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Infrared Spectroscopy
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Analytical Chemistry • Chromatography (Separations)
• Mass Spectrometry • Infrared (IR) Spectroscopy • Nuclear Magnetic Resonance (NMR) Spectroscopy • X-ray Crystallography (visual solid state molecular structure)
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The Electromagnetic Spectrum
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Infrared (IR) Spectroscopy
What insights are we hoping to gain? • Presence/Absence of Functional Groups
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Molecular Vibrations
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The functional group region The fingerprint region
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Carbon-Hydrogen (C–H) Bonds
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Heteroatom-Hydrogen (X–H) Bonds
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Other Single Bonds
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Carbon-Carbon Bonds
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Double Bonds
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Carbonyl Stretching Frequencies
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Effect of Conjugation
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Some Examples: Ethyl Benzene
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Some Examples: Molecular Ion = 84
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Some Examples: 2-Methyl-1-Pentene
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Some Examples: Molecular Ion = 106
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Some Examples: Benzaldehyde
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Some Examples: Molecular Ion = 56
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Some Examples: Propargyl Alcohol
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Some Examples: Molecular Ion = 148
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Some Examples: 1-Phenylbutan-2-one
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