1. Physical Chemistry (I)
화학과
박영동 교수

2. Contents of Atkins’ Physical Chemistry
Part 1- Thermodynamics(Chap 1-6)
Part 2- Structure(Quantum theory and spectroscopy, Statistical thermodynamics etc.)
Part 3- Change(Chemical kinetics: chap 19-22)
Thermodynamics
Matter in bulk
Macroscopic view
Quantum theory
Individual atoms and molecules
‘structure of molecule’
Microscopic (molecular) view
Statistical Mechanics
Provides the link between the microscopic properties of matter and its bulk properties

3. Part 1. Thermodynamics
Thermodynamics: the science of the transformation of energy
Heat
Energy
Temperature
Direction of Nature and Equilibrium
Qualitative and Quantitative description

4. Thermodynamics
→ Describes macroscopic properties of equilibrium systems
→ Entirely empirical
→ Built on 4 laws and “simple” mathematics
0th Law ⇒Defines temperature (T)
1st Law ⇒Defines energy (U)
2nd Law ⇒Defines entropy (S)
3rd Law ⇒Gives numerical value to entropy
These laws are UNIVERSALLY VALID, they cannot be circumvented.

5. Part 1. Thermodynamics 1. The properties of gases 2. The first law
3. The second and third laws
4. Physical transformations of pure substances
5. Simple mixtures
6. Chemical equilibrium

6. Foundations A. Matter 1.Atoms 2.Molecules
3.Bulk matter – properties: mass, volume, amount of substances,…
B. Energy
1.Force
2.Energy
3.The relation between molecular and bulk properties
C. Waves
1.Harmonic waves
2.The electromagnetic field

7. A. Matter 1. Atoms (a) The nuclear model (b) The periodic table
(c) Ions
2. Molecules
(a) Lewis Structure
(b) VSEPR theory
(c) Polar bonds
3. Bulk matter
(a) properties: mass, volume, amount of substances,…
(b) perfect gas equation

8. B. Energy 1. Force (a) Momentum (b) Newton’s second law of motion
(a) Work
(b) Definition of energy
(c) Coulomb potential energy
(d) Thermodynamics
3. The relation between molecular and bulk properties
(a) The Boltzmann distribution
(b) Equipartition

9. Tentative Course Schedule, 2017-1주별
교수내용
비고(Recommended Problems) 01
Chap.1- the properties of gases
1A.1, 1A.8, 1A.10, 1B.4, 1B.12, 1C.2, 1C.11, 1C.16 02
Chap.2- The First Law
2A.1, 2A.3, 2B.2, 2B.3, 2B.4 03
2C.4, 2C.9, 2C.10 04
Chap.2- The first law
2D.4, 2D.6, 2D.10, 2E.1
3월 29일(수)
quarterly exam.1 (Chap.1-2)
20% 05
Chap.3- The second law
3A.1, 3A.2, 3A.4, 3A.6, 3A.10, 06
3B.5, 3B.8, 3C.3 07
3D.3, 3D.6, 3D.7, 3D.9 08
mid term -exam. 2(4월 20-26일 중)
25% 09
Chap.4-physical transformations properties of pure substances
4B.1, 4B.2, 4B.3, 4B.4, 4B.11, 4B.12, 4B.17, 4B.18
Integrated activities: 4.1, 4.3, 4.5 10
Chap.5-Simple mixtures
5A.5, 5B.1, 5B.4, 5B.9, 5B.10 11
5C.3, 5C.4, 5C.5, 5C.6, 5C.7, 5C.8, Integrated activities: 5.5, 5.8, 5.10, 5.11
5월22(월)
qurterly exam. 3 - Chap 1-8 12
Chap.6-chemical equilibrium
6B.1, 6B.2, 6B.5, 6B.8, 6B.9, 6C.1, 6C.2, 6C.3, 6D.2 13
6B.1, 6B.2, 6B.5, 6B.8, 6B.9 14
Chap.6-equilibrium electrochemistry
6C.1, 6C.2, 6C.3, 6D.2 15
Integrated activities: 6.3, 6.7, 6.9, 6.10, 6.12 16
Exam 4- during final exam period(6월 16-22일 중)
30%