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Nuclear Physics Chapter 29
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Ernest Rutherford established the
existence of the nucleus through scattering experiments. Nucleus - (Nearly spherical, diameter ranging from 2.6 x m to 16 x m.) The atom is neutral so the positive charge of the nucleus is equal to the negative charge of the electrons. (If not equal, it is an ion.) The mass of a carbon atom is the mass of 12 protons, not 6. To account for the excess mass in the nucleus, Rutherford postulated the existence of a neutral particle with the mass of a proton.
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X Nuclear Notation A Z N (X = chemical symbol)
(mass number: # Nucleons=protons + neutrons) A X Z N (# Neutrons - usually omitted) (proton, or atomic number: # Protons – element species) A: mass number, total of protons + neutrons Z: proton number (aka atomic number), establishes the species of element in question N: neutron number (X = chemical symbol)
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atoms whose nuclei have the same
III. Isotopes - atoms whose nuclei have the same # of protons but different # of neutrons. A. Same electronic structure \ same chemical properties. B. Referred to by mass numbers (total # of nucleons) i.e. carbon-12, carbon-13, carbon-14 12 6 C 13 6 C 14 6 C C. Most elements have many isotopes that occur naturally.
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IX. Total Binding Energy (Eb) -
the amount of energy released when separate nucleons combine to form a nucleus. (energy equivalent of mass defect) Eb = (Dm)c2 =∆m (931.5MeV/1 u) A. The mass of the nucleus is less than the sum of its parts. B. Mass Defect - mass of the nucleus & the sum of its parts. the difference between the
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V. Nuclear Equations A. The decay process is represented by a nuclear equation which is similar to a chemical equation except it refers to nuclei. B. Two Conservation Laws apply to all nuclear processes. 1. Conservation of Nucleons - the total # of nucleons (A) remains constant. 2. Conservation of Charge
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1. In 1899 Rutherford discovered that
uranium compounds emit 3 different types of radiation. 2. He separated them by their penetrating ability. a. Alpha particles (a) can be stopped by a sheet of paper or a few cm of air. (+) b. Beta particles (b) can be stopped by a few mm of aluminum or a few m of air. (-) c. Gamma particles (g) can be stopped by several cm of lead. (neutral)
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VI. Types of Radiation A. Alpha particles are doubly (+) charged particles that contain 2 protons & 2 neutrons. (Emitted with a specific energy that depends on the radioactive isotope.) 1. Identical to helium nucleus (4He) 2 2. Since it contains P+ & n, it must come from the nucleus of an atom.
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92U 238 2He + 4 90Th 234 3. When an a particle is ejected, the
parent particle loses 2 p+, so the resulting daughter nucleus must be the nucleus of another element. 92U 238 2He + 4 90Th 234 Uranium isotope is transmuted to Thorium by a decay.
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90Th 234 91Pa 234 -1e B. Beta particles are high speed electrons and
emitted with a wide range of energies. 1. They are e- emitted by the nucleus. 2. The Mass # is unchanged since the mass of an e- is a tiny fraction of the atomic mass. 3. The nucleus contains no e-, so neutron in nucleus decays into a proton & electron (unseen neutrino accompanies b decay). 4. The # protons (Z) increases by one. 90Th 234 91Pa 234 -1e + Thorium emits b particle & becomes protactinium isotope.
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1 1 0 0n 1p + -1e a. b- Decay involves the emission of an e-.
Isotopes decay by this method because they have too many neutrons compared to protons to be stable. 0n p e (basic b- decay) neutron proton electron
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1p 0n + +1e 1 1 0 8O7 15 +1e 7N8 15 b. b+ Decay (Positron Decay) -
too many protons compared to neutrons. emission of a positron because there are involves the 1p n e (basic b+ decay) proton neutron positron 8O7 15 +1e 7N8 15 +
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C. Gamma Particles – high energy photons emitted with specific energy that depends on the radioactive isotope. 1. Redistribution of charge inside nucleus. 2. Emission of g ray by a nucleus to the emission of a photon by a de-excited atom. is analogous (The nucleus is left in an excited state after a previous radioactive decay.)
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3. Nuclei are thought of as having energy levels
like atomic electrons. a. Nuclear energy levels are much farther apart (keV or MeV as compared to a few eV). b. Gamma rays are very energetic with frequencies greater than those of X-rays & much shorter wavelengths.
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61 * 61 28Ni 28Ni + g nickel nickel gamma excited ray
61 * nickel nickel gamma excited ray 4. The * indicates that the nucleus is in an excited state. 5. The de-excitation process results in the emission of a gamma ray. 6. The daughter nucleus is simply the parent nucleus with less energy.
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unaffected by any external stimulus. A. Activity -
VII. Decay Rate - unaffected by any external stimulus. A. Activity - # of nuclear decays per second. 1. Decreases with time. 2. Each isotope has own rate of decrease. DN t = -lN (Minus indicates N is decreasing.) 3. l = decay constant - different for different isotopes (>l = greater rate of decay).
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N = Noe-lt 4. The curve & N are said to decay exponentially
since the graph follows the exponential function e-lt with time. e ~ is the base of natural logarithms. N = Noe-lt No = initial # nuclei (t=0) N = # of undecayed parent nuclei left
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B. Half-life (t½) - the time for half of the radioactive sample to decay (time corresponding to No/2). N/No = 1/2 1. Decay rate of isotope is often expressed in terms of its half-life rather than decay constant. 2. The # of decays/second or activity or decay rate is decreased by half. 3. Decay rate is usually measured to determine the half-life.
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N = Noe-lt N/No = e-lt1/2 e-.693 ~ 1/2 t½ = .693/l
N = Noe-(.693t / t1/2) C. One Curie (Ci) = 3.70 x 1010 decays/s (traditional unit). D. The Becquerel (Bq) is the SI unit. Bq = 1 decay/s 3.70 x 1010 Bq = 1 Ci
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