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ACIDS, BASES and SALTS
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Strong Acids HCl → H+ + Cl- - dissociate completely into ions
ACIDS, BASES and SALTS Strong Acids HCl → H+ + Cl- - dissociate completely into ions - readily transfer H+ ions - strong electrolytes Phet Simulation Acid-Base Solutions Strong & Weak Acids Animations
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ACIDS, BASES and SALTS Common Strong Acids (Table K) HCl – hydrochloric acid HNO3 – nitric acid H2SO4 – sulfuric acid Add HBr and HI to Table K
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Weak Acids HC2H3O2 ↔ H+ + C2H3O2-
ACIDS, BASES and SALTS Weak Acids HC2H3O2 ↔ H+ + C2H3O2- - do not dissociate completely into ions - do not readily transfer H+ ions - poor/weak electrolyte Phet Simulation Acid-Base Solutions
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ACIDS, BASES and SALTS Common Weak Acids (Table K) acetic acid - HC2H3O2 or CH3COOH carbonic acid - H2CO3 phosphoric acid - H3PO4
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Strong Bases LiOH → Li+ + OH- - dissociate completely into ions
ACIDS, BASES and SALTS Strong Bases LiOH → Li+ + OH- - dissociate completely into ions - readily yields OH- ions - have strong affinity (attraction) for H+ - strong electrolyte Phet Simulation Acid-Base Solutions All About That Base (No Acid) 03:40
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Common Strong Bases (Table L)
ACIDS, BASES and SALTS Common Strong Bases (Table L) metal hydroxides (OH-) with group 1 or 2 metals NaOH – sodium hydroxide KOH – potassium hydroxide Ca(OH)2 - calcium hydroxide LiOH – lithium hydroxide
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Weak Bases CuOH ↔ Cu+1 + OH-
ACIDS, BASES and SALTS Weak Bases CuOH ↔ Cu OH- - react only partially in water to form OH- ions Phet Simulation Acid-Base Solutions
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Common Weak Bases (Table L – NH3) and Fe(OH)2 – iron (II) hydroxide
ACIDS, BASES and SALTS Common Weak Bases (Table L – NH3) and all other metal hydroxides (OH-) not with group 1 or 2 metals Fe(OH)2 – iron (II) hydroxide Fe(OH)3 – iron (III) hydroxide CuOH – copper (I) hydroxide Al(OH)3 - aluminum hydroxide
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Amphoteric (Amphiprotic) substances
ACIDS, BASES and SALTS Amphoteric (Amphiprotic) substances – can act as either an acid _________________ or as a base _________________________ proton (H+) donor proton (H+) acceptor
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ACIDS, BASES and SALTS Identify the acid, base, conjugate acid and conjugate base. (see Table L - the stronger acid is the proton donor) Remember Bronstead-Lowery Definitions: An acid donates a proton (H+) A base accepts a proton (H+)
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ACIDS, BASES and SALTS H2O H2O + NH3 ↔ H2O + HCl ↔ NH3 NH3 + HCl ↔
NH3 NH3 + HCl ↔ NH3 + H- ↔ HCO3- HCO3- + H2O ↔ HCO3- + HSO4- ↔ HSO4- HSO4- + H2O ↔ HSO4- + HCl ↔ H2PO4- H2PO4- + H2O ↔ H2PO4- + HBr ↔
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