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Faceted Crystals Grown from Solution

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1 Faceted Crystals Grown from Solution
A Stefan Type Problem with a Singular Interfacial Energy Yoshikazu Giga University of Tokyo and Hokkaido University COE Joint work with Piotr Rybka December , 2005 Lyon

2 A basic problem from pattern formation in the theory of crystal growth
A basic problem from pattern formation in the theory of crystal growth. In what situation a flat portion (a FACET) of crystal surface breaks or not ? Goal : We shall prove : ‘All facets are stable near equilibrium for a cylindrical crystal by analysizing a Stefan type problem’

3 Contents 1 Model 2 Problem 3 Main mathematical results
4 Three ingredients - ODE analysis - Berg’s effect - Facet splitting criteria- 5 Open problems

4 1 Model Crystals grown from vapor (snow crystal)
from solution (NaCl crystal) <driving force : supersaturation> (density of atoms outside crystal is small)

5 Stefan like Model

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7 unnormalized version :

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10 One phase Stefan problem with Gibbs-Thomson + kinetic effect
We shall consider (1)-(5) for given quasi-stationary One phase Stefan problem with Gibbs-Thomson + kinetic effect

11 K. Deckelnik - C. Elliott ’99 ( Hele Shaw type )
Solvability (smooth ) K. Deckelnik - C. Elliott ’99 ( Hele Shaw type ) No   … Friedman –Hu ’92   Liu – Yuan ’94

12 Kuroda-Irisawa-Ookawa ‘77 Stability of facets Experiment e.g.
Others (No ) Kuroda-Irisawa-Ookawa ‘77 Stability of facets Experiment e.g. Gonda-Gomi ’85 (No ) : Fingering : Saffman-Taylor R.Almgrem ’95

13 2.Problem (specific to ours)

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19 3. Main Math Results

20 Th (Rybka-G ‘04) If is close to the Equilibrium then the solution solves the original problem (1),(2),(3), (4),(5),(6),(7) Near equilibrium Facet does not break.

21 Reduction to ODE

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27 Near equilibrium : close to zero / bounded away from zero

28 5. Open problems Existence of solution of the Original
problem is widly open if is not near equilibrium (Even if is given M.-H. Giga – Y. Giga ’98 graphs) ( : constant M.-H. Giga – Y. Giga ‘01 level set approach : unique existence of generalized sol (2-D)) Uniqueness of the solution of the original problem (Sol is unique for Reduced problems)

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30 All my preprints are in Hokkaido University Preprint Series on Math.


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