1. Physical Chemistry (TKK-2446)
16/17 Semester 2
Physical Chemistry (TKK-2446)
Instructor: Rama Oktavian
Office Hr.: M. 10 – 12, T. 10 – 12, W. 09 – 10, F.10 – 15

2. Introduction Find me on: /rama.oktavian Rama Oktavian +6285748298891
Lecturer’s blog

3. Introduction Based on study guide 4 credits – compulsory :
- 3 credits class, 1 credit laboratory
Allowed :

4. Introduction Not Allowed : Academic misconduct University Rule:
Come to class minimum 80% during one semester meeting or you will miss FINAL EXAM

5. Objectives
Student will be able to understand physical chemistry concepts: properties of substances.
Student will be able to understand basic concept in 1st law thermodynamics and its application in chemical reaction.
Student will be able to understand basic concept in phase equilibrium

6. Course Contents Week Content Sub content 1. Introduction
Introduction to course rule and objectives.
Course grading system.
2 - 3
The properties of gas I
Ideal gas, Boyle, and Charles law
Intensive and extensive properties
Equation of state (brief review)
Ideal gas properties
Gas Mixtures: Dalton’s law and Partial Pressure 4.
Solid and liquid properties
Condensed phase
Properties of liquid
Thermal compressibility and volume expansivity
Vapor pressure
5-6
Energy and 1st law thermodynamics
Thermodynamic terms
Heat and work
1st law thermodynamics basic concept
Maximum and minimum work
Change in energy

7. Course Contents 7 Phase equilibrium I: Simple system 8 Midterm exam 9
Week
Content
Sub content
5-6
Energy and 1st law thermodynamics (cont’d)
Application of 1st law thermodynamics
Thermochemistry
Standard enthalpy change
Hess’ law 7
Phase equilibrium I: Simple system
Equilibrium condition
Phase stability of pure substance
P-T diagram for pure substance (phase diagram)
The Clayperon equation for vapor pressure
Phase rule 8
Midterm exam
Course material week 1 - 6 9
Phase equilibrium II: Solution
Ideal solution
Binary solution
P-x diagram
T-x diagram

8. Course Contents 16 Final exam Week Content Sub content 10.
Phase equilibrium II: Solution (cont’d)
Fractional distillation
Azeotrope
Henry’s law and the solubility of gases
11-12
Phase equilibrium in condensed phase
Liquid-liquid equilibria (2-components)
Liquid-liquid equilibria (3-components)
Ternary diagrams
13-14
Phase equilibrium in condensed phase (cont’d)
Solid-liquid equilibrium
Liquid-solid phase diagram
Eutectic point
Salting out 15
Review
Course review 16
Final exam
Course materials week 9-15

9. References Text book Additional references:
Castellan, G.W., Physical Chemistry, Addison Wesley Publishing Company
Additional references:
P. Atkins, J. De Paula Physical Chemistry 8th ed. W. H. Freeman and Company, New York.
Maron, S. H, and Lando, J. B., Fundamentals of Physical Chemistry, Mac Millan Publishing Co. Inc., New York., 1975
Levine, I., Physical Chemistry, Mc Graw Hill, 6th ed., 2008

10. Laboratory Content Sub content Introduction to laboratory
Laboratory apparatus and instrumentation principle, chemicals MSDS (material safety datasheets)
Laboratory safety
Properties of substances
Density measurement
Molecular mass determination by gas density measurement
1st law thermodynamics
Enthalpy-concentration diagram
Heat of combustion of alcohol chains
Heat of netralization

11. Grading system Content Sub content Course (3 credits): 75%
Assignment (20%)
Quiz/Mid-term (40%)
Final Exam (40%)
Laboratory (1 credit): 25 %
Pre-Test
Lab activities
Report

13. Thank You !