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Ch. 7 Bonding 7.2ish Types of Bonds
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Metal(M), Nonmetal(NM), Semi- metals (SM)
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Ionic Bonds Atoms gain or lose electrons to form charged ions.
+/- attraction creates electrostatic attraction to form bond Recognize by Metal with a Nonmetal (M/NM) Ex: NaCl AlBr3 MgSO4 NH4Cl Ionic Compounds are also called salts
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Metallic Bonds Metallic bonds explain why metals have the properties they have (shiny, etc) Bonds can occur within an element or Alloy Alloy is a mixture of 2 or more metals Stainless steel, bronze, brass, etc. In metallic bonds v.e. are mobile (like a “sea” of e-. V.E. can float between atoms.
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Covalent or Molecular Bonds
Atoms share v.e. to obtain octet rule. Covalent bond or molecular bond (interchangeable) Recognize by Nonmetal and Nonmetal (NM/NM) Ex: CO NH H2O Biological Molecules are covalent Ex: C6H12O amino acids Diatomic molecules are covalent (N2, O2, F2, Cl2, Br2, I2)
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Ionic Compounds Properties
Most are crystalline solids at room temp. High melting and boiling points They are electrolytes (conduct e- in water)
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Molecular Properties Tend to be liquids or gases at room temp.
Lower melting/boiling point than Ionic Non-electrolytes (doesn’t conduct e- in water) Some elements tend to be Diatomic Diatomic elements come in pairs when not in compound “Scared 7” N2, O2, F2, Cl2, Br2, I2, H2
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Element Ion formula and charge Ion name Lewis dot structure of atom # of valence e- in atom Cation or anion? Tin-lost 2 e- X Potassium nitrate Chlorine Manganese (lost 1 e-) Zinc sulfite Sulfur Phosphorus Cyanide Ammonium Strontium Iron (lost 3 e-) Silver Aluminum Fluorine Calcium acetate Copper (lost 2 e-) Carbonate
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Ch. 7 Bonds 7.1 Recap of Ions
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IONS Valence Electrons (v.e.): used in bonding
Group number = valence electrons Cations: + ions; lose e- Anions: - ions; gain e- Polyatomic Ions: group of atoms with a charge Octet Rule: compounds form so atoms can achieve a noble gas configuration (8 v.e.)
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Ions on the Periodic Table
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Naming Ions Cations(group 1A,2A,3A): name element off P.T. and add “ion” Mg+2 = Magnesium Ion Anions: Name element off P.T. BUT change ending to “ide” then add “ion” O-2 = Oxide ion Transition Metals: have multiple charges (all +) so charge is represented by a Roman Numeral. Mn+2 = Manganese II Ion; Mn+3 =Manganese III ion Polyatomic Ions: groups of atoms w/ a charge NO3- = nitrate *** memorize***
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Group 1A,2A,3A (all cations): name only
*Group 1A,2A,3A (all cations): name only *Group 5A,6A,7A (all anions): end –ide Transition (cations): charge variable so Roman Numeral
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Polyatomic Ions Most are anions Most have oxygen
They end in –ate, ite, occasionally -ide
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Ion formula Ion Name LDS V.E. Cation or Anion? Lead: lost 4e- Sodium
Element Ion formula Ion Name LDS V.E. Cation or Anion? Lead: lost 4e- Sodium Iodine Pb+4 X Cation Lead IV X Na+ 1 Cation Sodium I- 7 Iodide Anion
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Naming and Writing Ionic Compounds Ch. 7/9
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Writing Formulas Charges must add up to 0; compounds are neutral
Write down ions with charges Find common multiple so charges cancel The multiplier becomes subscripts Example: Magnesium Iodide = Mg+2, I- Common multiple is 2, so for Mg 1 is multiplier; for I- 2 is multiplier Formula is MgI2
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Your Turn Write formulas of the following ionic compounds:
Potassium sulfate Zinc phosphide Manganese II carbonate
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Naming Ionic Compounds
Split compound into Cation/Anion (2 ions) Metal/Non-metal Name cation using periodic table. If representative (1A,2A,3A); just name If transition: determine charge. Charge becomes Roman Numeral after name Name Anion: If representative (5A,6A, 7A), change ending to –ide If polyatomic, name from memory Put 2 ion names together (generally ONLY 2 names)
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Example for Naming Ca(NO3)2 Ca NO3
Ca is representative so just Calcium Anion is polyatomic = nitrate Calcium Nitrate
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Your Turn: Name: AlCl3 Mn2O3 CdCl2 K2SO4
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