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How Atoms Interact with Each Other
Sodium chloride Nitrogen dioxide Carbon monoxide Chapter 1 Activity 8 Hydrochloric acid Calcium fluoride How Atoms Interact with Each Other Magnesium sulphate Hydrogen peroxide
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Why Do Elements Form Compounds?
to become stable The Octet Rule: Atoms tend to gain or lose electrons during chemical reactions so that the atoms have a filled outer energy level (usually 8 electrons). Lose 1 electron Gain 1 electron Na F 2 7
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How do we show bonding between atoms?
We show bonding using: electron-dot diagrams or Lewis Dot Diagrams 4
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Lewis Dot Diagrams Each dot represents a valence electron
Now practice writing the Lewis Dot for elements in the third period
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Try this!!! Practice determining the number of valence electrons in an atom Practice writing the Lewis diagram for atoms 1-20. 6
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Is it still an atom? protons = electrons THEY ARE NOW IONS!!!
Atoms are neutral- protons = electrons After electrons are lost or gained, they are no longer atoms. THEY ARE NOW IONS!!!
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Ionic Bonds Exist between a metal & nonmetal
Metals want to lose their valence electrons And become Cations (+) Nonmetals want to gain more valence electrons And become Anions (-) Why……. To become stable
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Which elements lose and gain electrons?
IA VIIIA IIA IIIA IVA VA VIA VIIA -4 +4 -3 -2 -1 +1 +2 +3 Which elements lose and gain electrons? 9
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So… A Metal and a Nonmetal get together! But remember, they get together to get a filled outer energy level And that is the octet rule
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FORMATION OF IONIC BONDS
Electrons are transferred from a metal to a nonmetal The metal becomes a cation; the nonmetal becomes an anion. The attraction of the oppositely charged ions forms the ionic bond.
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Naming Ionic Compounds
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Ionic Compounds Attraction between a metal cation (M+) and a nonmetal anion (X-) M+ X- Charges on ions must add up to zero!
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Naming an Ionic Compound:
1. Write the name for the metal and nonmetal 2. Change the nonmetal ending to IDE Ex: NaCl sodium chloride
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Element Ion Name Carbon Nitrogen Phosphorus Oxygen Sulfur Fluorine Chlorine Bromine Iodine carbide nitride phosphide oxide sulfide fluoride chloride bromide iodide
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Chemical Formula Chemical Name
EXAMPLES: Chemical Formula Chemical Name KBr Na2O MgS Ca3N2 AlF3 potassium bromide sodium oxide magnesium sulfide calcium nitride aluminum fluoride
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Writing Ionic Compounds
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How to Write an Ionic Formula:
1. Write down symbols 2. Determine Ionic Charges 3. Charges must cancel each other out (equal zero) if not, use criss-cross method to form subscripts to cancel out charges
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KBr MgO AlN MgCl2 Na2S Chemical Name Ion Charges Chemical Formula
EXAMPLES: Chemical Name Ion Charges Chemical Formula Potassium Bromide Magnesium Oxide Aluminum Nitride Magnesium Chloride Sodium Sulfide K+1 Br-1 charges cancel KBr Mg+2 O-2 charges cancel MgO Al+3 N-3 charges cancel AlN Mg+2 Cl-1 charges DON’T cancel criss-cross MgCl2 Na+1 S-2 charges DON’T cancel criss-cross Na2S
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EXAMPLES: Potassium Bromide K Br charges cancel KBr Magnesium Oxide Mg O-2 charges cancel MgO Aluminum Nitride Al N-3 charges cancel AlN Magnesium Chloride Mg Cl charges don’t cancel, criss-cross MgCl2 Sodium Sulfide Na S charges don’t cancel, criss-cross Na2S Aluminum Oxide Al O charges don’t cancel, criss-cross Al2O3
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Ionic Bonds: One big greedy thief dog! Ionic bonding can be best imagined as one big greedy dog steeling the other dog's bone.
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Lewis Dot Diagrams Ionic Bonds
Li F • F • Li 2 1 • F 2 7 • Li • F • Li • F • Li by giving or taking electrons with other atoms. Each atom attempts to attain a filled outer energy level • F • Li +1 • F Li -1 Li 2 +1 F 2 8 -1 22
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Count around Fluorine, there are 8 dots (8 valence electrons to make it stable)
• F Li +1 -1
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What is an Ion? A charged atom
Becomes charged after it loses or gains electrons It has a charge because the number of protons and electrons are no longer equal Li 2 +1 F 2 8 -1 • F Li +1 -1 P=3 E= P=9 E =10
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Bonding & Non-bonding Electrons
Bonding electrons-are the 2 electrons that form the bond between the atoms This can be represented with a dash • F Li Bonding electrons
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Bonding & Non-bonding Electrons
Nonbonding electrons-are any electrons that DO NOT form the bond between the atoms. They are in pairs (here there are 3 pairs of nonbonding electrons • F Li Nonbonding electrons
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Chapter 1 Activity 8 Covalent Bonding
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What is an Ionic Bond? IONIC BONDS:
1. Give or Take (transfer) valence electrons 2. Occur between a metal & nonmetal 3. High melting points 4. Conducts electricity when in solution EX: NaCl MgCl2
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What is a Covalent Bond? COVALENT BONDS: 1. Share valence electrons
2. Occur between nonmetal atoms only 3. Low melting point 4. Don’t conduct electricity when in solution EX: H2O Cl2
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COVALENT VS. IONIC BONDS
Covalent bonds Ionic bonds Share valence electrons Transfer valence electrons Occur between nonmetals only Occur between metals and nonmetals No ions involved Forms + and – ions Low Melting Point High Melting Point Ex. H2 CCl4 Ex. NaCl K2S 31
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Lewis Dot Diagrams for Covalent Bonds
• F H • H F • F H • H F by sharing electrons with other atoms. Each atom attempts to attain a filled outer shell • H F • F H (typically a noble gas electron configuration)
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Structural Formulas Bonds are represented with a dashed line F H F H
Circle all bonded electron pairs • F H Lewis dot Diagram Bonds are represented with a dashed line 1 single covalent bond (1 shared pair of e-s) 3 unshared pairs of e-s • F H Structural Diagram
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Covalent Bonds: Dogs of equal strength. Covalent bonds can be thought of as two or more dogs with equal attraction to the bones. Since the dogs (atoms) are identical (same electronegativities), then the dogs share the pairs of available bones evenly.
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Naming Covalent Compounds
Ex: CO CO2 1. The first element’s name doesn’t change. carbon carbon 2. Second element ends in IDE carbon oxide carbon oxide 3. Use prefixes to distinguish between compounds & to show how many atoms of each element are present carbon monoxide carbon dioxide
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Prefixes for Molecular Compounds:
1 mono Don’t use for first named element 2 di Ex: CO 3 tri carbon monoxide 4 tetra 5 penta 6 hexa 7 hepta 8 octa 9 nona 10 deca 1. drop vowel on prefix if element starts with vowel EX: monooxide = monoxide 2. Don’t drop vowel for di and tri prefixes
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phosphorus pentachloride
EXAMPLES: NO NO2 N2O N2O3 PCl5 CS2 SF6 nitrogen monoxide nitrogen dioxide dinitrogen monoxide dinitrogen trioxide phosphorus pentachloride carbon disulfide sulfur hexafluoride
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How to Write a Molecular Formula:
Write down element symbol Prefixes give you what subscripts to use Ex: Carbon tetrachloride Sulfur trioxide Tetraiodine nonoxide Ex: Carbon tetrachloride Sulfur trioxide Tetraiodine nonoxide Ex: Carbon tetrachloride Sulfur trioxide Tetraiodine nonoxide Ex: Carbon tetrachloride Sulfur trioxide Tetraiodine nonoxide CCl CCl4 SO SO3 I O I4O9
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Warm-up Name the following: P2O5 C3H8 K2O Cl2O7 Al2O3
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How to review for a quiz or test
1. create study checklists 2. create summary notes Organize your notes (graphic organizers) Create Flashcards Form study groups Create possible test questions.
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???? Bond Energies
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