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Boltzmann Transport Equation for Particle Transport
Distribution Function of Particles: f = f(r,p,t) --probability of particle occupation of momentum p at location r and time t Equilibrium Distribution: f0, i.e. Fermi-Dirac for electrons, Bose-Einstein for phonons Non-equilibrium, e.g. in a high electric field or temperature gradient: Relaxation Time Approximation t Relaxation time
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Energy Flux Energy flux in terms of particle flux carrying energy:
q v Energy flux in terms of particle flux carrying energy: dk q k f Vector Integrate over all the solid angle: Scalar Integrate over energy instead of momentum: Density of States: # of phonon modes per frequency range
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Continuum Case BTE Solution: Quasi-equilibrium Direction x is chosen
to in the direction of q Energy Flux: Fourier Law of Heat Conduction: t(e) can be treated using Callaway method (Phys. Rev. 113, 1046) If v and t are independent of particle energy, e, then Kinetic theory:
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At Small Length/Time Scale (L~l or t~t)
Define phonon intensity: From BTE: Equation of Phonon Radiative Transfer (EPRT) (Majumdar, JHT 115, 7): Heat flux: Acoustically Thin Limit (L<<l) and for T << qD Acoustically Thick Limit (L>>l)
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Outline Macroscopic Thermal Transport Theory – Diffusion
-- Fourier’s Law -- Diffusion Equation Microscale Thermal Transport Theory – Particle Transport -- Kinetic Theory of Gases -- Electrons in Metals -- Phonons in Insulators -- Boltzmann Transport Theory Thermal Properties of Nanostructures -- Thin Films and Superlattices -- Nanowires and Nanotubes -- Nano Electromechanical System
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Thin Film Thermal Conductivity Measurement
3w method (Cahill, Rev. Sci. Instrum. 61, 802) Metal line Thin Film L 2b V I ~ 1w T ~ I2 ~ 2w R ~ T ~ 2w V~ IR ~3w I0 sin(wt) Substrate
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Silicon on Insulator (SOI)
Ju and Goodson, APL 74, 3005 IBM SOI Chip Lines: BTE results Hot spots!
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