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The Application of Ultraviolet/Visible Spectroscopy to the Study of Surface Astrochemistry
James W. Stubbing, Tara L. Salter, Wendy A. Brown, Skandar Taj and Martin R. S. McCoustra
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Introduction Simulate conditions of the ISM
T ≈ 24 K p ≤ 2.0 × mbar Adsorb molecules onto surfaces HOPG Silica Interstellar processing of ices Thermal Bombardment Irradiation Spectroscopically RAIRS
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New UV/vis Setup
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Determine values of n and k
Why? Determine values of n and k
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How? Determined values of n and k iterate
Fit using Fresnel equations and Kramers-Kronig relation Compare simulated spectrum to experiment Measure reflectance Model R’ Determined values of n and k θ, ν, d R R’ θ, ν, d θ, ν, d R θ, ν, d iterate
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