84 58.4 584 5840 58400 584000 811.89 8119.0 .81189 8.1189 81.189 2.692 26.92 2692 269.2 26920 269200 .74752 7.4752 74.752 747.52 7475.2 74752 Move decimal pt. to the left, number gets smaller Move decimal pt. to the right, number gets larger
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Dimensional Analysis aka Factor Label
A way to analyze and solve problems using the units or dimensions, of the measurements. Keep the conversion table in your packet in front of you. You will not have to memorize these conversions. For any test or quiz, you will have a clean copy of it in front of you! It is a system of cancelling units of equivalent measures 6 inches ? yards 6 inches x 1 foot 12 in x 1 yard 3 feet 6 inches x 1 foot 12 in / x 1 yard 3 feet / = .17 yd / /
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Significant Figures The significant figures in a measurement include all of the digits that are known, plus a last digit that is estimated Measurements must always be reported to the correct number of significant figures because calculated answers often depend on the number of significant figures in the values in the calculation To count the number of significant figures in a number, use the Atlantic-Pacific Rule If the decimal point is absent (Atlantic) start on the right side of the number. Do not count until you reach the first non-zero digit. Once you start counting, don’t stop until the number ends. If the decimal point is present (Pacific) start on the left side of the number. Do not count until you reach the first non-zero digit. Once you start counting, don’t stop until the number ends.
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Pacific Ocean Atlantic Ocean Decimal point absent Decimal point present
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3000- 1 sf 5 sf 3000.- 4 sf 1 sf
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Addition and Subtraction with sig. figs.
Answer should have the same number of DECIMAL PLACES as the measurement with the least number of decimal places Ex.: 349.0 2 decimal places 1 decimal place 2 decimal places 369.76 Answer can only have 1 decimal place Answer:
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Multiplication and Division of Sig. Figs.
Need to round the answer to the same number of significant figures as the measurement with the least number of significant figures Ex.: (2.10)(0.70) = 1.47 3 sf 2 sf Answer can only have 2 sig figs. 1.5
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% Error The equation can be found on Table T The percent that a measured value differs from the accepted value Measured (experimental) – accepted (true) x 100 = accepted (true) Jenn thought she received a 90 on her chemistry exam but when the test was returned, she got an 85. What was her percent error? x = 85 5.88 %
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On the same chemistry exam, Sal thought he got a 74 but when the test was returned, he got a 89. What was his percent error? 74 – 89 x 100 = 89 % What does a “+” percent error mean? The measured value is greater than the accepted value What does a “–” percent error mean? The measured value is less than the accepted value
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Density The ratio of the mass of an object to its volume Formula is on Table T Density = mass volume Mass is obtained through use of the electronic balance Volume is obtained 1 of 2 ways 1. Direct measurement (L x W x H)-look for units cm3 2. Water Displacement (final vol – initial vol)-look for units mL
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Volume of an irregular shaped object through water displacement
1. Find the mass of the irregular shaped object 2. Fill a graduated cylinder with water and record the volume 3. Carefully put the object into the graduate 4. Record the volume of the water with the object in the graduate Subtract the final vol (step # 4) from the initial vol (step # 2) This is the volume of the irregular shaped object Why is it important to mass the object before finding its volume? The water from finding its volume will add mass to the object
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Properties used to describe matter are both intensive and extensive
Extensive property- A property that depends on the amount of matter in the sample Intensive property- A property that does not depend on the amount of matter in the sample
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What are some intensive & extensive properties?
odor mass density volume boiling point length color weight melting point texture conductivity luster ductility malleability hardness
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Graphing Rules for graphs 1. All graphs are done on a full sheet of paper 2. Never use the back of the graph paper 3. Graphs are always done in pencil 4. Draw each axis with a ruler 5. Label each axis and include units if necessary If more than one piece of information is being graphed on the same graph, include a key 7. The spacing on each axis must be consistent 8. Each graph must have a title
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What information goes on the x-axis?
What information goes on the y-axis? Independent variable-the variable that is changed during an experiment. AKA manipulated variable Dependent variable-the variable that is observed during an experiment. AKA responding variable The independent variable ALWAYS is on the x-axis The dependent variable ALWAYS is on the y-axis.
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In science, most numbers that are reported need units
It is not enough to report a number as 54 Did you mean 54 g? 54 mg? Most numbers need units to ensure that all work is accurate Look at what an error can lead to
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