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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Expectations from a new cleaning / drying technology Cleaning / Drying Performance Material Compatibility Safety-in-use (toxicology, flammability, stability) Environmental Impact Durability (regulatory issues) Cost of Ownership (long-term strategy vs. short-term thinking) Vertrel® is a balanced combination of properties related to performance, material compatibility, operator safety, environmental issues, and costs. B-1
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids What is Vertrel® HFC 43-10mee? Vertrel® HFC 43-10mee is a proprietary HFC (hydrofluorocarbon) fluid suited for cleaning, rinsing and drying processes Vertrel® HFC 43-10mee is also used as a carrier, heat transfer and dielectric fluid Tradename: Vertrel® XF Formula: C5H2F10 1,1,1,2,3,4,4,5,5,5 decafluoropentane B-2
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Molecule of Vertrel® XF vs. Freon® CFC-113 F F F F F CI F | | | | | | | F - C - C - C - C - C - F F - C - C - CI F H H F F CI F HFC CFC-113 B-3
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Purpose of Vertrel® HFC 43-10mee Vertrel® is designed to replace ozone-depleting solvents such as: CFC-113 (Freon®) HCFC-141b HCFC-225 Vertrel® is also an ideal replacement for TCA, Trichlorethylene (TCE), Perchlorethylene, and Perfluorocarbons (PFCs) Vertrel® may also replace aqueous-, alcohol-, n-Propyl Bromide- and hydrocarbon-based cleaning systems B-4
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Key characteristics of Vertrel® HFC 43-10mee (1) Ozone Depletion Potential (ODP) = ZERO Very low Global Warming Potential (GWP) Non-flammable, no flashpoint, no auto-ignition Excellent toxicity profile Higher boiling point and lower surface tension than CFC-113 Low viscosity High liquid density Very low water solubility B-5 due to lower atmospheric lifetime
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Key characteristics of Vertrel® HFC 43-10mee (2) Excellent thermal, chemical and hydrolytic stability High material compatibility Excellent dielectric properties Easily miscible with numerous common solvents Recyclability of azeotropic mixtures Low energy consuming process, thus cost efficiency Can be used in combination with low volatility solvating agents (such as Hydrocarbons) B-6
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Comparison of Vertrel® with CFC-113 and HCFC-141b Physical and Chemical Properties Property / Unit HFC 43-10mee CFC-113 HCFC-141b Boiling Point (BP) °C Freezing Point °C Liq. density at 25°C kg/l Vapor pressure hPa Surface tension dyne/cm Dyn. Visc. at 25°C CP Specific heat 25°C KJ/kgK Heat of vap. at BP KJ/kg Kauri Butanol (KB) Purity (min.) % NVR max. ppm H2O ppm < B-7
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Comparison of Vertrel® with CFC-113 and HCFC-141b Safety and Toxicity related Properties Property / Unit HFC 43-10mee CFC-113 HCFC-141b Flash Point none none none Flammable range % none none – 17.7 Auto-ignition temperature °C none none AEL 8-hr weighted average ppm Ceiling ppm 400 B-8
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Comparison of Vertrel® with CFC-113 and HCFC-141b Environmental Properties Property / Unit HFC 43-10mee CFC-113 HCFC-141b Atmospheric lifetime yr Ozone depletion potential Hal. Global warming potential (vs. CFC-11 =1 ) Global warming potential 100 years IHT Solubility in water ppm Solubility of water ppm B-9
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Comparison of Vertrel® with CFC-113 and PFC (C6F14) Dielectric Properties (at 23ºC, 1 atm) Property / Unit HFC 43-10mee CFC C6F14 Breakdown Voltage, liquid KV-RMS (ASTM D-2477) disc electrodes, 0.1 inch gap Dielectric constant (ASTM D-924) KHz Dissipation factor (ASTM D-924) KHz E n.a <3E-04 Conductivity (DC), (ASTM 1169) Siemens E E E-15 current measured amp E-06 B-10
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Benefits of HFC vs. CFC-113 and/or HCFC-141b Higher BP and liquid density Reduced solvent losses due to easier containment in vapor degreasers Lower surface tension and viscosity Easier penetration in tight spaces (blind holes) on complex parts No solvent trapping when part is lifted into the saturated vapor zone Easier draining from the parts Lower heat of vaporization Reduced drying time and reduced drag out losses Reduced energy consumption to boil up the solvent B-11
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Vertrel® Specialty Fluids
Service Chimie : 5 place de l’église, Saint Thibault des vignes : (33) : (33) : Vertrel® Specialty Fluids Material Compatibility Table (non exhaustive overview) Vertrel® is highly compatible with essentially all metals, and most plastics and elastomers Plastics Polyethylenes Polyacetals Polypropylenes ABS Polystyrenes Epoxy Polyesters PET & PBT Ionomers Polyphenylene Oxides Polyamides Polyimides Polyarylates Polycarbonates PVC, CPVC Polyetherketones PVDF Elastomers Natural Rubbers Nitrile Rubbers Butyl Rubbers Neoprene® EPDM (Nordel®) Chloro-sulfonated PE SBR Polysulfides Silicones Polyesters B-12
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