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Isomerism and Functional Groups
Use the “molymod” kit to make the following: All the chain structural isomers (ie straight and branched structures) of propane (1 isomer) butane (2 isomers) pentane (3 isomers) Write a semi-displayed structural formulae and give the IUPAC name for each isomer.
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Functional Groups aldehyde O CH3CH2CH2C butanal H O ketone
CH3CH2CCH2CH3 O ketone pentan-3-one
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Functional Groups CH3 carboxylic acid O CH3CHCH2C
OH CH3 carboxylic acid 3-methylbutanoic acid CH3CH2C O OCH2CH3 ester ethylpropanoate
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Functional groups alcohol alkene ester ketone carboxylic acid
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carboxylic acid ester ether aldehyde amine nitrile
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Epoxyethane General reaction for addition across epoxyethane: H2C CH2
+ ROH ROCH2CH2OH with excess ROH RO H RO H ROH H2C CH2 O H2C CH2 O R is H i.e.HOH water or alkyl R i.e.ROH alcohol
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Hydrogen bromide Electrophilic addition of HBr to trans but-2-ene: H C
CH3 H C CH3 H C + carbocation + - Br H Br - CH3 H C Br 2-bromobutane
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