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ATOMS & ELEMENTS
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(Greek for indivisible)
HISTORY OF THE ATOM 460 BC Democritus develops the idea of atoms He divided an element into halves until it could no longer be divided and called the units … ATOMA (Greek for indivisible)
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HISTORY OF THE ATOM 1808 John Dalton ATOMS
suggested that all matter was made up of tiny spheres that were able to bounce around with perfect elasticity and called them ATOMS
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MATTER any physical object that has mass and takes up space ELEMENT all atoms are identical ATOMS the smallest particles that represent the properties of an element
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HISTORY OF THE ATOM Joseph John Thompson 1898
found that atoms would eject a smaller negative particle which he called an ELECTRON
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HISTORY OF THE ATOM 1904 Joseph John Thompson
He described atoms as a soup of positive charges to balance the electron's charge, like plums surrounded by pudding. PLUM PUDDING MODEL
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HISTORY OF THE ATOM Ernest Rutherford 1910
fired Helium nuclei at a piece of gold foil which was only a few atoms thick. although most of helium nuclei passed through, some bounced back. Rutherford’s new evidence allowed him to propose a more detailed model with a central positive nucleus surrounded by electrons.
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ATOMIC STRUCTURE: Particles
By 1910, we envisioned atoms as being made up of these three subatomic particles Sub-atomic Particle Location Charge Mass p: proton nucleus + charge 1 amu n: neutron nucleus No charge 1 amu outside nucleus - charge .0005 amu e-:electron
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ATOMIC STRUCTURE: Mass
most of mass is in nucleus protons and neutrons have the same mass (~1 amu) electrons have such a small mass that they have only a small effect on the mass of an atom
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ATOMIC STRUCTURE: Charge
Nucleus has a positive charge (protons + neutrons = +) Charge of protons and electrons cancel each other out! Atoms on the periodic table have zero charge because the #p = # e-, so the # + = # -
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He ATOMIC STRUCTURE: AZX Notation 4 2
Atomic mass #p + #n 2 Atomic number # protons # of electrons = # of protons in a NEUTRAL atom
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HISTORY OF THE ATOM Niels Bohr 1913
Bohr refined Rutherford's idea by adding that the electrons were in orbitals or energy levels. Each orbital was only able to contain a set number of electrons.
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ATOMIC STRUCTURE Electrons move around the nucleus
Energy level = amount of energy used by electron to go around the nucleus (orbitals = path shape, a quantum trait) Each energy level has set number of electrons p orbital s orbital Each electron is unique for that atom- no two have the same 4 characteristic traits (study of these traits = QUANTUM PHYSICS)
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HELIUM ATOM electrons in orbits nucleus
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HELIUM ATOM ATOM Energy Level proton N + - + N - electron neutron
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ATOMIC STRUCTURE Electrons are arranged in Energy Levels or shells around the nucleus of an atom. 1st energy level 2nd energy level 3rd energy level a maximum of 2 electrons a maximum of 8 electrons a max of 8 (or 18) electrons
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ELECTRONIC CONFIGURATION
Write the electronic configuration for the following elements: 16 23 11 O Na B a) b) c) 8 11 5 2, 6 2, 8, 1 2, 3 28 35 40 Cl Si Ca d) e) f) 17 14 20 2, 8, 4 2, 8, 7 2, 8, 8, 2
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BOHR DIAGRAMS Bohr Diagram is a model made by Neils Bohr to show parts of atom & energy levels Bohr diagrams aren’t accurate, but are useful in explaining atomic behavior this is the model we will use
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BOHR DIAGRAMS Nitrogen Write the number of p and n in the center,
Circles to show the shells. Use a dot or “X” to show electrons, and X Nitrogen X X X 7p 7n X 14 X 7 X
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BOHR DIAGRAMS Cl O Draw the Bohr diagrams for the following elements;
X X 35 16 Cl O a) b) 17 8 X X X X X X X X 17p 18n X X X X X X X X X 8p 8n X X X X X X X
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ISOTOPES same # of protons, different # of NEUTRONS
different atoms of the same element have different masses The average mass of all the isotope weights is the exact atomic mass
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IONS same # of protons, different # of ELECTRONS
Different atoms of the same element having different CHARGES Positive ions = cations Negative ions = anions Notice that the number of energy level changes!!
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SUMMARY CHANGING PARTICLES
another Element Different Atomic # Changing #p changes the atom into a different element with a new atomic number Changing #n makes an ISOTOPE and changes the atomic mass Changing #e- makes an ION with a new charge Compound or molecule Ion new charge Isotope new atomic mass
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SUMMARY The Atomic Number of an atom = number of
protons in the nucleus; unique for each element The Atomic Mass of an atom = number of Protons + Neutrons in the nucleus. The number of Electrons = Number of protons in neutral atom. Electrons orbit the nucleus in energy levels. Each energy level can only carry a set number of electrons.
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