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Published byIris Young Modified over 6 years ago
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Natural Radioactivity – Unstable Nuclei Emit Radiation
Spontaneous nuclear change to attain good n/p ratio. Form a new kind of atom. Each isotope or nuclide decays in a certain manner to get a better n/p ratio. The decay mode is named for the particle emitted. See Table N.
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Balancing Nuclear Equations
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Nuclear Equations Describe the decay process.
reactant or starting side (left) product or ending side (right). separates two sides
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Nuclear Equations - tasks
Have to identify type (out of 4) Have to balance to find 1 unknown term.
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Natural Transmutation – I.D.
1 term on the reactant side – starting isotope. 2 terms on the product side – ending isotope and emitted particle. Type of particle emitted is characteristic of the isotope – look up particle in Table N.
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Nuclear Equations Use conservation of atomic number & conservation of mass number to balance them. Mass number = left superscript. Atomic Number = left subscript.
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Writing Equations Write the equation for the decay of Thorium-232.
Use Table N to find the decay mode: Write the initial equation: 232Th 4He + X 90 2 Have to figure out what element it turned into.
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Alpha decay, Th-232 232Th 4He + YX 90 2 Z
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Alpha decay, Th-232 232 = 4 + Y so Y = 228
232Th 4He X Y Z 90 2 Conservation of Mass Number: The sum of the mass numbers on the left side must equal the sum of the mass numbers on the right side.
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Alpha decay, Th-232 so Z = 88 90 = 2 + Z
232Th 4He + 228X 90 2 Z 90 = Z so Z = 88 Conservation of Atomic Number: The sum of the atomic numbers on the left side must equal the sum of the atomic numbers on the right side.
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Alpha decay, Th-232 232Th 4He + 228X 90 2 88 Use the P.T. to find X:
X = Ra 232Th 4He + 228Ra 90 2 88
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Nuclear Equations If there is only 1 unknown term you can figure out what it is. Doesn’t matter which one isn’t known. Don’t forget – you can look up the decay mode in Table N. Decay mode means what particle is emitted.
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Write an equation for the decay of Am-241
so Y = 237 241 Am 4He + YX Z 95 2 so Z = 93 95 = Z What’s X? X = Np
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Write equations for α decay
218Rn + 4He 222Ra 208Po 256Lr 88 86 2 204Pb + 4He 84 82 2 252Md + 4He 103 101 2
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Writing equations for α decay
231Pa 225Ac 211Fr 185Au 227Ac + 4He 91 89 2 221Fr + 4He 89 87 2 207At + 4He 87 85 2 181Ir + 4He 79 77 2
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α decay 229Th + 4He 233U 149Gd 232Th 175Pt 237Np 90 2 92 145Sm + 4He 2 62 64 228Ra + 4He 88 2 90 171Os + 4He 76 78 2 233Pa + 4He 91 93 2
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α decay 234Th 144Nd 146Sm 151Ho 192Pt 4He + 230Ra 90 88 2
4He Ce 60 2 58 4He Nd 62 2 60 4He Tb 67 2 65 4He Os 78 2 76
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Radioactive Decay Series
Sometimes 1 transmutation isn’t enough to achieve stability. Some radioisotopes go through several changes before they achieve stability (and are no longer radioactive).
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Decay series for U-238.
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Decay series for Thorium-232
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Decay series for U-235
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Alpha Decay 238 = 238 = 92 =
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Positron Emission 1p 1n + 0e 1 +1
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Beta minus emission 1n 1p + 0e 1 -1
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14C 14N + 0e 6 7 -1 18F 18O + 0e 9 8 +1
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How does the mass number or atomic number change in (or or ) decay?
Just go to Table N, find an isotope that decays by alpha decay, write the equation, and see how the mass number (or atomic number) changes. 226Ra 4 + X so X has to be 222X X is Ra The mass number decreases by 4 and the atomic number decreases by 2. 2 86 88
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