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Chemical Reactions Text Reference: 8.2 (pg )
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Types: Synthesis Example C + O2 O C + O C General: A + B AB
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Types: Decomposition Example: NaCl Cl Na Cl + Na General: AB A + B
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Types: Single Replacement
Example: Zn + CuCl2 Zn Cl Cu + Cl Zn Cu + General: AB + C AC + B
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Types: Double Replacement
Example: MgO + CaS S O Mg Ca + O S Mg Ca + General: AB + CD AD + CB
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Types: Combustion CHO + O2 CO2 + H2O CH4 + O2 CO2 + H2O
CH3OH + O2 CO2 + H2O Reactants: always oxygen with another compound that contains hydrogen and carbon Products: always CO2 + H2O
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The Activity Series Text Reference: 8.3 (pg )
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We have looked at several reactions: Fe + CuSO4 Cu + Fe2(SO4)3
Li + H2O LiOH + H2 The activity series ranks the relative reactivity of metals. It allows us to predict if certain chemicals will undergo single replacement reactions when mixed. Metals near the top are most reactive and will replace metals near the bottom. K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au
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Q: Which of these will react? Fe + CuSO4 Ni + NaCl Li + ZnCO3
Al + CuCl2 K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au No, Ni is below Na Yes, Li is above Zn Cu + Fe2(SO4)3 Yes, Al is above Cu NR (no reaction) Yes, Fe is above Cu Zn + Li2CO3 Cu + AlCl3
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A: No for cold, yes if it is hot/steam Mg + H2O hot H2O H2 + Mg(OH)2
The reaction with H2O depends on metal reactivity & water temp. Q: will Mg react with H2O? K Na Li Ca Mg Al Zn Fe Ni Sn Pb H Cu Hg Ag Au cold H2O A: No for cold, yes if it is hot/steam Mg + H2O hot H2O H2 + Mg(OH)2 steam Q: Zn + HCl H2 + ZnCl2 acid Complete these reactions: Al + H2O(steam) Cu + H2O Na + H2O H2 + Al(OH)3 NR H2 + NaOH
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Other Activity Series Information
All metals will have a specific place in the activity series. For simplicity, only the most common metals are shown. The metals near the top of the activity series are more reactive because their valence electrons are more easily removed.
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Mg + AgNO3 Ag+ Mg(NO3)2 Cu + AgNO3 Ag+ Cu(NO3)2 Zn + AgNO3
Ag+ Zn(NO3)2 AgNO3 Zn + CuCl2 Cu + ZnCl2 Mg + CuCl2 Cu + MgCl2 CuCl2 NR Mg+ Fe(NO3)3 Fe+ Mg(NO3)2 Zn+ Fe(NO3)3 Fe+ Zn(NO3)2 Fe(NO3)3 NR
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Homework P. 264 #1-3 P. 267 #1-3
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