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Definition of Corrosion
Corrosion is the deterioration of materials by chemical interaction with their environment. The term corrosion is sometimes also applied to the degradation of plastics, concrete and wood, but generally refers to metals.
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Anodic & Cathodic Reactions
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Effects of corrosion Losses are economic and safety
Reduced mechanical properties Downtime of equipment Leak of fluids Reduced value of goods
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Uniform Corrosion: Rust!
FORMS OF CORROSION Uniform Corrosion: Rust! Prevention: Paint Cathodic Protection
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FORMS OF CORROSION Galvanic Corrosion Causes: Dissimilar metals
Prevention: Choose metals close in galvanic series Have large anode/cathode ratios Insulate dissimilar metals Cathodic protection Described by Galvanic Series
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Pitting and Creviced Corrosion
FORMS OF CORROSION Pitting and Creviced Corrosion Causes: concentration gradients in electrolyte cause some areas high in ion concentrations that accelerate oxidation Prevention: Weld – don’t rivet Use non-absorbing gaskets Polish surfaces Avoid stagnant water
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FORMS OF CORROSION Intergranular corrosion Stress corrosion Erosion
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Corrosion prevention Applied Voltage Sacrificial Anode
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Corrosion prevention Surface coatings & Passivation
Some materials, such as Aluminum or Stainless Steel, form oxide barrier coatings that prevent oxidation at active surface – this is called “passivation” Surface can be coated with protective layers: painted, anodized, plated.
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Corrosion prevention Design of structures Material selection
Control the environment Inhibitors Protective Coatings
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