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Phasing out of CFC refrigerants in India
Speaker Mrs. Jyoti S. Jadhav
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The Real Alarm 1974- Mario Molina and F. Sherwood Rowland
Nobel prize (1995) The Real Alarm
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Earlier refrigerants Natural ice Salt + Water Ether Ammonia
Sulphur dioxide Methyl chloride Carbon dioxide Air Earlier refrigerants
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Problems with early refrigerants
Toxicity (Ethers, ammonia) Flammability (Hydrocarbons) Material Compatibility( Ammonia) Chemical stability (SO2) Operating pressures (CO2) Limited temperature range Problems with early refrigerants
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CFC refrigerants Thomas Midgley of Du Pont, USA Boom in RAC industry
1920 CFC refrigerants
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Earth’s Atmosphere
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UV radiations
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Ozone Depletion What is ozone? Where is the “ozone layer”
Keeps out about 95% of UV rays
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Consumption of ODS in India
Sl. No. Sector Chemical Used 1. Foam CFC-11, HCFC-141b 2. RAC CFC-11, CFC-12, HCFC-22,HCFC-123 3. Aerosol CFC-11, CFC-12 4. Solvent Methyl Chloroform, CFC-113 5. Fire Halon – 1211 Extinguishers Halon – 1301
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India and Montreal Protocol
Joined on 17 Sep. 1992 Is an Article 5 country, along with 146 other countries (less than 0.3 kg. per capita ODS consumption) India and Montreal Protocol
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Phase-out Schedule as per Montreal Protocol
Ozone-depleting substance Developed Countries Developing Total Phase-out by 1st January of the year CFCs 1996 2010 Halons 1994 HBFCs CTC Methyl Chloroform 2015 Methyl Bromide 2005 HCFCs 2030 2040
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CFC phase out schedule for India
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India’s Initiatives towards ODS Phase-Out
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ODS Alternatives Sub-sector Application Alternative Technology
Domestic Refrigeration Household Refrigerators And Freezers HFC-134a,HFC-152a,Blends and mixtures, Hydrocarbons (for refrigerants) and HCFC-22, HCFC b, HCFC-141b, Hydrocarbons for foaming) Commercial Refrigeration Refrigerated Cabinets Water Coolers Ice-candy machines Walk-in coolers HFC-134a,HFC-152a,Blends and mixtures, Hydrocarbons (for refrigerants) and HCFC-22, HCFC b, Hydrocarbons (for foaming) HCFC-22, HFC-134a FCFC-22,HFC-134a (refrigerants) and HCFC-14b (foaming) Industrial Refrigeration Cold Storages Process Chillers HCFC-22,HFC-134a, Ammonia Transport Refrigeration Perishable Transport HCFC-22, HFC-134a, Blends and mixtures Air Conditioning Chillers Automotive air conditioning HCFC-123,HFC-134a,HCFC-22 HFC-134a, Blends and mixtures
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Thank you…………..
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