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4.2 NEWTON’S LAW OF VISCOSITY

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Presentation on theme: "4.2 NEWTON’S LAW OF VISCOSITY"— Presentation transcript:

1 Principles of Colloid and Surface Chemistry Ch4 The Rheology of Dispersions

2 4.2 NEWTON’S LAW OF VISCOSITY

3 4.2 NEWTON’S LAW OF VISCOSITY

4 4.2 NEWTON’S LAW OF VISCOSITY

5 4.3a Concentric-Cylinder Viscometers

6 4.3a Concentric-Cylinder Viscometers

7 4.3b cone-and-Plate Viscometers

8 4.4a Flow Through Cylinders:The Poiseuille FloW

9 4.2b Capillary Viscometers

10 4.5a The Navier-Stokes Equation: General Consideration

11 4.6a The Effect of Particles on the Viscosity of Disperdions

12 4.6b Einstein’s Theory: Experimental Tests

13 4.6b Einstein’s Theory: Experimental Tests

14 4.6b Einstein’s Theory: Experimental Tests

15 4.7a Effect of High Volume Fractions

16 4.7b Effects of Solvation and Shapes

17 4.7c Electroviscous Effects and Viscoeletric Effects
FIG Intrinsic viscosity of a protein solution : ( a ) variation of the intrinsic viscosity of aqueous protein solutions with axial ratio a/b and extent of hydration m1,b / m2 ( redrawn from L .Oncley, Ann. NY Acad . Sci. , 41, 121 ( 1941 ) )

18 4.7c Electroviscous Effects and Viscoeletric Effects
FIG Intrinsic viscosity of a protein solution :( b ) superposition of the [η] = 8.0 contour from Fig. 4.13a and the f/f0 = l.45 contour from Figure 2.9. The crossover unambiguously characterizes particles with respect to hydration and axial ratio

19 4.7c Electroviscous Effects and Viscoeletric Effects

20 4.8a Examples of Non-Newtonian Features

21 4.9a The Staudinger-Mark-Houwink Equation

22 4.9b Polymer Chain Extension and Viscosity


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