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Chemical Bonding: PART 1 - IONIC
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Chemical Bond 8 Chemical bonding is the way atoms are attracted to each other to form compounds. Chemical bonding determines nearly all of the chemical properties we see in life. And as we know, the number “8” is very important to chemical bonding!
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Bonding Basics All atoms want to have a FULL outer energy level – just like the Noble Gases – because this means stability! Atoms want 8 valence electrons (except H & He who want 2 because 2 electrons mean FULL)
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Compound a pure substance formed by two or more elements Examples:
FeO2 – Rust HCl – An acid found in your stomach CH4 – A gas produced in your body (methane) CO2 – Soda pop bubbles (carbon dioxide)
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Compound a pure substance formed by two or more elements Examples:
NH3 – You’ll know this when you smell it (ammonia) C12H22O11 – It will make your life sweeter (table sugar) NaHCO3 – Something you’ll need to make good cakes and cookies (baking soda) C8H10N4O2 – This will give you some pep! (caffeine)
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Compound a pure substance formed by two or more elements Examples:
CO – A dangerous gas (carbon monoxide) H2SO4 – Acid found in car batteries CaCO3 – Used to write on a blackboard (calcium carbonate) H2O2 – Used to disinfect wounds (hydrogen peroxide)
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Valence Electrons How many valence electrons? What group number?
What family?
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Valence Electrons How many valence electrons? What group number?
What family?
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Valence Electrons How many valence electrons? What group number?
What family?
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All in the Family… Group 1: Alkali Metals
Group 2: Alkaline Earth Metals Groups 3-12: Transition Metals Group 13: Boron Group Group 14: Carbon Group Group 15: Nitrogen Group Group 16: Oxygen Group Group 17: Halogens Group 18: Noble Gases
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Electron Dot Diagrams…
H Mg B C N O Cl Ne
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Ionic Bonding In an Ionic Bond, electrons are lost or gained in order to reach a FULL outer energy level which results in the formation of Ions
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Positive Ions METAL elements LOSE electrons to form positive ions: cations It is easier to lose 1-2 electrons than gain 6-7 Groups 1,2,13
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Group 1 Imagine 2 children playing together and sharing their toys
A force that keeps the children together is their mutual attraction to the toys they share. In a similar fashion, two atoms can be held together by their mutual attraction for electrons they share A chlorine atom for example has a strong attraction for one additional electron to fill its outermost shell
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Group 2 Imagine 2 children playing together and sharing their toys
A force that keeps the children together is their mutual attraction to the toys they share. In a similar fashion, two atoms can be held together by their mutual attraction for electrons they share A chlorine atom for example has a strong attraction for one additional electron to fill its outermost shell
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Group 13 Imagine 2 children playing together and sharing their toys
A force that keeps the children together is their mutual attraction to the toys they share. In a similar fashion, two atoms can be held together by their mutual attraction for electrons they share A chlorine atom for example has a strong attraction for one additional electron to fill its outermost shell
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Negative Ions NON-METAL elements GAIN electrons to become negative ions: anions It is easier to gain 1-2 electrons than lose 6-7 Groups 15,16,17
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NaCl Na + Cl Na+ + Cl- How to Ionic Bond…
Metal + Non-metal (Metal always listed first) Opposite charges must balance + and - charges hold ions together Na + Cl Na+ + Cl- NaCl
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Opposites Attract!
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Becoming Potassium Fluoride:
K F
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Becoming Potassium Fluoride:
K F
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Becoming Potassium Fluoride:
K F
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Becoming Potassium Fluoride:
K F
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K+ F _ Becoming Potassium Fluoride:
The ionic bond is the attraction between the ________ ion (K+) and the ________ ion (F-) K+ F _ POSITIVE NEGATIVE
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Positive Ions
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NEXT SLIDE ADVANCED STUDENTS ONLY
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Electromagnetic Attraction
The + and – ions have an electromagnetic attraction (similar to static electricity).
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Electron Dot Diagram for Positive Ions (EDD for + Ions)
Metals have few valence electrons Point out metals on periodic table Mg
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Electron Dot Diagram for Positive Ions (EDD for + Ions)
Metals have few valence electrons Electrons are given away Mg Point out metals on periodic table
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Electron Dot Diagram for Positive Ions (EDD for + Ions)
Metals have few valence electrons Electrons are given away Positive Ions are formed Point out metals on periodic table Mg2+
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Examples of Positive Ions :
Li Li+ Group 1 Mg Mg+2 Group 2 Al Al+3 Group 13
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Electron Dot Diagram for Negative Ions (EDD for - Ions)
Non-Metals have more valence electrons Point out metals on periodic table P
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Electron Dot Diagram for Negative Ions (EDD for - Ions)
Non-Metals have more valence electrons Electrons are gained to fill outer energy shell Point out metals on periodic table P P
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Electron Dot Diagram for Negative Ions (EDD for - Ions)
Non-Metals have more valence electrons Electrons are gained to fill outer energy shell Point out metals on periodic table Negative Ions are formed P -3
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Examples of Negative Ions :
Group 15 S S-2 Group 16 I I- Group 17
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What about group 18? They rarely bond because they are already happy and stable with 8 valence electrons!
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Na+ + Cl- NaCl Putting Ions Together 1 to 1 ratios:
Groups 1 & 17 (Alkali Metals & Halogens) Na+ + Cl- NaCl
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Ca+2 + O-2 CaO Putting Ions Together
2.Groups 2 & 16 (Alkaline-Earth Metals & Oxygen Family) Ca+2 + O-2 CaO
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Na+ + O-2 Na2O Ca+2 + Cl- CaCl2 Putting Ions Together 2 to 1 ratios:
Groups 1 & 16 (Alkali Metals & Oxygen Family) Na+ + O-2 Na2O Groups 2 & 17 (Alkaline-Earth Metals & Halogens) Ca+2 + Cl- CaCl2
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Putting Ions Together Li+ + Br- LiBr K+ + Cl- KCl Mg+2 + F- MgF2
Lithium + Bromine Lithium Bromide K+ + Cl- KCl Potassium + Chlorine Potassium Chloride Mg+2 + F- MgF2 Magnesium + Fluorine Magnesium Fluoride Al+3 + I- AlI3 Aluminum + Iodine Aluminum Iodide
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Putting Ions Together Na+ + Cl- NaCl Ca+2 + O-2 CaO Ca+2 + Cl- CaCl2
Sodium + Chlorine Sodium Chloride Ca+2 + O-2 CaO Calcium + Oxygen Calcium Oxide Ca+2 + Cl- CaCl2 Calcium + Chlorine Calcium Chloride Na+ + O-2 Na2O Sodium + Oxygen Sodium Oxide
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Putting Ions Together Na+2 + F- SnF2 Sodium + Fluorine Tin Fluoride
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FINAL SLIDES ADVANCED STUDENTS ONLY
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Electron Energy The energy level relates to the amount of energy electrons have within the atom.
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What are the characteristics of electrons closer to the nucleus??
Farther away?? How does that affect bonding??
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Electron Energy
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Electrons FARTHEST from Nucleus Electrons CLOSEST to Nucleus
Electron Energy Electrons FARTHEST from Nucleus Electrons CLOSEST to Nucleus
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE Ability to remove electrons
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE Ability to remove electrons EASIER
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE Ability to remove electrons EASIER HARDER
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE Ability to remove electrons EASIER HARDER Amount of electron energy available for bonding
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE Ability to remove electrons EASIER HARDER Amount of electron energy available for bonding
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Electron Energy Electrons FARTHEST from Nucleus
Electrons CLOSEST to Nucleus Pull on electrons by positive nucleus LESS MORE Ability to remove electrons EASIER HARDER Amount of electron energy available for bonding
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BONDING REACTIVITY METALS NONMETALS
More reactive with MORE energy levels because WEAKER force pulling electrons into the nucleus More reactive the LOWER the element is in the group Group 1 MORE reactive than Group 2 because it is easier to remove 1 electron than 2 More reactive with FEWER energy levels because STRONGER force pulling electrons into the nucleus More reactive the HIGHER the element is in the group Group 17 MORE reactive than Group 16 because it is easier to gain 1 electron than 2
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Electron Energy
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Quote of the Day: “Equipped with his five senses, man explores the universe around him and calls the adventure Science.” ~Edwin Powell Hubble, The Nature of Science, 1954
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And Remember:
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Name (first AND last) Date Period
Head Your Papers! Name (first AND last) Date Period
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