1. Drill: Draw & name 5 isomers of C5H8

2. Review Drill & Test

3. 11)

4. 3 4 2
11) 1

5. 11) 1,2,4-trimethylbenzene 3 4 2 1

6. 12)

7. 12) 4-methyl-5-phenyl- 2-hexyne

9. 13) para-phenylcyclopropylbenzene

10. 14)

11. 14) trans-4-cyclobutyl-3-methyl-2-pentene

12. 15)

13. 15) cis-7-cyclohexyl-
3,5-dimethyl-3-octene

14. 16)
CH3-CH CH3
CH3-CH-CH-CH2-C-CH2-CH3
CH CH2-CH2-CH3

15. 16) 6-ethyl-3,4,6- trimethylnonane
CH3-CH CH3
CH3-CH-CH-CH2-C-CH2-CH3
CH CH2-CH2-CH3

16. 17)

17. 18)
CH CH CH3
CH C-CH2-CH-CH2-CH3
CH CH

18. 19) C C C C C C C C C C C C C

19. 20)

20. Functional Groups

21. Chm II/Org HW Review PP-40
Complete the attached assignment & turn it in tomorrow

22. Are there any questions on previous material?

23. Draw & Name Isomers of: C4H6

24. Chemically active part of an organic compound
Functional Groups
Chemically active part of an organic compound

25. Functional Groups
Anything other than singularly bonded carbon & hydrogen in an organic compound

26. Functional Groups
The name of any organic compound ends with the suffix for the most important functional group

27. Terminology
R- represents the part of the organic compound you are not referring to

28. -OH is the functional group
Terminology
R-OH
-OH is the functional group
R- anything else

29. Alkene
C=C

30. Alkyne
C=C

31. Halides
R-X
X = F, Cl, Br, or I
haloalkane
alkylhalide

32. Halides Cl
2-chlorobutane
2-butylchloride

33. Ethers
R1-O-R2
alkylalkylether
alkoxyalkane

34. Ethers
CH3CH2-O-CH3
Methylethylether
methoxyethane

35. Hydroxyl Group
C OH

36. Alcohols
R-OH
hydroxyalkane
alkanol

37. Alcohols
CH3-CH2-OH
hydroxyethane
ethanol

38. Carbonyl Group
C=O

39. Ketones O
R-C-R
Oxy or ketoalkane
alkanone

40. Ketones O
3-pentanone
3-oxypentane

41. Aldehyde O
R-C-H
alkanal
alkanaldehyde

42. Aldehydes O
hexanal
hexanaldehyde H

43. Homework
Draw & Name 5 isomers of C4H8O

44. Name the following:
OH Cl
CH CH
H3C CH2 CH3

45. Name the following:
OH Cl
CH CH
H3C CH2 CH3

46. 4-chloro-2-pentanol
OH Cl
CH CH
H3C CH2 CH3

47. Drill: Name the following:OH O

48. OH O

49. 2-hydroxy-4-hexanone
5-hydroxy-3-hexanone OH O

50. Review Drill & Check HW

51. Organic HW
Review PP-10
Complete the attached assignment & turn it in tomorrow.

52. Are there any questions on previous material?

53. Carboxyl Group
C=O HO

54. Carboxylic Acid O
R-C-OH
Alkanoic Acid

55. Carboxylic Acid O
CH3-CH2-C-OH
Propanoic Acid

56. Drill: Draw & name 5 isomers of:OH OH

57. Review & Collect Drill & HW

58. CHM II/ORG HW
Review PP 40
Complete the attached assignment & turn it in tomorrow.

59. Any Questions?

60. Functional Isomers: Isomers with different functional groups:
The suffix changes

61. Propanone Propanaldehyde

62. Positional Isomers: Isomer’s functional group in a new location
The # before the main chain name changes

63. OH
2-propanol 1-propanol OH

64. CH3-CH2-CH2-OH CH3-CH2-O- CH2-CH3 O CH3-CH2-C-CH2-CH3
Name the following:
CH3-CH2-CH2-OH
CH3-CH2-O- CH2-CH3 O
CH3-CH2-C-CH2-CH3

65. Name the following:
O O
C C
H3C CH OH OH

66. Name the following:
O O
C C
H3C CH OH OH

67. 2-hydroxy-3-ketobutanoic acid
O O
C C
H3C CH OH OH

68. Name the following: O
CH3-CH2-CH2-C-OH
CH3-CH2-C-H

69. Carboxyl Derivatives
C=O O

70. Esters O
R1-C-O-R2
Alkylalkanoate

71. Esters O
CH3-CH2-CH2-C-O-CH3
methylbutanoate

72. Alkanoicalkanoic anhydride
Anhydrides
O O
R1-C-O-C-R2
Alkanoicalkanoic anhydride

73. O O O
Butanoicpropanoic anhydride

74. Draw the following: 2-hydroxypentanal Methylpropylether
Trichloroethanoic acid
Ethylbutanoate
Aceticformic anhydride

75. Drill: Draw & Name 5 isomers of:
C3H6O2

76. Review Drill & Check HW

77. Organic HW
Review PPs 1-40
Begin the Final review attached to Poly’s Website

78. Name, then & Draw & name a Functional Isomer of:OH O C C C OH C C C

79. C OH O C C C OH C C C

80. 3-hydroxy-5- methylhexanoic acidOH O C C C OH C C C

81. 2,3-dihydroxy-5- methylhexanal(dehyde)C OH O C C C H C C C OH

82. 1,3-dihydroxy-5-methyl-2-hexanoneC OH C C C OH C C C O

83. Name & Draw 1 Positional Isomer of:C OH O C C C OH C C C

84. 2-hydroxy-5- methylhexanoic acidOH C C C OH

85. Name & Draw 1 Structural Isomer of:OH O C C C OH C C C

86. 3-hydroxyheptanoic acidOH O C C C OH C C

87. Name & Draw 1 Optical Isomer of:OH O C C C OH C C C

88. To draw an optical isomer, draw the mirror image of an assymetric compound

89. 3-hydroxy-5- methylhexanoic acidOH O C C C OH C C C

90. 3-hydroxy-5- methylhexanoic acidOH O C C C C HO C C

91. Draw: 2-phenylpropanoic acid 3-hydroxy-2-iodopentanal
2-cyclohexyl-3-octanone
phenylbutanoate

92. Drill: Name: Cl O OH C C C C C O

93. Cl O OH C C C C C O

94. 4-chloro-2-keto-3-
phenylpentanoic acid Cl O OH C C C C C O

95. Drill: Draw the following:
Butanoicpentanoic anhydride

96. O O C C C C C C O C C C

97. Review Drill & Check HW

98. Organic HW
Review PP-10
Complete the attached assignment & turn it in tomorrow.

99. Thiol
R-SH
Sulfhydrylalkane
Mercaptoalkane
Alkanethiol

100. SH
3-sulfhydrylpentane
3-mercaptopentane
3-pentanethiol

101. Sulfide
R1-S-R2
Alkylalkylsulfide
Alkylalkylthioether

102. Sulfide S
diethylsulfide
diethylthioether

103. Disulfide
R1-S-S-R2
Alkylalkyldisulfide

104. methylphenyldisulfide
S-S
methylphenyldisulfide C

105. Thioesters O
R1-C-S-R2
Alkylthioalkanoate

106. Thioesters O
CH3-C-S-CH3
Methylthioethanoate

107. Draw the Following: Methylthiobutanoate Methylphenyl ether
Diphenyl thioether
2-propanethiol

108. Name: SH OH C C C C C O Cl

109. SH OH C C C C C O Cl

110. 3-chloro-2-mercaptopentanoic acidSH OH C C C C C O Cl

111. Drill: Name: O C C C C C O

112. Name: O C C C C C O

113. Methyl-2-cyclohexyl butanoate

114. Check Drill & HW

115. CHM II/ORG HW Review PPs 22 – 40
Begin the Final Review attached to Poly’s Website

116. Amine Group N:

117. Ammonia
:NH3

118. Ammonium
NH4+

119. Primary Amines
R-NH2
Aminoalkane
alkylamine

120. Primary Amines
CH3-NH2
Aminomethane
methylamine

121. Secondary Amines R2
R1-NH
Alkylalkylamine

122. CH3
CH3-CH2-NH
methylethylamine

123. Alkylalkylalkylamine
Tertiary Amines R2
R1-N-R3
Alkylalkylalkylamine

124. CH2-CH3
CH3-N:
CH2-CH2-CH3
methylethylpropylamine

125. Quaternary Amines R2
R1-N-R3 R4
Tetraalkylammonium +

126. CH3
CH3-N-CH3
CH2-CH2-CH3 +
trimethylpropylammonium

127. CH3
CH3-N-H
CH2-CH2-CH3 +
dimethylpropylammonium

128. Amides O
R1-C-NH2
Alkanoamide

129. O
C-C-C-C-C
NH2
Pentanoamide

130. Nitrile
R-C=N
Cyanoalkane
Alkanonitrile

131. Nitrile
CH3-C=N
Cyanomethane
Ethanonitrile

132. Name: OH OH C C C C C O F

133. Name: OH OH C C C C C O F

134. 3-fluoro-4-hydroxypentanoic acid

135. Draw & name 10 isomers of:
C4H9NO

136. Draw the following:
2-phenyl-1-propanol
Butylethenyl ether

137. Draw the following: phenylthioacetate methylisopropylsulfide
2-mercaptobutanal

138. Name: C C S C C C O

139. Name: C C S C C C O

140. propylthioacetate C C S C C C O

141. Name: SH OH O OH

142. Name: SH OH O OH

143. 3-hydroxy-5-mercapto-6-methyl-7-phenyloctanoic acidSH OH O OH

144. Draw & name 10 isomers of:
C4H8SO2

145. Drill: Name O H O SH

146. Drill: Name O H O SH

147. 5-cyclohexyl-2-keto-3-mercapto-4-phenylpentanalSH

148. Homework
Draw & Name 5 isomers of C4H9NO2

149. Name N H OH C N H O

150. Name N H OH C N H O

151. 4-cyano-2-hydroxy-3-methylhexanoamide

152. Drill: Name OH Cl OH O

153. Name OH Cl OH O

154. 4-chloro-2-hydroxy-3-methylhexanoic acidCl N O

155. Return Tests, Review Drill, & Review Tests

156. Organic HW
Review PP-10
Complete the attached assignment & turn it in tomorrow.

157. Discuss Grades

158. Primary Amines
R-NH2
Aminoalkane
alkylamine

159. Secondary Amines R2
R1-NH
Alkylalkylamine

160. Alkylalkylalkylamine
Tertiary Amines R2
R1-N-R3
Alkylalkylalkylamine

161. Quaternary Amines R2
R1-N-R3 R4
Tetraalkylammonium +

162. Amides O
R1-C-NH2
Alkanoamide

163. Nitrile
R-C=N
Cyanoalkane
Alkanonitrile

164. Name N OH C
NH2 O

165. Drill: Name N HO C
NH2 O

166. trans-4-cyano-2-hydroxy-3-methyl-3-heptenoamideHO C
NH2 O

167. Cyanate
R-O-C=N
Alkylcyanate

168. Cyanate
O-C=N
cyclohexylcyanate

169. Isocyanate
R-N=C=O
Alkylisocyanate

170. Isocyanate
N=C=O
1-pentylisocyanate

171. Thiocyanate
R-S-C=N
Alkylthiocyanate

172. Thiocyanate
S-C=N
2-propylthiocyanate

173. Isothiocyanate
R-N=C=S
Alkylisothiocyanate

174. Methylisothiocyanate
CH3-N=C=S
Methylisothiocyanate

175. Lab: 05
Functional Groups Containing Nitrogen

176. Phosphates O
R-O-P-O-1
O-1
Alkylphosphate

177. Phosphates O
-O-P-O-1
O-1
Phenylphosphate

178. Diphosphates
O O
R-O-P-O-P-O-1
O-1 O-1
Alkyldiphosphate

179. Diphosphates
O O
CH3-O-P-O-P-O-1
O-1 O-1
Methyldiphosphate

180. Triphosphates
O O O
R-O-P-O-P-O-P-O-1
O-1 O-1 O-1
Alkyltriphosphate

181. Triphosphates
O O O
-O-P-O-P-O-P-O-1
O-1 O-1 O-1
2-butyltriphosphate

182. Methylethylphosphate
Phosphodiester O
CH3-CH2-O-P-O-CH3
O-1
Methylethylphosphate

183. Carboxylic acid Carboxylic acid derivative Aldehyde Ketone Alcohol Amine Thiol

184. Drill: Draw & Name 5 isomers of:
C3H7NO2

185. Drill: Name: OH O C OH Br
NH2

186. Name the following: OH O C OH Br
NH2

187. Draw & Name 5 isomers of: C3H6SO
Organic HW
Draw & Name 5 isomers of: C3H6SO

188. Drill:
Draw & Name 5 Isomers of:
C4H7NO

189. Lab: Today Review: Tomorrow Test : Wednesday

190. Name the following: N C O C
NH2 OH

191. Name the following: N C O C
NH2 OH

192. 3-cyano-2-hydroxy-7-methyl-6-phenyloctanoamide
NH2 OH

193. Drill: Name the following:Cl O C OH SH NH

194. Name the following: Cl O C OH SH NH

195. 2-amino-3-chloro-4-mercapto-N,7-dimethyl-6-phenylnonanoic acidCl O C OH SH NH

196. Test Tomorrow on Functional Groups

197. Name the following: O F OH

198. Name the following: O F OH

199. 3-fluoro-1-methoxy-4-methyl-2-cyclopropylhepta-5-yn-1-olOH

200. Name the following:
PO4-2 OH O O O

201. Name the following:
PO4-2 OH 1 2 O O O

202. 4-methyl-3-phenyl-2-phosphopentanoic-2-hydroxypropanoic anhydride
PO4-2 OH 1 2 O O O

203. Draw: 3-mercaptohexanoamide Methyl-2-hydroxythioacetate
Para-iodophenylformic acid
Phenylpropylamine
2-amino-3-ethyl-4-keto-N- methylhexanaldehyde

204. Draw & Name 10 isomers of:
C4H9SNO

205. Draw & Name 10 isomers of:
C4H9NO2

206. Name the following:
P3O10-4 NH

207. Name the following:
P3O10-4 NH

208. 4-amino-6,7-dimethyl-N-phenyl-3-octyltriphosphate
P3O10-4 NH

209. Name the following:
SH O H O

210. Name the following:
SH O H O

211. 3-mercapto-6,7-dimethyl-4-phenoxynonanal
SH O H O

212. Drill: Name: N C
NH2 O OH OH

213. Name: N C
NH2 O OH OH

214. 3-amino-5-cyano-4-hydroxyhexanoic acid
NH2 O OH OH

215. Name the following: N C S O O Br

216. Name the following: N C S 1 O O Br

217. propyl-4-bromo-3-cyclobutyl-5-thiocyanatohexanoateS 1 O O Br

218. Name the following: O Cl OH

219. Name the following: O Cl OH

220. 3-chloro-2-cyclopropyl-4-methylpentanoic acidOH

221. Drill: Name the following:

222. Drill: Name the following:1 O O F O 2

223. Methyl-3-fluoro-2-keto-4-methylpentanoate1 O O F O 2

224. Name the following: N C S OH O

225. Name the following: N C 1 S 2 OH O

226. Ethyl-2-cyano-3-hydroxythiohexanoate1 S 2 OH O

227. 3-methyl-5-propyl-octanoamide Octylbutanoate
Draw the Following:
3-methyl-5-propyl-octanoamide
Octylbutanoate

228. Draw the Following:
Aceticpentanoic anhydride
2-cyano-3-mercaptohexanoic acid

229. Drill Draw & name 5 isomers of:
C4H7NO

230. Draw:
Benzoic acid

231. 4-hydroxy-N-methyl-benzoamide
Draw:
4-hydroxy-N-methyl-benzoamide

232. Drill: Draw:
4-hydroxy-2-mercapto
pentanoic acid

233. Review

234. C=C

235. O
R C
O R

236. R N C O

237. R-SH

238. R-NH2

239. O
R C OH

240. O C
R R

241. R-OH

242. O O
C C
R O R

243. R C N

244. H
:N R R

245. O
R C
NH2

246. O
R C H

247. R O C N

248. R1-O-R2

249. R-I

250. R +
R N R R

251. C=C

252. R +
R NH R

253. R1-S-R2

254. O
R C
S R

255. R S C N

256. O -2
O P O R O

257. R
:N R

258. R-S-S-R

259. R N C S

260. Drill: Name:
NH2 OH O SH

261. Name the compounds on the board

262. Draw the compounds on the board

263. Draw & Name 10 isomers of C4H7SNO

264. C4H7NO