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Published byGeraldine Lawrence Modified over 6 years ago
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“a-” = “not” “tom-” = “cut” “atom” = “indivisible”
Atomic Theory “a-” = “not” “tom-” = “cut” “atom” = “indivisible”
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You will need to know the contributions of…
Democritus Dalton Rutherford Thomson Millikan Curie Chadwick
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You will need to know the contributions of…
Democritus– coined the term “atom” (uncuttable) suggested the relationship between the particle and the substance
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You will need to know the contributions of…
Dalton—modern atomic theory -all matter is made of atoms -atoms of one element are identical, atoms of different elements are different -atoms form compounds in simple whole number ratios -chemical reactions are rearrangements of atoms, the atoms are not changed -compounds with different ratios of atoms are different compounds
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You will need to know the contributions of…
Dalton—modern atomic theory -all matter is made of atoms -atoms of one element are identical, atoms of different elements are different -atoms form compounds in simple whole number ratios -chemical reactions are rearrangements of atoms, the atoms are not changed -compounds with different ratios of atoms are different compounds The law of definite proportions The law of multiple proportions
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PS The mass of a proton is about the same as the mass of a neutron (an electron is about 1/1800th of that mass) This mass is called an atomic mass unit (1 amu) It is also called a dalton
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You will need to know the contributions of…
Rutherford-gold foil experiment -showed atom is mainly empty space -mass and (+) charge in the center
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You will need to know the contributions of…
Thomson—cathode “rays” = stream of electrons, -calculated charge/mass ratio of electron
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You will need to know the contributions of…
Millikan—oil drop experiment determined the charge (& therefore the mass) of an electron
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You will need to know the contributions of…
Curie— -described the process of radioactive decay of atoms
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You will need to know the contributions of…
Chadwick— -discovered neutrons Cloud chamber—the straight track shows that it has no charge
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Protons, neutrons, electrons
Name Symbol Mass Charge Location Proton Neutron Electron
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Protons, neutrons, electrons
Name Symbol Mass Charge Location Proton p 1 amu in nucleus Neutron n 1 amu in nucleus Electron e amu -1 (about) (about) around nucleus, in electron cloud (about)
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Atomic number and mass number
Atomic mass number # electrons
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Atomic number and mass number
Atomic number is the number of protons—this determines the element Atomic mass number = #protons + #neutrons # electrons = # protons, in an uncharged atom
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What is an isotope?
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What is an isotope? “the same” “place”
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What is an isotope? Same Different
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What is an isotope? Same Different Element Mass
Atomic number Mass number # protons # neutrons # electrons Radioactivity Ion charge Chemical properties (mostly)
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Nuclide Notation A nuclide is a nucleus or atom of a specific isotope of an element 39 K 19 This is potassium-39. It has 19 protons (atomic number = 19), making it potassium, and 20 neutrons, making a mass number of 39
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How many p, n, e- in each? What is the mass number and atomic number?
3 He 80 Br- 111 Ag+ 2 35 47 59 Fe+2 40 Ca+2 238 Pu 26 20 94
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Write the nuclide designation
Proton Neutron Electron (A) (B) (C) (D)
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Write the nuclide designation
(B) (C) (D) 51 V+2 23 14 N-3 7 123 Te-2 52 87 Sr+2 38
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What is the atomic number and mass number?
Proton Neutron Electron (A) (B) (C) (D)
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Average atomic mass --A weighted average of the naturally occurring isotopes Ex: 99.63% N-14 (mass= amu/atom) .37% N-15 (mass= amu/atom) Avg= (.9963x14.003) +(.0037x15.000)=
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Average atomic mass --A weighted average of the naturally occurring isotopes
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Average atomic mass --A weighted average of the naturally occurring isotopes Ex: 99.63% N-14 (mass= amu/atom) .37% N-15 (mass= amu/atom) Avg= (.9963x14.003) +(.0037x15.000)=
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Average atomic mass --A weighted average of the naturally occurring isotopes Ex: 99.63% N-14 (mass= amu/atom) .37% N-15 (mass= amu/atom) Avg= (.9963x14.003) +(.0037x15.000)= = = amu / atom
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Average atomic mass What is the average atomic mass of carbon:
98.89% C-12 ( amu/atom) 1.11% C-13 ( amu/atom)
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Average atomic mass What is the average atomic mass of carbon:
98.89% C-12 ( amu/atom) 1.11% C-13 ( amu/atom) amu/atom
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How common is Cl-37? Cl-35 has a mass of 34.969 amu/atom
The average atomic mass of chlorine is amu/atom
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How common is S-34? S-32 has a mass of 31.972 amu/atom
(less common nuclides are ignored) The average atomic mass of sulfur is amu/atom
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The greatest conversion of all time!
1 amu X x = 1 gram atom X x mole Avogadro’s number!
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