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Atomic Structure Current Atomic model
Dense nucleus contains the mass and positive charge. The electrons are far outside the nucleus. (e- cloud)
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The Atomic Scale Most of the mass of the atom is in the nucleus (protons and neutrons) Electrons are found outside of the nucleus (the electron cloud) Most of the volume of the atom is empty space “q” is a particle called a “quark”
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About Quarks…(particles that make up protons and neutrons)
Protons and neutrons are NOT fundamental particles. Protons are made of two “up” quarks and one “down” quark. Neutrons are made of one “up” quark and two “down” quarks. Quarks are held together by “gluons”
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Subatomic particle symbols
Proton p+ Neutron n0 Electron e-
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Atomic Particles Summary
Subatomic Particle Charge Mass (kg) Location Proton, p+ +1 1.673 x 10-27 Nucleus Neutron, n0 1.675 x 10-27 Electron, e- -1 9.109 x 10-31 Electron cloud (Very far outside the nucleus)
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Comparing relative mass:
Subatomic Particle Charge Mass (kg) Location Proton, p+ +1 1.673 x 10-27 Nucleus Neutron, n0 1.675 x 10-27 Electron, e- -1 9.109 x 10-31 Electron cloud (Very far outside the nucleus) 1 1 1 1840 = Neutron Proton 1.675 x kg 1.673 x kg 1 = Neutron Electron 1.675 x kg 9.109 x kg 1838.8 1 = Proton Electron 1836.6 1 &
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(Very far outside the nucleus)
Atomic Particles Subatomic Particle Charge Mass (amu) Location Proton, p+ +1 1 Nucleus Neutron, n0 Electron, e- -1 1840 Electron cloud (Very far outside the nucleus) Note: atomic mass unit (amu) 1 amu = 1/12 the mass of a carbon-12 isotope.
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Atomic Number Atomic number (Z) of an element is the number of protons in the nucleus of each atom of that element. Atomic # C Carbon 6 12.011 P Phosphorus 15 30.97 Au Gold 79 196.97 Periodic Table Atomic mass (average) Element # of protons Atomic # (Z) Carbon 6 Phosphorus 15 Gold 79
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Mass Number Nuclide p+ n0 e- Mass #
Mass number is the number of protons and neutrons in the nucleus of an isotope. Mass # = p+ + n0 Nuclide p+ n0 e- Mass # Oxygen - 10 - 33 42 - 31 15 18 8 8 18 Arsenic 75 33 75 Phosphorus 16 15 31 Periodic Table of Elements
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Isotopes Isotopes are atoms of the same element having different masses due to varying numbers of neutrons. Isotope Protons Electrons Neutrons Nucleus Hydrogen–1 (protium) 1 Hydrogen-2 (deuterium) Hydrogen-3 (tritium) 2
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Chemical Symbol Notation
Zinc-64 Specific Isotope mass (A) = Mass # (p+ + n0) 64 2+ Charge on ion Zn Oxidation state: (Lost 2 e-) LEO (Z) =Atomic # (p+) 30 Chemical Symbol (Zinc) 30 proton + 34 neutrons 64 (mass #)
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H Hydrogen-1 (Protium) Isotope symbols Chemical Symbol (Hydrogen) 1
Mass # (p+ + n0) H 1 proton + 0 neutrons 1 Atomic # (p+) 1
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H Hydrogen-2 (Deuterium) Isotope symbols Chemical Symbol (Hydrogen) 2
Mass # (p+ + n0) H 1 proton + 1 neutrons 2 Atomic # (p+) 1
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H Hydrogen-3 (Tritium) Isotope symbols Chemical Symbol (Hydrogen) 3
Mass # (p+ + n0) H 1 proton + 2 neutrons 3 Atomic # (p+) 1
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H H H Isotope symbols Hydrogen-1 Hydrogen-2 Hydrogen-3 (Protium)
(Deuterium) Hydrogen-3 (Tritium) 1 3 2 H H H 1 1 1 1 proton + 0 neutrons 1 1 proton + 1 neutrons 2 1 proton + 2 neutrons 3 Isotopes only differ by number of neutrons.
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Calculating Average Mass
Atomic mass is the average of all the naturally isotopes of that element. Copper = amu Isotope Symbol Composition of the nucleus Mass in (amu) Relative Abundance (% in nature) Copper-63 63 29 29 protons 34 neutrons 62.93 69.2 % Copper-65 65 36 neutrons 64.93 30.8 % Cu Cu x Mass (amu) Relative abundance (% as a decimal) Copper-63 62.93 amu x 0.692 = amu + Copper-65 64.93 amu x 0.308 = amu amu Periodic Table of Elements
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Atomic Particles 1+ Nucleus e- n0 Note: atomic mass unit (amu)
Subatomic Particle Symbol Charge Location Relative Mass (amu) Proton p+ Electron 1- Neutron Nucleus 1 amu 1+ Nucleus 1 Very far outside nucleus 1 e- 1840 n0 Note: atomic mass unit (amu) 1 amu = 1/12 the mass of a carbon-12 isotope.
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C N Cl Your Turn 7 7- 14 7 7- 15 17 17- 35 17 17- 37 6C N Cl Atomic #
Isotope Symbol Atomic # neutrons electrons Mass Number (p+ + n0) Isotope Mass in (amu) Relative abundance Carbon-12 6C 6 = 6 6 - 6 + 6 = 12 12.000 98.89% Carbon-13 13 – 6 = 7 6 + 7 = 13 13.003 1.11% Nitrogen-14 N 14.003 99.63% Nitrogen-15 15.000 0.37% Chlorine-35 Cl 34.969 75.77% Chlorine-37 36.966 24.23% 12 13 14 7 7- 14 14-7=7 7 15 7 7- 15 15-7=8 7 35 17 17- 35 35-17=18 17 37 17 17- 37 37-17=20 17 Atomic # C Carbon 6 12.011 N Nitrogen 7 14.007 Cl Chlorine 17 35.453 Atomic mass (average)
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Your Turn (Calculate Average Mass)
Isotope Symbol Atomic # neutrons electrons Mass Number (p+ + n0) Isotope Mass in (amu) Relative abundance Carbon-12 6C 6 = 6 6 - 6 + 6 = 12 12.000 98.89% Carbon-13 13 – 6 = 7 6 + 7 = 13 13.003 1.11% 12 13 x Mass (amu) Relative abundance (% as a decimal) Carbon-12 amu x 0.9889 = amu + Carbon-13 amu x 0.0111 = amu amu 12.01 amu Atomic # C Carbon 6 12.011 Atomic mass (average)
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Your Turn (Calculate Average Mass)
Isotope Symbol Atomic # neutrons electrons Mass Number (p+ + n0) Isotope Mass in (amu) Relative abundance Nitrogen-14 N 14.003 99.63% Nitrogen-15 15.000 0.37% Chlorine-35 Cl 34.969 75.77% Chlorine-37 36.966 24.23% 14 7 7- 14 14-7=7 7 15 7 7- 15 15-7=8 7 35 17 17- 35 35-17=18 17 37 17 17- 37 37-17=20 17 x Mass (amu) Relative abundance (% as a decimal) Nitrogen-14 amu x 0.9963 = amu + Nitrogen-15 amu x 0.0037 = amu amu N Nitrogen 7 14.007 amu
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Your Turn (Calculate Average Mass)
Isotope Symbol Atomic # neutrons electrons Mass Number (p+ + n0) Isotope Mass in (amu) Relative abundance Nitrogen-14 N 14.003 99.63% Nitrogen-15 15.000 0.37% Chlorine-35 Cl 34.969 75.77% Chlorine-37 36.966 24.23% 14 7 7- 14 14-7=7 7 15 7 7- 15 15-7=8 7 35 17 17- 35 35-17=18 17 37 17 17- 37 37-17=20 17 x Mass (amu) Relative abundance (% as a decimal) Chlorine-35 amu x 0.7577 = amu + Chlorine-37 amu x 0.2423 = amu amu Cl Chlorine 17 35.453 amu
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F Si Ti Mn 9 10 14 15 47 25 55 Atomic # = p+ = e- (neutral atom)
Mass # = p+ + n0 Atomic number Mass Number of protons p+ neutrons n0 electrons e- Symbol of element 9 10 14 15 47 25 55 19 9 9 F 14 Si 14 29 22 22 - 25 22 Ti 25 = 30 25 Mn Atomic # F Fluorine 9 18.998 Si Silicon 14 28.086 Ti Titanium 22 47.867 Mn Manganese 25 54.938 Atomic mass (average)
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Pb Calculate Average Mass Mass # = p+ + n0 1.37 100 + 204 206 207 208
Lead 82 207.20 Calculate Average Mass Mass # = p+ + n0 82p 122n 82p 124n 82p 125n 82p 126n % abundance: 1.37% 26.26% 20.82% 51.55% Mass # 204 206 207 208 1.37 100 No amu mass shown. Use mass # instead. x Mass (amu) Relative abundance (% as a decimal) Lead-204 204 x 0.0137 = Lead-206 206 x 0.2626 = Lead-207 207 x 0.2082 = + Lead-208 208 x 0.5155 = 207.21
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