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QM Review and SHM in QM Review and Tunneling Calculation.

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Presentation on theme: "QM Review and SHM in QM Review and Tunneling Calculation."— Presentation transcript:

1 QM Review and SHM in QM Review and Tunneling Calculation.
No quiz but some clicker questions. Read about the Schrodinger Equation in 3 dimensions and 3-D particle in a box for next time.

2 Review: The Schrödinger equation in 1-D: Stationary states
If a particle of mass m moves in the presence of a potential energy function U(x), the one-dimensional Schrödinger equation for the particle is If the particle has a definite energy E, the wave function Ψ(x, t) is a product of a time-independent wave function Ψ (x) and a factor that depends on time t but not position. For such a stationary state the probability distribution function |Ψ (x, t)|2 = |Ψ (x)|2 does not depend on time. The time-independent one-dimensional Schrödinger equation for a stationary state of energy E is

3 Review: Particle in a finite potential well I
A finite potential well is a region where potential energy U(x) is lower than outside the well, but U(x) is not infinite outside the well (see Figure below). In Newtonian physics, a particle whose energy E is less than the “height” of the well can never escape the well. In quantum mechanics the wave function of such a particle extends beyond the well, so it is possible to find the particle outside the well.

4 Particle in a finite potential well II
Figure (bottom left) shows the stationary-state wave functions Ψ (x) and corresponding energies for one particular finite well. Figure (bottom right) shows the corresponding probability distribution functions |Ψ (x)|2.

5 Application of QM potentials: QM semiconductor dots
Nanometer-sized (nm) particles of a semiconductor such as CdSe Discovered by Russian physicist Alexey Ekimov in St. Petersburg in1981 The fluorescence color under UV is determined by the size of the dot. (5-6 nm orange or red; 2-3 nm blue or green) Can be injected into patients for medical research and treatment (tagging and treating cancer cells). Also solar cell and computing applications

6 QM Potential Well Clicker
The first three wave functions for a finite square well are shown. The probability of finding the particle at x > L is A. least for n = 1. B. least for n = 2. C. least for n = 3. D. the same (and nonzero) for n = 1, 2, and 3. E. zero for n = 1, 2, and 3. Answer: A

7 QM Potential Well Clicker
The first three wave functions for a finite square well are shown. The probability of finding the particle at x > L is A. least for n = 1. B. least for n = 2. C. least for n = 3. D. the same (and nonzero) for n = 1, 2, and 3. E. zero for n = 1, 2, and 3. A look at |psi(x)|^2 plot on the right

8 Review: Potential barriers and tunneling
The figure (below left) shows a potential barrier. In Newtonian physics, a particle whose energy E is less than the barrier height U0 cannot pass from the left-hand side of the barrier to the right-hand side. Look at the wave function Ψ (x) for such a particle. The wave function is nonzero to the right of the barrier, so it is possible for the particle to “tunnel” from the left-hand side to the right-hand side.

9 Applications of tunneling
A scanning tunneling microscope measures the atomic topography of a surface. It does this by measuring the current of electrons tunneling between the surface and a probe with a sharp tip (see Figure below). An alpha particle inside an unstable nucleus can only escape via tunneling (see Figure on the right). UH Physics Professor Klaus Sattler has a scanning tunneling microscope

10 Example of tunneling calculation
Tunneling probability A 2.0 eV electron encounters a rectangle barrier 5.0 eV high. What is the tunneling probability if the barrier width is 0.50 nm ? Find G and κ

11 Example of tunneling calculation
Tunneling probability A 2.0 eV electron encounters a rectangle barrier 5.0 eV high. What is the tunneling probability if the barrier width is 0.50 nm ?

12 Example of tunneling calculation
Tunneling probability A 2.0 eV electron encounters a rectangle barrier 5.0 eV high. What is the tunneling probability if the barrier width is 0.50 nm ? Reducing the width L by a factor of two, increasing the tunnel probability of a factor of Exponential sensitivity in the barrier factor.

13 Clicker Tunneling Question
A potential-energy function is shown. If a quantum-mechanical particle has energy E < U0, it is impossible to find the particle in the region A. x < 0. B. 0 < x < L. C. x > L. D. misleading question—the particle can be found at any x Answer: D

14 Clicker Tunneling Question
A potential-energy function is shown. If a quantum-mechanical particle has energy E < U0, it is impossible to find the particle in the region A. x < 0. B. 0 < x < L. C. x > L. D. misleading question—the particle can be found at any x

15 A comparison of Newtonian and quantum oscillators
Let’s work out Ψ (x) for the QM harmonic oscillator.

16 A comparison of Newtonian and quantum oscillators
Let’s work out Ψ (x) for the QM harmonic oscillator. Why is (d) the only possibility ? (a), (b), and c all go to infinity or –infinity as xinfinity

17 A comparison of Newtonian and quantum oscillators
Using the boundary condition, we obtain Ψ (x) for the QM harmonic oscillator and its energy levels. These are the possible energies of the QM harmonic oscillator Note that ω=√(k’/m) but that n starts from n=0 ! (a), (b), and c all go to infinity or –infinity as xinfinity The ground state has n=0; no QM solution with energy equal to zero.

18 A comparison of Newtonian and quantum oscillators
Figure (below, top) shows the first four stationary-state wave functions Ψ (x) for the harmonic oscillator. A is the amplitude of oscillation in Newtonian physics. Figure (below, bottom) shows the corresponding probability distribution functions |Ψ (x)|2. The blue curves are the Newtonian probability distributions.

19 A comparison of Newtonian and quantum oscillators
Classical, confined to –A, A; QM SHM is different. 

20 Clicker question on QM Harmonic Oscillator
The figure shows the first six energy levels of a quantum-mechanical harmonic oscillator. The corresponding wave functions A. are nonzero outside the region allowed by Newtonian mechanics. B. do not have a definite wavelength. C. are all equal to zero at x = 0. D. Both A. and B. are true. E. All of A., B., and C. are true. Answer: D

21 A40.8 The figure shows the first six energy levels of a quantum-mechanical harmonic oscillator. The corresponding wave functions A. are nonzero outside the region allowed by Newtonian mechanics. B. do not have a definite wavelength. C. are all equal to zero at x = 0. D. Both A. and B. are true. E. All of A., B., and C. are true.

22 an infinitely deep square potential well (particle in a box)
QM Potential Wells A particle in a potential well emits a photon when it drops from the n = 3 energy level to the n = 2 energy level. The particle then emits a second photon when it drops from the n = 2 energy level to the n = 1 energy level. The first photon has the same energy as the second photon. What kind of potential well could this be? an infinitely deep square potential well (particle in a box) B. a harmonic oscillator C. either A. or B. D. neither A. nor B. Answer: B

23 A40.9 A particle in a potential well emits a photon when it drops from the n = 3 energy level to the n = 2 energy level. The particle then emits a second photon when it drops from the n = 2 energy level to the n = 1 energy level. The first photon has the same energy as the second photon. What kind of potential well could this be? A. an infinitely deep square potential well (particle in a box) B. a harmonic oscillator C. either A. or B. D. neither A. nor B.


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