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New Generation Fibers Dr B L Deopura IIT Delhi
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INTRODUCTION Most exciting starting materials
Winning as well as loosing stories The advent of new fibres Assemble into almost infinitely different ways Materials with distinguishing characteristics can be produced
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A large number of fibers
Kevlar Carbon HP Polyethylene M5 PBO PBI PEEK Glass Basalt Cotton Wool Silk PET PPT Nylons Polypropylene
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More Types of fibers PLA PCL PVA PVDC PBT Nylon 11
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Modified Fibers Hollow Porous Fibers Profile Fibers
Surface Modified fibers Nano incorporated Fibers Polymer Blended Fibers Color Changing Fibers Shape changing Fibers Fragrance Fibers Environmental Sensitive Fibers Electrically Conducting Fibers
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KEVLAR FIBRE
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KEVLAR Aromatic polyamide Very high strength and modulus
Excellent toughness – difficult to cut Highest tensile strength to weight ratio amongst current reinforcing fibres
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Bullet proof vests (non-composite)
Aramid has negative CTE, Zero thermal expansion of composites, applications limited due to moisture sensitivity; Leading edges of wings in aircraft, Ballistic Armor, Sporting- goods, Break lining, marine, soft and light weight body armours.
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Poly (p-phenylene benzobisoxazole) PBO
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Poly (p-phenylene benzobisoxazole) PBO
Flame resistance and high thermal stability Good resistance to creep, chemical and abrasion Excellent high energy absorption High impact resistance
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APPLICATIONS Heat/flame resistant work wear e.g. fire fighters
For ballistic protection Heat resistant felts~ conveyor belts (hot fabrication) Reinforcement~ tyres, belts,cords Optical fibre cables ( good dielectric properties) Hot gas filters
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M5 FIBRE Polyhydroquinone diimidazopyridine
Most fire resistant organic fibre High tensile strength and modulus Excellent UV stability
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Properties
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BASALT FIBRE:ALTERNATIVE TO GLASS
Material from lava flow Minerals: Plagioclase, pyroxene and olivine; Basalt formations in the Ukraine are particularly well suited to fiber processing
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Properties It is similar to glass fiber Tensile strength 4.84 Gpa
Elastic modulus 89 GPa Elongation at break 3.15 % Density 2.7 g/cm³ Good electrical insulation Highly flame retardent
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Tissue Engineering Textile fibers for human organs
Produced from biocompatible and degradable polymers like PLA,PCL The process involves culturing and growing living cells, taken from human organs, on a textile scaffold, to the desired 2-dimensional and/or 3-dimensional shapes.
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Polycaprolactone Fibres
Fully biodegradable. Suture Tissue engineering –Cell culture Body implants Drug delivery device A distinguishing feature of these fibres is that crystalline region is deformable.
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Polylactic Acid (Pla) Fibres
Excellent wicking property Good UV resistance Biodegradable Ecofriendly Spun bonded, industrial and household wipes. Hygiene and filtration areas.
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APPLICATIONS Fire resistant panels and components
Fire proof textile Fire resistant panels and components For Friction applications Composite brake pads Used in some parts of Wind blade Used as a reinforcement Concrete reinforcement rods(Pultruded) Used to make camera tripods and heads Snowboard composite brake pads, because it does not soften at elevated temperatures and won't deposit on its counterpart (either the disc or brake drum) in the braking system.
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FIBRES WHICH DON’T MAKE IT
1 Polybutylene Terepthalate (PBT) Excellent elastic recovery Dyeing at Boiling water High raw material cost PPT did made it
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2 Polyvinylidene chloride PVDC Copolymer (Saran)
Low permeability to a wide range of gases and vapours Self extinguishing
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ASSEMBLING OF FIBRES There are various ways in which the fibres can be assembled such as yarn ,woven structures, nonwoven structures etc. Depending upon the particular application, particular form is used. Each form has its own distinguishing properties.
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AFTER TREATMENTS There are many after treatments such as: drawing,
heat setting etc. which brings about a dramatic change in properties.
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EXAMPLE……. Polyethylene tape fabric Apply heat and pressure
Sheet like structure Single polymer Composite Polyethylene terepthalate Polypropylene Nylon, PEEK, PCL
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Ref: http://speautomotive.com/SPEA_CD/SPEA2002/pdf/a01.pdf
Schematic of the Composite formation Composite cross section by SEM Some products from SPC Ref:
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Thanks!
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