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Volume 33, Issue 1, Pages (January 2017)

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1 Volume 33, Issue 1, Pages 12-22 (January 2017)
Composite resin reinforced with silver nanoparticles–laden hydroxyapatite nanowires for dental application  Miao Ai, Zhiyun Du, Siqi Zhu, Hongjuan Geng, Xu Zhang, Qing Cai, Xiaoping Yang  Dental Materials  Volume 33, Issue 1, Pages (January 2017) DOI: /j.dental Copyright © 2016 The Academy of Dental Materials Terms and Conditions

2 Fig. 1 Preparation and characterizations of nanowires including HA, HA–PDA and HA–PDA–Ag using SEM (a), TEM (b, c), XRD (d), XPS (e) and TGA (f) analysis: (a) as-prepared HA nanowires; (b) HA–PDA–Ag-1.0 nanowires; (c) magnification of image (b). The inset in image (e) is the magnification of Ag signals. Dental Materials  , 12-22DOI: ( /j.dental ) Copyright © 2016 The Academy of Dental Materials Terms and Conditions

3 Fig. 2 TEM images (a–c) and TGA measurements (d) of HA–PDA–Ag nanowires prepared from Tollens’ reagents with different AgNO3 concentrations: (a) HA–PDA–Ag-0.1; (b) HA–PDA–Ag-0.5; (c) HA–PDA–Ag-1.0. The insets are the average particle size and particle size distribution of corresponding AgNPs. Dental Materials  , 12-22DOI: ( /j.dental ) Copyright © 2016 The Academy of Dental Materials Terms and Conditions

4 Fig. 3 Release of silver ions from different HA–PDA–Ag nanowires (a) and cytotocixity assay by culturing L929 fibroblasts in extracts from different nanowires prepared according to ISO :200 (b) and in corresponding ten times diluted extracts (c). The cell proliferation rates had been normalized to the OD values of the negative control. Each value is mean±SD (n=3). Bars with * and ** indicate values that are significantly different (p<0.05) and highly significantly different (p<0.01), respectively. Dental Materials  , 12-22DOI: ( /j.dental ) Copyright © 2016 The Academy of Dental Materials Terms and Conditions

5 Fig. 4 (a) Curing temperature of Bis-GMA/TEGDMA/BPO system determined by DSC, and flexural properties of Bis-GMA/TEGDMA composites containing different mass fractions of HA–PDA–Ag-1.0 nanowires: (b) flexural strength; (c) flexural modulus. Each value is mean±SD (n=8). Bars with * and ** indicate values that are significantly different (p<0.05) and highly significantly different (p<0.01), respectively. Dental Materials  , 12-22DOI: ( /j.dental ) Copyright © 2016 The Academy of Dental Materials Terms and Conditions

6 Fig. 5 SEM images (a1–d1) and element mapping images including calcium (a2–d2) and silver element (a3–d3) of fractured surfaces of Bis-GMA/TEGDMA composites containing different mass fractions of HA–PDA–Ag-1.0 nanowires after flexural testing: (a1–a3) 4wt.%; (b1–b3) 6wt.%; (c1–c3) 8wt.%; (d1–d3) 10wt.%. The arrows indicate the location of HA nanowire bundles. Dental Materials  , 12-22DOI: ( /j.dental ) Copyright © 2016 The Academy of Dental Materials Terms and Conditions

7 Fig. 6 Antibacterial activity of Bis-GMA/TEGDMA composites containing different mass fractions of HA–PDA–Ag-1.0 nanowires against streptococcus mutans (S.M.) by live/dead assay (a–e): (a) 0wt.%; (b) 4wt.%; (c) 6wt.%; (d) 8wt.%; (e) 10wt.%, together with silver ion release from corresponding composites (f). The values in (f) are mean±SD (n=3). (For interpretation of the references to color in the text, the reader is referred to the web version of this article.) Dental Materials  , 12-22DOI: ( /j.dental ) Copyright © 2016 The Academy of Dental Materials Terms and Conditions


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