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Chapter 8 Chemical Reactions and Equations
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What does a chemical formula represent?
The elements contained in a chemical substance Indicates the number of atoms of the element just to the right of the element symbol a whole number that appears in front of a formula in a chemical equation. What is a subscript? What does it indicate? What is a coefficient?
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Coefficient means 2 molecules
Chemical Formulas 2 C8H18 Coefficient means 2 molecules indicates there are 8 Carbon atoms in the molecule indicates there are 18 hydrogen atoms in the molecule
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Visualizing Compounds Example: H2O
H atoms = ________ O atoms = ________ Model of H2O: 1
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What is a diatomic element?
An element with two atoms when it is by itself H2 O2 F2 Br2 I2 N2 Cl2 Hydrogen Molecule Oxygen Molecule
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DIATOMIC ELEMENTS You can also mark them off on your periodic table as the SUPER SEVEN! 7
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Symbolizes or represents a chemical reaction
When bonds are broken and new bonds are formed producing a new substance Chemical Equation Symbolizes or represents a chemical reaction
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Original substances in a chemical reaction
Reactants Original substances in a chemical reaction Products Substances formed in a chemical reaction REACTANTS yields PRODUCTS
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H2 + O2 H2O Reactants Product
Igniting a mixture of hydrogen and oxygen will form water. The symbol equation is: H O2 H2O Reactants Product
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How does a chemical reaction occur?
Atoms must collide for the reaction to occur Atoms are rearranged in a chemical change - None are lost - None are gained
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any reaction that gives off heat
Exothermic Reaction any reaction that gives off heat Example: 2H2 (g) + O2 (g) H2O (l) + heat
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heat + 2HgO (s) 2Hg (l) + O2 (g)
Endothermic Reaction any reaction in which heat is added Example: heat + 2HgO (s) Hg (l) + O2 (g)
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Evidence of a Chemical Change
Color change (THAT YOU DID NOT CAUSE!!) Temperature change Odor change Formation of a gas Formation of a precipitate precipitate: insoluble solid that separates out of solution
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Balancing Chemical Equations Notes
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A Chemical Reaction Potassium Iodide [KI] Lead Nitrate [Pb(NO3)2]
Final Product
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Did a chemical change occur? How do you know?
Is matter conserved in this reaction?
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According to the LAW OF CONSERVATION OF MATTER:
the total atoms of reactants must equal the total atoms of products [matter can’t be created or destroyed!] When you have a chemical reaction, you must add coefficients to balance the reaction!
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UNBALANCED! __H2 + __O2 __H2O Reactant Side Product Side 2 2 2 1
Atom Inventory __H __O2 __H2O Reactant Side Product Side Atom Type Number of Atoms H O UNBALANCED! 2 2 2 1
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To balance an equation, coefficients CAN be added in front of products or reactants. DO NOT CHANGE SUBSCRIPTS!
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UNBALANCED! New Atom Inventory 2 __H2 + __O2 __H2O Reactant Side
Product Side Atom Type Number of Atoms H O UNBALANCED! 2 4 2 2
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BALANCED! New Atom Inventory 2 2 __H2 + __O2 __H2O Reactant Side
Product Side Atom Type Number of Atoms H O BALANCED! 4 4 2 2
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Balancing Equations ___ Mg + ___ N2 ---> ___ Mg3N2 ___ H2S + ___ Cl2 ---> ___ S8 + ___ HCl ___ Al + ___ HCl ---> ___ AlCl3 + ___ H2 ___ Fe2O3 + ___ CO ---> ___ Fe + ___ CO2
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Classifying Chemical Reactions
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A + X AX Synthesis Two or more reactants combine to form ONE product.
(marriage) A + X AX example: 2Mg (s) + O2 (g) 2MgO (s)
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AX A + X Decomposition ONE reactant breaks down into smaller parts.
(divorce) AX A + X example: 2H2O (l) 2H2 (g) + O2 (g)
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A + BX B + AX Y + BX X + BY Single Displacement
A single element replaces an element that is part of a compound. A + BX B + AX Y + BX X + BY example: 2 Al(s) + 3 Fe(NO3)2(aq) Fe(s) + 2 Al(NO3)3(aq)
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AX + BY AY + BX Double Displacement
Ions from two different compounds exchange places to form two new compounds. (wife swap) AX + BY AY + BX 2KI(aq) + Pb(NO3)2 (aq) PbI2 (s) + 2KNO3 (aq)
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Combustion A compound (usually a hydrocarbon) reacts with oxygen, releasing carbon dioxide and water. AB + O CO2 + H2O example: combustion of propane C3H8 (g) + 5O2 (g) CO2 (g) + 4H2O (g)
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What is the activity series?
When elements are ranked in order of their relative reactivities
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Activity Series of the Elements
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1.Why is sodium not used for silverware?
It is highly reactive and reacts with water.
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2. Why has so much gold jewelry survived from ancient civilizations?
It is unreactive with oxygen or water and therefore does not readily break down.
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3. Why is food canned in containers made from steel coated with a thin layer of tin?
Steel makes a strong container and the tin lining does not react with the contents.
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To prevent the iron from rusting by being exposed to oxygen in air.
4. Why are cars painted? To prevent the iron from rusting by being exposed to oxygen in air.
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Writing Chemical Reactions Notes
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a word equation is qualitative
Word Equations word equation: equation in which the reactants and products in a chemical reaction are represented by words a word equation is qualitative example: methane + oxygen carbon dioxide + water
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a formula equation is quantitative
Formula Equations formula equation: represents the reactants and products of a chemical reaction by their symbols or formulas a formula equation is quantitative example: CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
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Symbols in a Chemical Reaction
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Writing Chemical Reactions
Steps to writing a reaction: Balance the equation. Fill in the phases of matter. Identify the reaction type.
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Example 1 Aluminum metal reacts with a solution of hydrochloric acid to produce hydrogen gas and aluminum chloride solution.
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Example 2 Magnesium metal burns in oxygen gas to produce solid magnesium oxide.
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Example 3 Hydrogen peroxide (H2O2) solution breaks down to produce oxygen gas and liquid water in the presence of the catalyst “catalase”.
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