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Quiz 6/1/05 Identify the quantities from the units:
15kPa 170 K 22.3 torr 2.0 atm If 5.0 ml of a gas at a constant temperature at 100 kPa, expands to fill 15 ml, what is the new pressure? Identify V1, V2, and P1 and P2 ( 4 pts) Solve the previous problem using the appropriate form of the equation P1 V1 = P2 V2 pressure temperature Pressure V1 = 5.0 mL 6. V2 = 15 mL 7. P1 = 100 kPa 8. P2 = ? -1 = 89 % -2 = 78% -3 = 67% -4 = 56% -5 = 45 % -6 = 34 % -7 = 23% -8 = 12 % -9 = 0% 6. P2 = (5mL)(100kPa) 15 mL P2 = 33 kPa
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Charles’ Law Volume and Temperature are directly proportional. V2 T2
= A 2.0 L volume of a gas is heated from 00C to 100 oC What is the new volume? 2.0 L = V1 0oC =T1 add 273 = 273 K 100oC = T2 add 273 = 373 K New Volume = unknown Solve for V2 V1T2 = V2 T1 (2.0 L)(373K) (273K) = 2.73 L
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HW 21: Notes page 463 #15 page 464 and # 43,44,45,46 on page 473
Combined Gas Law: PV is equal to some number, T a constant. P1V1 T1 = P2V2 T2 = P3V3 T etcetera
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How to solve wordy problems
#14. Freon-12, dichlorodifluoromethane (CCl2F2) was a widely used refrigerant. Consider a sample of gaseous CCl2F2 at a 2.23 dm3 pressure of 4.85 kPa and a temperature of C. Calculate the volume of the gas at a pressure of 1.38 kPa and a temperature of 5.5oC. Step 1: ignore the extra words! Remember dm3 = L V1 = 2.23 L P1 = 485 kPa T1 = – 1.36 = K V2 = ? P2 = 1.38 kPa T2 = = K
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V2 = ? P2 = 1.38 kPa T2 = = K V1 = 2.23 L P1 = 485 kPa T1 = – 1.36 = K (485 kPa) (2.23L) (279 K) (1.38 kPa) (272 K) = 8.04 L
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# 15. Correct the volumes of the following gases as indicated:
P2 = kPa T2 = 273 K V1 = 7.51 m3 P1 = 59.9 kPa T1 = = 278 K (59.9 kPa) (7.51 dm3) (273 K) (101.3 kPa) (278 K) = 4.36 m3
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# 15. Correct the volumes of the following gases as indicated:
b. V2 = ? P2 = 94.5 kPa T2 = = 309 K V1 = 3.51 cm3 P1 = 82.5 kPa T1 = = 282 K (82.5 kPa) (3.51 cm3) (309 K) (94.5 kPa) (282 K) = 324 cm3
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# 43. For the following gases, correct the volumes to the conditions indicated.
b. V2 = ? P2 = 94.5 kPa T2 = = 309 K V1 = 654 cm3 P1 =65.3 kPa T1 = = 279 K (82.5 kPa) (654 cm3) (309 K) (94.5 kPa) (279 K) = 324 cm3
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Updated Problem solving vocabulary
Correct the volume: figure out the new volume. Cylinder: A container the shape of a can of soup. Compressed: Smooshed, particles are packed tightly and at high pressure. are held constant: The beginning and end are the same. piston: A device used to push a gas or fluid (like in a car engine, or a syringe. vapor pressure: pressure caused by water molecules which have evaporated. Standard Temperature = 273 K or 0oC occupies: fills, has a volume of… remains: stays (the same) indicated: listed here
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