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Acids and Alkalis Grade 10
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Acids Sour Turn litmus red pH less than 7 Dissolve carbonate rocks
Corrode metals Conduct electricity
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Acids Acids are substances that give H+ ions when added to water.
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Alkalis Bitter Turn litmus blue pH greater than 7 Slippery caustic
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Alkalis An alkali is a substance that gives OH- ions when added to water
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Neutralizations reactions
Acids and alkalis neutralize each other to form a salt Example: HCl + NaOH NaCl + H2O Reactions of acids and alkalis are called neutralization reactions
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Neutralization examples
Indigestion is caused by too much amounts of hydrochloric acid in the stomach. It is cured by indigestion tablets. Indigestion tablets contain magnesium oxide that neutralises the excess HCl.
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Neutralization examples
Fields with acidic soil can be improved by adding lime. The lime contains calcium hydroxide Ca(OH)2 which is an alkali
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Neutralization examples
Lakes affected by acid rain can be neutralized by adding lime.
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Strong vs. weak Strong = complete dissociation
Example, when HCl is dissolved in water, all of it becomes H+ + Cl HCl, H2SO4, HNO3 HCl H+ + Cl- H2SO4 2H+ + SO4 2- Weak = incomplete dissociation Acetic acid (vinegar) is a weak acid CH3COOH, small amounts dissociate into H+ and CH3COO CH3-COOH, H2CO3, HF CH3COOH CH3COO H+ More dissociation = stronger acid
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Strong bases dissociate completely
NaOH, KOH, Ca(OH)2 NaOH Na OH- Weak bases dissociate partially Mg(OH)2, Fe2O3, NH4OH NH4OH NH OH- If a base is soluble in water, it is called an alkali. NaOH, KOH
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Strong and weak bases Strong bases ionises completely NaOH Na+ + OH-
NaOH, KOH, Ba(OH)2, Ca(OH)2 Weak bases ionises partially Mg(OH)2, CuO, Al2O3, NH4OH Strong acids have a small pH strong bases have large pH Neutral solutions have pH 7 Smaller the pH, stronger the acid Larger the pH, stronger the base
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Indicators Indicators are substances that change
colour when placed in an acid or an alkali. There are four important indicators: Methyl orange Phenolphthalein Litmus paper Universal indicator.
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Procedure:. put 3 cm3 of HCl in a test tube
Procedure: put 3 cm3 of HCl in a test tube. Add few drops of methyl orange. record your observation. Methyl orange Phenolphthalein Litmus paper Universal indicator HCl Red Colourless NaOH Orange/yellow Pink Blue Purple/violet
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REACTIONS OF ACIDS Neutralisation
Acid reacts with a base to form salt and water. Base can be a metal oxide or metal hydroxide. Ammonium hydroxide is also a base. Calcium oxide + Nitric acid Calcium nitrate + water CaO + HNO3 Ca(NO3)2 + H2O Copper(II) oxide + Hydrochloric acid Copper(II)chloride + water CuO + HCl CuCl2 + H2O Sodium hydroxide + Sulphuric acid Sodium sulphate + water 2NaOH + H2SO4 Na2SO4 + 2H2O Ammonium hydroxide + hydrochloric acid Ammonium chloride + water NH4OH + HCl NH4Cl + H2O
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Acid reacts with metals to form salt and hydrogen gas
Most metals react with dilute acids to form salt and hydrogen Copper, Silver, Gold etc do not react with acids easily because these metals are not reactive. Magnesium + sulfuric acid Magnesium sulfate + Hydrogen Mg + H2SO4 MgSO4 + H2 Zinc + Hydrochloric acid Zinc chloride + Hydrogen Zn + HCl ZnCl2 + H2 Acids react with carbonate to form salt, carbon dioxide and water Sodium carbonate + Hydrochloric acid Sodium chloride + Carbon dioxide + water Na2CO HCl NaCl + CO2 + H2O Copper(II) carbonate + sulphuric acid Copper(II) sulphate + Carbon dioxide + water CuCO3 + H2SO4 CuSO4 + CO2 + H2O
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Salts Salts formed from an acid and a base.
First part of a salt is from the base (+) Second part from the acid (-) For example, Sodium chloride is a salt. Sodium part comes from a base like sodium hydroxide. Chloride part comes from an acid (hydrochloric acid) Second part of the salt depends on the acid. Hydrochloric acid HCl chloride Cl (-) Sulphuric acid H2SO4 - sulphate SO4 (2-) Nitric acid HNO nitrate NO3 (-) Carbonic acid H2CO carbonate CO3 (2-) Phosphoric acd H3PO phosphate PO4 (3-)
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How to make salts? Acid react with metal
Example: Making Zinc sulphate. Take sulphuric acid in a beaker. Add excess zinc and warm the mixture. Wait until no more bubbles come out. Cool the mixture and filter to get rid of excess Zinc. Take the filtrate in an evaporating dish, heat and evaporate until crystallisation point. Cool it in room temperature to get the crystals of Zinc sulphate.
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Two soluble chemicals Best example is acid and alkali reaction(neutralisation) and a salt is made. Example: When hydrochloric acid and potassium hydroxide solution are mixed, we can make Potassium chloride salt. KOH (aq) + HCl (aq) KCl (aq) + H2O (l) First conduct a titration to know what volume of acid and base exactly required for neutralisation. Then mix acid and base in larger volume in the same ratio you found in the titration for complete neutralisation. Heat and evaporate the resulting solution until crystallisation. Cool it to get the crystals of potassium chloride.
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Double decomposition or Precipitation.
This method is useful to make a salt which is insoluble in water. For example to make calcium carbonate salt which is insoluble. Mix solutions of sodium carbonate and calcium chloride; both soluble and the calcium carbonate precipitates. Na2CO3 (aq) + CaCl2 (aq) CaCO3 (s) + 2NaCl (aq) When two soluble salt solutions when mixed, the insoluble salt is precipitated out. The mixture is then filtered and the solid salt is left for drying.
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Soluble and insoluble Following statements help you to identify if a chemical can dissolve in water or not. All compounds of SODIUM, POTASSIUM and AMMONIUM are soluble in water. All NITRATE compounds are soluble. All CHLORIDES are soluble except Silver chloride and Lead(II) chloride. All SULPHATES are soluble except Barium sulphate and Lead(II) sulphate. All CARBONATES are insoluble except sodium carbonate, potassium carbonate and ammonium carbonate. All metal oxides and metal hydroxides are insoluble in water except sodium, potassium and calcium oxide/hydroxide.
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Soluble or insoluble??? Sodium carbonate Na2CO3 Soluble
Copper(II) sulphate CuSO4 Lead(II) chloride PbCl2 Insoluble Silver sulphate Ag2SO4 Barium chloride BaCl2 Ammonium sulphate (NH4)2SO4 Iron(III) oxide Fe2O3
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Copper(II) hydroxide Cu(OH)2
Insoluble Silver chloride AgCl Barium sulphate BaSO4 Lead(II) nitrate Pb(NO3)2 Soluble Sulphuric acid H2SO4 Potassium chloride KCl Calcium sulphate CaSO4 Magnesium carbonate MgCO3
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THE END
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