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CARBON NANOSTRUCTURES (FULLERENES, CARBON NANOTUBES, GRAPHENE)
lecture for physics and chemistry students (2017. summer semester – 06. April) Prof. Jenő Kürti ELTE Department of Biological Physics www: virag.elte.hu/kurti
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C60
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EELS Im(-1/)
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ω·Im() Eprimer = 170 keV
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! Eb = eV
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Raman- and infrared spectroscopy
VIBRATIONS: Raman- and infrared spectroscopy
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Sir Chandrasekhara Venkata Raman
(7 November 1888 – 21 November 1970) The Nobel Prize in Physics 1930 "for his work on the scattering of light and for the discovery of the effect named after him".
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anti - Stokes Stokes D.A. Long: Raman spectroscopy McGraw-Hill, 1977
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https://faculty.unlv.edu/klipinska/assets/Lab/RAMAN/
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Inelastic light scattering: classical picture
induced dipole moment k k k polarizability Rayleigh anti-Stokes Stokes Raman
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Inelastic light scattering: QM picture
w1 w2 w1 w2 w (ħ=1) ground state - - w2 = w1 + w w2 = w1 – w wikipedia
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1st order Raman (Stokes)
phonon q 0 (–point) w2 = w1 – w photon in photon out a b w, w, w,
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hin hout hin hout hin hout resonance Raman (incoming)
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g = 120
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Eddig mondtam el április 6-án
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