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Alkene Preparation Reactions

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Presentation on theme: "Alkene Preparation Reactions"— Presentation transcript:

1 Alkene Preparation Reactions
Alkyne reductions Syn orientation Anti orientation Elimination reactions Alcohol dehydration Alkyl halide dehydrohalogenation Vicinal dihalide dehalogenation

2 Alkenes via Alkyne Reduction
Syn reduction of Alkynes to Alkenes Catalytic Hydrogenation using a poisoned catalyst Anti reduction of Alkynes to Alkenes Dissolving Metal reduction

3 Alkenes via Alkyne Reduction

4 Alcohol Elimination E-1 Unimolecular kinetics
Carbocation intermediates Skeletal rearrangements possible

5 Alkenes via Alcohol Dehydration

6 Dehydrohalogenation of Alkyl Halides
Unimolecular versus Bimolecular elimination

7 Bimolecular Dehydrohalogenation of Alkyl Halides
Periplanar anti-elimination

8 Dehalogenation of Vicinal Dihalides
Bimolecular kinetics Periplanar Anti-orientation No skeletal rearrangements possible

9 E-2 Dehalogenation of Vicinal Dihalides
Periplanar anti-elimination

10 Alkyne Preparation Reactions
Elimination Vicinal tetrahalide dehalogenation Vicinal dihalide dehydrohalogenation Substitution Alkynyl anion synthesis

11 Vicinal Tetrahalide Dehalogenation

12 Vicinal Dihalide Dehydrohalogenation

13 Substitution Alkynyl Anion Synthesis of Alkynes via Bimolecular Nucleophilic Substitution


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