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Faceted Crystals Grown from Solution
A Stefan Type Problem with a Singular Interfacial Energy Yoshikazu Giga University of Tokyo and Hokkaido University COE Joint work with Piotr Rybka December , 2005 Lyon
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A basic problem from pattern formation in the theory of crystal growth
A basic problem from pattern formation in the theory of crystal growth. In what situation a flat portion (a FACET) of crystal surface breaks or not ? Goal : We shall prove : ‘All facets are stable near equilibrium for a cylindrical crystal by analysizing a Stefan type problem’
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Contents 1 Model 2 Problem 3 Main mathematical results
4 Three ingredients - ODE analysis - Berg’s effect - Facet splitting criteria- 5 Open problems
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1 Model Crystals grown from vapor (snow crystal)
from solution (NaCl crystal) <driving force : supersaturation> (density of atoms outside crystal is small)
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Stefan like Model
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unnormalized version :
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One phase Stefan problem with Gibbs-Thomson + kinetic effect
We shall consider (1)-(5) for given quasi-stationary One phase Stefan problem with Gibbs-Thomson + kinetic effect
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K. Deckelnik - C. Elliott ’99 ( Hele Shaw type )
Solvability (smooth ) K. Deckelnik - C. Elliott ’99 ( Hele Shaw type ) No … Friedman –Hu ’92 Liu – Yuan ’94
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Kuroda-Irisawa-Ookawa ‘77 Stability of facets Experiment e.g.
Others (No ) Kuroda-Irisawa-Ookawa ‘77 Stability of facets Experiment e.g. Gonda-Gomi ’85 (No ) : Fingering : Saffman-Taylor R.Almgrem ’95
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2.Problem (specific to ours)
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3. Main Math Results
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Th (Rybka-G ‘04) If is close to the Equilibrium then the solution solves the original problem (1),(2),(3), (4),(5),(6),(7) Near equilibrium Facet does not break.
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Reduction to ODE
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Near equilibrium : close to zero / bounded away from zero
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5. Open problems Existence of solution of the Original
problem is widly open if is not near equilibrium (Even if is given M.-H. Giga – Y. Giga ’98 graphs) ( : constant M.-H. Giga – Y. Giga ‘01 level set approach : unique existence of generalized sol (2-D)) Uniqueness of the solution of the original problem (Sol is unique for Reduced problems)
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All my preprints are in Hokkaido University Preprint Series on Math.
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