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1 Copyright© by Houghton Mifflin Company. All rights reserved.
Chapter 14 Liquids and Solids Copyright© by Houghton Mifflin Company. All rights reserved.

2 Figure 14.1: Representations of the gas, liquid, and solid states.
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3 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.2: Intermolecular forces exist between molecules. Bonds exist within molecules. Copyright© by Houghton Mifflin Company. All rights reserved.

4 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.3: (a) Interaction of two polar molecules. (b) Interaction of many dipoles in a liquid. Copyright© by Houghton Mifflin Company. All rights reserved.

5 Figure 14.4: Polar water molecules.
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6 Figure 14.4: Hydrogen bonding among water molecules.
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7 Figure 14.5: The boiling points of covalent hydrides.
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8 Figure 14.6: Atoms with spherical electron probability.
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9 14.6: The atom on the left develops an instantaneous dipole.
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10 Figure 14.6: Instantaneous dipole on A induces a dipole on B.
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11 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.7: The heating/cooling curve for water heated or cooled at a constant rate. Copyright© by Houghton Mifflin Company. All rights reserved.

12 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.8: Both liquid water and gaseous water contain H2O molecules. Copyright© by Houghton Mifflin Company. All rights reserved.

13 Figure 14.9: Microscopic view of a liquid near its surface.
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14 Figure 14.10: Behavior of a liquid in a closed container.
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15 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.11: (a) Measuring vapor of a liquid by using a simple barometer (b) The water vapor pushed the mercury level down (c) Diethyl ether shows a higher vapor pressure than water. Copyright© by Houghton Mifflin Company. All rights reserved.

16 Figure 14.12: Water rapidly boiling on a stove.
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17 Figure 14.13: Bubble expands as H2O molecules enter.
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18 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.14: The formation of the bubble is opposed by atmospheric pressure. Copyright© by Houghton Mifflin Company. All rights reserved.

19 Figure 14.15: Sodium and chloride ions.
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20 Figure 14.17: The classes of crystalline solids.
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21 Figure 14.18: Molecular representation of diamond.
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22 Figure 14.18: Molecular representation of sodium chloride.
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23 Figure 14.18: A molecular solid.
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24 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.19: The packing of Cl¯ and Na+ ions in solid sodium chloride. Copyright© by Houghton Mifflin Company. All rights reserved.

25 Copyright© by Houghton Mifflin Company. All rights reserved.
Figure 14.21: A representation of part of the structure of solid phosphorus. Copyright© by Houghton Mifflin Company. All rights reserved.

26 Figure 14.22: Molecular representation of brass.
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27 Figure 14.22: Molecular representation of steel.
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