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Solid and Hazardous Waste
Chapter 21
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Case Study: Love Canal, NY
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Core Case Study: E-waste—An Exploding Problem (1)
Electronic waste, e-waste: fastest growing solid waste problem Composition includes High-quality plastics Valuable metals Toxic and hazardous pollutants
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Core Case Study: E-waste—An Exploding Problem (3)
What should be done? Recycle E-cycle Reuse Prevention approach: remove the toxic materials
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Rapidly Growing E-Waste from Discarded Computers and Other Electronics
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21-1 What Are Solid Waste and Hazardous Waste, and Why Are They Problems?
Concept Solid waste represents pollution and unnecessary waste of resources, and hazardous waste contributes to pollution, natural capital degradation, health problems, and premature deaths.
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Case Study: Love Canal, NY
1980: Comprehensive Environmental, Compensation, and Liability Act (CERCLA), or Superfund Polluters pay for cleanup (the idea) Tax payers foot the bill for cleanup (reality) Pace of cleanup has slowed
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We Throw Away Huge Amounts of Useful Things and Hazardous Materials (1)
Solid waste Industrial solid – comes from industry Municipal solid waste (MSW) – “trash” Hazardous, toxic, waste – threatens human health or the environment
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Hazardous Waste Hazardous wastes can be: Examples of hazardous waste:
Poisonous Chemically reactive Flammable Examples of hazardous waste: Organic compounds Toxic heavy metals Radioactive waste
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Yucca Mountain
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Yucca Mountain
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Waste Isolation Pilot Plant (WIPP)
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We Throw Away Huge Amounts of Useful Things and Hazardous Materials (2)
80–90% of hazardous wastes produced by developed countries Why reduce solid wastes? ¾ of the materials are an unnecessary waste of the earth's resources Huge amounts of air pollution, greenhouse gases, and water pollution
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Natural Capital Degradation: Solid Wastes Polluting a River in Indonesia
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Solid Waste in the United States
Leader in solid waste problem What is thrown away? Leader in trash production, by weight, per person Recycling is helping
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Hundreds of Millions of Discarded Tires in a Dump in Colorado, U.S.
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We Can Burn or Bury Solid Waste or Produce Less of It
Waste Management Waste Reduction Integrated waste management Uses a variety of strategies
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Integrated Waste Management
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Processing and manufacturing Products
Raw materials Processing and manufacturing Products Solid and hazardous wastes generated during the manufacturing process Waste generated by households and businesses Figure 21.5 Integrated waste management: wastes are reduced through recycling, reuse, and composting or managed by burying them in landfills or incinerating them. Most countries rely primarily on burial and incineration. Question: What happens to the solid waste you produce? Food/yard waste Remaining mixed waste Plastic Glass Metal Paper Hazardous waste To manufacturers for reuse or for recycling Compost Hazardous waste management Incinerator Landfill Fertilizer Fig. 21-5, p. 565
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Integrated Waste Management: Priorities for Dealing with Solid Waste
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We Can Cut Solid Wastes by Reducing, Reusing, and Recycling (1)
Waste reduction is based on Reduce Reuse Recycle
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7 strategies industries and communities can use to reduce resource use, waste, and pollution
Redesign manufacturing processes and products to use less material and energy Redesign manufacturing process to produce less waste and pollution (ecoindustrial revolution) Develop products that are easy to repair, reuse, remanufacture, compost, or recycle. Eliminate or reduce unnecessary packaging Use fee-per-bag waste collection systems Establish cradle-to-grave responsibility laws Restructure urban transportation systems
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Milkman – 1950s & 60s
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“If only nature would find a way to cover these oranges so we didn't need to waste so much plastic on them”
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What Can You Do? Solid Waste
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Reuse: Important Way to Reduce Solid Waste, Pollution and to Save Money
Reuse: clean and use materials over and over Example – Glass soda bottles, glass milk bottles Downside of reuse in developing countries -Exposure to disease
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Case Study: Use of Refillable Containers
Reuse and recycle Refillable glass beverage bottles Paper, plastic, or reusable cloth bags Pros Cons
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Polyethylene terephthalate (PET) plastics
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Polyvinyl Chloride (PVC) plastics
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Commonly Used Plastics
#1 PLASTICS: POLYETHYLENE TEREPHTHALATE (PET) Common uses: 2-liter soda bottles, single-use water bottles, cooking oil bottles, peanut butter jars, etc. #2 PLASTICS: HIGH DENSITY POLYETHYLENE (HDPE) Common uses: detergent bottles, yoghurt tubs, milk jugs, bottle caps, backpack frames, hard hats, hula hoops, etc. #3 PLASTICS: POLYVINYL CHLORIDE (PVC) Common uses: plastic pipes, Saran wraps, outdoor furniture, flooring, siding, etc. #4 PLASTICS: LOW DENSITY POLYETHYLENE (LDPE) Common uses: plastic film, grocery bags, dry cleaning bags, produce bags, trash can liners, food storage containers #5 PLASTICS: POLYPROPYLENE (PP) Common uses: bottle caps, food containers, drinking straws, etc PLASTIC #6: POLYSTYRENE (PS) Common uses: packaging pellets or "Styrofoam® peanuts," cups, plastic tableware, meat trays, to-go "clam shell" containers.
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Energy Consumption Involved with Using Different Types of 350 ml Containers
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What Can You Do? Reuse
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There Are Two Types of Recycling
Primary, closed-loop recycling Materials are recycled into new products of the same type Ex. Aluminum cans to aluminum cans Secondary recycling Waste material converted to different products Plastic bottles to park benches
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Types of wastes that can be recycled
Preconsumer – generated by manufacturing process Postconsumer – generated by consumer use of products
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Material Recovery Facilities (MRFs)
Machines or workers separate mixed waste recover valuable materials for sale to manufacturers as raw materials paper, plastics, and other combustible wastes are recycled or burned to produce steam or electricity to run the recovery plant or to sell to nearby industries or homes.
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Science Focus: Bioplastics
Plastics from plants Sources Corn Soy Sugarcane Algae Compostable
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Trade-Offs: Recycling, Advantages and Disadvantages
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Burning Solid Waste Has Advantages and Disadvantages
Waste-to-energy incinerators Burns (incinerates) waste to produce energy Advantages Reduces volume of MSW by 90% Disadvantages Air pollution (CO2, toxic metals, dioxin) Remaining waste (fly ash) is toxic and must be disposed of in special landfills
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Solutions: A Waste-to-Energy Incinerator with Pollution Controls
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Trade-Offs: Incineration, Advantages and Disadvantages
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Burying Solid Waste Has Advantages and Disadvantages
Open dumps Fields or holes in the ground where garbage is deposited Sanitary landfills Waste spread out in thin layers Compacted Covered daily with clay or foam
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Leaching and Leachate Leaching – process in which various chemicals in the upper layers are dissolved and carried to lower layers Leachate – water that has percolated through a solid and leached out chemicals Concern about groundwater contamination
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Solutions: State-of-the-Art Sanitary Landfill
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When landfill is full, layers of soil and clay seal in trash
Topsoil Sand Electricity generator building Clay Leachate treatment system Garbage Methane storage and compressor building Probes to detect methane leaks Pipes collect explosive methane for use as fuel to generate electricity Methane gas recovery well Leachate storage tank Compacted solid waste Figure 21.15 Solutions: state-of-the-art sanitary landfill, which is designed to eliminate or minimize environmental problems that plague older landfills. Since 1997, only modern sanitary landfills are allowed in the United States. As a result, many small, older local landfills have been closed and replaced with larger regional landfills. Question: How do you think sanitary landfills could develop leaks of toxic liquids? Leachate pipes Groundwater monitoring well Leachate pumped up to storage tank for safe disposal Garbage Sand Synthetic liner Leachate monitoring well Sand Groundwater Clay and plastic lining to prevent leaks; pipes collect leachate from bottom of landfill Clay Subsoil
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Trade-Offs: Sanitary Landfills, Advantages and Disadvantages
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We Can Use Integrated Management of Hazardous Waste
Integrated management of hazardous wastes Produce less Convert to less hazardous substances Rest in long-term safe storage
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Integrated Hazardous Waste Management
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We Can Detoxify Hazardous Wastes
Collect and then detoxify Physical methods Chemical methods Bioremediation Phytoremediation Nanomagnets Incineration
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Solutions: Phytoremediation
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Trade-Offs: Phytoremediation, Advantages and Disadvantages
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Trade-Offs: Plasma Arc, Advantages and Disadvantages
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We Can Store Some Forms of Hazardous Waste
Burial on land or long-term storage Deep-well disposal Surface impoundments Secure hazardous landfills
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Surface Impoundment in Niagara Falls, New York, U.S.
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Trade-Offs Surface Impoundments, Advantages and Disadvantages
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Solutions: Secure Hazardous Waste Landfill
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What Can You Do? Hazardous Waste
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Case Study: Hazardous Waste Regulation in the United States
1980: Comprehensive Environmental, Compensation, and Liability Act (CERCLA), or Superfund Polluters pay for cleanup (the idea) Tax payers foot the bill for cleanup (reality) Pace of cleanup has slowed Laws encouraging the cleanup of brownfields Brownfields – abandoned industrial and commercial sites In most cases, contaminated with hazardous waste Can be cleaned up and turned into parks
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Leaking Barrels of Toxic Waste at a Superfund Site in the United States
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21-6 How Can We Make the Transition to a More Sustainable Low-Waste Society?
Concept Shifting to a low-waste society requires individuals and businesses to reduce resource use and to reuse and recycle wastes at local, national, and global levels.
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Grassroots Action Has Led to Better Solid and Hazardous Waste Management
“Not in my backyard” Produce less waste “Not in anyone’s backyard” “Not on planet Earth”
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Providing Environmental Justice for Everyone Is an Important Goal
Which communities in the U.S. have the largest share of hazardous waster dumps?
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